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Diesel engine combustion is simulated using Large Eddy Simulation (LES) with a multi-mode combustion (MMC) model. The MMC model is based on the combination of chemical kinetics, chemical equilibrium, and quasi-steady flamelet calculations in different local combustion regimes. The local combustion regime is identified by two combustion indices based on the local temperature and the extent of mixture homogeneity. The LES turbulence model uses the dynamic structure model (DSM) for sub-grid stresses. A new spray model in the LES context is used, and the Reynolds-averaged Navier-Stokes (RANS) based wall model is retained with the LES derived scales. These models are incorporated in the KIVA3V-ERC-Release 2 code for engine combustion simulations. A wide range of diesel engine operating conditions were chosen to validate the combustion model.

Exhaust gas recirculation (EGR) can be used to mitigate knock in SI engines. However, experiments have shown that the effectiveness of various EGR constituents to suppress knock varies with fuel type and compression ratio (CR). To understand some of the underlying mechanisms by which fuel composition, octane sensitivity (S), and CR affect the knock-mitigation effectiveness of EGR constituents, the current paper presents results from a chemical-kinetics modeling study. The numerical study was conducted with CHEMKIN, imposing experimentally acquired pressure traces on a closed reactor model. Simulated conditions include combinations of three RON-98 (Research Octane Number) fuels with two octane sensitivities and distinctive compositions, three EGR diluents, and two CRs (12:1 and 10:1). The experimental results point to the important role of thermal stratification in the end-gas to smooth peak heat-release rate (HRR) and prevent acoustic noise.

EGR can be used beneficially to control combustion phasing in HCCI engines. To better understand the function of EGR, this study experimentally investigates the thermodynamic and chemical effects of real EGR, simulated EGR, dry EGR, and individual EGR constituents (N2, CO2, and H2O) on the autoignition processes. This was done for gasoline and various PRF blends. The data show that addition of real EGR retards the autoignition timing for all fuels. However, the amount of retard is dependent on the specific fuel type. This can be explained by identifying and quantifying the various underlying mechanisms, which are: 1) Thermodynamic cooling effect due to increased specific-heat capacity, 2) [O2] reduction effect, 3) Enhancement of autoignition due to the presence of H2O, 4) Enhancement or suppression of autoignition due to the presence of trace species such as unburned or partially-oxidized hydrocarbons.

The effects of charge dilution on low-temperature diesel combustion and emissions were investigated in a small-bore single-cylinder diesel engine over a wide range of injection timing. The fresh air was diluted with additional N2 and CO2, simulating 0 to 65% exhaust gas recirculation in an engine. Diluting the intake charge lowers the flame temperature T due to the reactant being replaced by inert gases with increased heat capacity. In addition, charge dilution is anticipated to influence the local charge equivalence ratio ϕ prior to ignition due to the lower O2 concentration and longer ignition delay periods. By influencing both ϕ and T, charge dilution impacts the path representing the progress of the combustion process in the ϕ-T plane, and offers the potential of avoiding both soot and NOx formation.

The transportation industry has been scrutinized for its contribution towards the global greenhouse gas emissions over the years. While the automotive sector has been regulated by strict emission legislation globally, the emissions from marine transportation have been largely neglected. However, during the past decade, the international maritime organization focused on ways to lower the emission intensity of the marine sector by introducing several legislations. This sets limits on the emissions of different oxides of carbon, nitrogen and sulphur, which are emitted in large amounts from heavy fuel oil (HFO) combustion (the primary fuel for the marine sector). A 40% and 70% reduction per transport work compared to the levels of 2008 is set as target for CO2 emission for 2030 and 2050, respectively. To meet these targets, commonly, methanol, as a low-carbon fuel, and ammonia, as a zero-carbon fuel, are considered.

Dual-mode dual-fuel combustion is a promising combustion concept to achieve the required emissions and CO2 reductions imposed by the next standards. Nonetheless, the fuel formulation requirements are stricter than for the single-fuel combustion concepts as the combustion concept relies on the reactivity of two different fuels. This work investigates the effect of the low reactivity fuel sensitivity (S=RON-MON) and the octane number at different operating conditions representative of the different combustion regimes found during the dual-mode dual-fuel operation. For this purpose, experimental tests were performed using a PRF 95 with three different sensitivities (S0, S5 and S10) at operating conditions of 25% load/950 rpm, 50%/1800 rpm and 100%/2200 rpm. Moreover, air sweeps varying ±10% around a reference air mass were performed at 25%/1800 rpm and 50%/1800 rpm. Conventional diesel fuel was used as high reactivity fuel in all the cases.

A slipstream of exhaust from a Caterpillar 3126B engine was diverted into a plasma-catalytic NOx control system in the space velocity range of 7,000 to 100,000 hr-1. The stream was first fed through a non-thermal plasma that was formed in a coaxial cylinder dielectric barrier discharge reactor. Plasma treated gas was then passed over a catalyst bed held at constant temperature in the range of 573 to 773 K. Catalysts examined consisted of γ-alumina, indium-doped γ-alumina, and silver-doped γ-alumina. Road and rated load conditions resulted in engine out NOx levels of 250 - 600 ppm. The effects of hydrocarbon level, catalyst temperature, and space velocity are discussed where propene and in one case ultra-low sulfur diesel fuel (late cycle injection) were the reducing agents used for NOx reduction. Results showed NOx reduction in the range of 25 - 97% depending on engine operating conditions and management of the catalyst and slipstream conditions.

Experiments were conducted in an optically accessible constant-volume combustion vessel to investigate soot formation at diesel combustion conditions in a high exhaust-gas recirculation (EGR) environment. The ambient oxygen concentration was decreased systematically from 21% to 8% to simulate a wide range of EGR conditions. Quantitative measurements of in-situ soot in quasi-steady n-heptane and #2 diesel fuel jets were made by using laser extinction and planar laser-induced incandescence (PLII) measurements. Flame lift-off length measurements were also made in support of the soot measurements. At constant ambient temperature, results show that the equivalence ratio estimated at the lift-off length does not vary with the use of EGR, implying an equal amount of fuel-air mixing prior to combustion. Soot measurements show that the soot volume fraction decreases with increasing EGR.

Ethanol and ethanol/gasoline blends are being widely considered as alternative fuels for light-duty automotive applications. At the same time, HCCI combustion has the potential to provide high efficiency and ultra-low exhaust emissions. However, the application of HCCI is typically limited to low and moderate loads because of unacceptably high heat-release rates (HRR) at higher fueling rates. This work investigates the potential of lowering the HCCI HRR at high loads by using partial fuel stratification to increase the in-cylinder thermal stratification. This strategy is based on ethanol's high heat of vaporization combined with its true single-stage ignition characteristics. Using partial fuel stratification, the strong fuel-vaporization cooling produces thermal stratification due to variations in the amount of fuel vaporization in different parts of the combustion chamber.

The paper proposes the way of using scavenging curves, i.e., dependence of residual gas fraction in exhaust port or valve on residual fraction in a cylinder, found by CFD simulations. In the general case, exhaust gas recirculation outside of a cylinder (EGR) or internal gas recirculation caused by variable values of burned gas backflow to inlet system may influence in-cylinder residual gas fraction. These deviations may take place during engine optimization, done by 1D models. The determination of scavenging curves via 3D CFD simulations is a time consuming process, which cannot be repeated for every 1D case.

A new diagnostic technique is described that has the capability of making real-time, in situ measurements of the volatile fraction of diesel particulate matter (PM). LIDELS uses two laser pulses of comparable energy, separated in time by an interval sufficiently short to freeze the flow field, to measure the change in PM volume caused by laser-induced desorption of the volatile fraction. The first laser pulse produces elastic light scattering (ELS) that gives the volume of the total PM, and also deposits the energy to desorb the volatiles. ELS from the second pulse gives the volume of the remaining solid portion of the PM, and the ratio of these two measurements is the quantitative solid volume fraction. Calibration is required for the individual total PM and solid fraction to be quantitative. Applicability of the technique is demonstrated for load and EGR sweeps for a turbocharged, direct-injection diesel engine.

Reactivity Controlled Compression Ignition (RCCI) is an approach to increase engine efficiency and lower engine-out emissions by using in-cylinder stratification of fuels with differing reactivity (i.e., autoignition characteristics) to control combustion phasing. Stratification can be altered by varying the injection timing of the high-reactivity fuel, causing transitions across multiple regimes of combustion. When injection is sufficiently early, combustion approaches a highly-premixed autoignition regime, and when it is sufficiently late it approaches more mixing-controlled, diesel-like conditions. Engine performance, emissions, and control authority over combustion phasing with injection timing are most favorable in between, within the RCCI regime.

Laser-induced incandescence (LII) is a sensitive diagnostic technique capable of making exhaust particulate-matter measurements during transient operating conditions. This paper presents measurements of LII signals obtained from the exhaust gas of a 1.9-L TDI diesel engine. A scanning mobility particle sizer (SMPS) is used in fixed-size mode to obtain simultaneous number concentration measurements in real-time. The transient studies presented include a cranking-start/idle/shutdown sequence, on/off cycling of EGR, and rapid load changes. The results show superior temporal response of LII compared to the SMPS. Additional advantages of LII are that exhaust dilution and cooling are not required, and that the signal amplitude is directly proportional to the carbon volume fraction and its temporal decay is related to the primary particle size.

Various gold catalysts were prepared using commercial and in-house fabricated advanced catalyst supports that included mesoporous silica, mesoporous alumina, sol-gel alumina, and transition metal oxides. Gold nanoparticles were loaded on the supports by co-precipitation, deposition-precipitation, ion exchange and surface functionalization techniques. The average gold particle size was ∼20nm or less. The oxidation activity of the prepared catalysts was studied using carbon monoxide and light hydrocarbons (ethylene, propylene and propane) in presence of water and CO2 and the results are presented.

This paper describes two independent studies on γ-alumina as a plasma-activated catalyst. γ-alumina (2.5 - 4.3 wt%) was coated onto the surface of mesoporous silica to determine the importance of aluminum surface coordination on NOx conversion in conjunction with nonthermal plasma. Results indicate that the presence of 5- and 6- fold aluminum coordination sites in γ-alumina could be a significant factor in the NOx reduction process. A second study examined the effect of changing the reducing agent on NOx conversion. Several hydrocarbons were examined including propene, propane, isooctane, methanol, and acetaldehyde. It is demonstrated that methanol was the most effective reducing agent of those tested for a plasma-facilitated reaction over γ-alumina.

NOx reduction efficiency in simulated lean exhaust conditions has been examined for three proprietary catalyst materials using a non-thermal plasma discharge as a pretreatment stage to the catalyst. Using propene as the reducing agent for selective catalytic reduction, 74% reduction of NOx has been observed in the presence of 20 ppm SO2. For sulfur-free simulated exhaust, 84% NOx reduction has been obtained. Results show that the impact of sulfur on the samples examined can vary widely from virtually no effect (< 5%) to more than 20% loss in activity depending on the catalyst. Any loss due to sulfur poisoning appears to be irreversible according to limited measurements on poisoned catalysts exposed to sulfur-free exhaust streams. Catalysts were tested over a temperature range of 473-773K, with the highest activity observed at 773K. Examination of this large temperature window has shown that the optimum C1:NOx ratio changes with temperature.

Low pressure exhaust gases recirculation (LP-EGR) is becoming a state-of-the-art technique for Nitrogen oxides (NOx) reduction in compression ignited (CI) engines. However, despite the pollutant reduction benefits, LP-EGR suffers from strong non-linearities and delays which are difficult to handle, resulting in reduced engine performance under certain conditions. Measurement and observation of oxygen concentration at the intake have been a research topic over the past few years, and it may be critical for transition phases (from low pressure to high pressure EGR). Here, an adequate selection of models and sensors is essential to obtain a precise and fast measurement for control purposes. The present paper analyses different sensor configurations, with oxygen concentration measurements at the intake and exhaust manifold and combines observation techniques with sensor models to determine the potential of each configuration.

Partially premixed low-temperature combustion (LTC) using exhaust-gas recirculation (EGR) has the potential to reduce engine-out NOx and soot emissions, but increased unburned hydrocarbon (UHC) emissions need to be addressed. In this study, we investigate close-coupled post injections for reducing UHC emissions. By injecting small amounts of fuel soon after the end of the main injection, fuel-lean mixtures near the injector that suffer incomplete combustion can be enriched with post-injection fuel and burned to completion. The goal of this work is to understand the in-cylinder mechanisms affecting the post-injection efficacy and to quantify its sensitivity to operational parameters including post-injection duration, injection dwell, load, and ignition delay time of the post-injection mixture.

Engine combustion strategies that preserve high cycle efficiency while minimizing engine-out pollutant emissions are the focus of major research efforts around the world. Such high efficiency clean combustion (HECC) strategies typically employ compression ignition of a charge that exhibits an elevated degree of fuel/air premixing and/or dilution with combustion products. Prior studies have shown that a highly dilute, mixing-controlled combustion strategy using a high-cetane, oxygenated fuel can achieve HECC while avoiding the control, high-load knock, and light-load incomplete combustion difficulties that are often experienced with approaches that use a high degree of charge premixing. On the other hand, employing high dilution levels (e.g., by using large amounts of cooled exhaust gas recirculation, EGR) can place excessive burdens on engine heat exchangers and air-handling systems.

The knock-suppression effectiveness of exhaust-gas recirculation (EGR) can vary between implementations that take EGR gases after the three-way catalyst and those that use pre-catalyst EGR gases. A main difference between pre-and post-catalyst EGR gases is the level of trace species like NO, UHC, CO and H2. To quantify the role of NO, this experiment-based study employs NO-seeding in the intake tract for select combinations of fuel types and compression ratios, using simulated post-catalyst EGR gases as the diluent. The four investigated gasoline fuels share a common RON of 98, but vary in octane sensitivity and composition. To enable probing effects of near-zero NO levels, a skip-firing operating strategy is developed whereby the residual gases, which contain trace species like NO, are purged from the combustion chamber. Overall, the effects of NO-seeding on knock are consistent with the differences in knock limits for preand post-catalyst EGR gases.