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Φ-sensitivity is a fuel characteristic that has important benefits for the operation and control of low-temperature gasoline combustion (LTGC) engines. A fuel is φ-sensitive if its autoignition reactivity varies with the fuel/air equivalence ratio (φ). Thus, multiple-injection strategies can be used to create a φ-distribution that leads to several benefits. First, the φ-distribution causes a sequential autoignition that reduces the maximum heat release rate. This allows higher loads without knock and/or advanced combustion timing for higher efficiencies. Second, combustion phasing can be controlled by adjusting the fuel-injection strategy. Finally, experiments show that intermediate-temperature heat release (ITHR) increases with φ-sensitivity, increasing the allowable combustion retard and improving stability. A detailed mechanism was applied using CHEMKIN to understand the chemistry responsible for φ-sensitivity.

Using renewable fuels is a reliable approach for decarbonization of combustion engines. iso-Butanol and n-butanol are known as longer chain alcohols and have the potential of being used as gasoline substitute or a renewable fraction of gasoline. The combustion behavior of renewable fuels in modern combustion engines and advanced combustion concepts is not well understood yet. Low-temperature combustion (LTC) is a concept that is a basis for some of the low emissions-high efficiency combustion technologies. Fuel ɸ-sensitivity is known as a key factor to be considered for tailoring fuels for these engines. The Lund ɸ-sensitivity method is an empirical test method for evaluation of the ɸ-sensitivity of liquid fuels and evaluate fuel behavior in thermal. iso-Butanol and n-butanol are two alcohols which like other alcohol exhibit nonlinear behavior when blended with (surrogate) gasoline in terms of RON and MON.

Previous research has shown that the homogeneous charge compression ignition (HCCI) combustion concept holds promise for reducing pollutants (i.e. NOx, soot) while maintaining high thermal efficiency. However, it can be difficult to control the operation of the HCCI engines even under steady state running conditions. Power density may also be limited if high inlet air temperatures are used for achieving ignition. A methodology using a small pilot quantity of diesel fuel injected during the compression stroke to improve the power density and operation control is considered in this paper. Multidimensional computations were carried out for an HCCI engine based on a CAT3401 engine. The computations show that the required initial temperature for ignition is reduced by about 70 K for the cases of the diesel pilot charge and a 25∼35% percent increase in power density was found for those cases without adversely impacting the NOx emissions.

Exhaust gas recirculation (EGR) can be used to mitigate knock in SI engines. However, experiments have shown that the effectiveness of various EGR constituents to suppress knock varies with fuel type and compression ratio (CR). To understand some of the underlying mechanisms by which fuel composition, octane sensitivity (S), and CR affect the knock-mitigation effectiveness of EGR constituents, the current paper presents results from a chemical-kinetics modeling study. The numerical study was conducted with CHEMKIN, imposing experimentally acquired pressure traces on a closed reactor model. Simulated conditions include combinations of three RON-98 (Research Octane Number) fuels with two octane sensitivities and distinctive compositions, three EGR diluents, and two CRs (12:1 and 10:1). The experimental results point to the important role of thermal stratification in the end-gas to smooth peak heat-release rate (HRR) and prevent acoustic noise.

The objectives of this paper are to describe the research efforts in diesel engine combustion at Sandia National Laboratories' Combustion Research Facility and to provide recent experimental results. We have four diesel engine experiments supported by the Department of Energy, Office of Heavy Vehicle Technologies: a one-cylinder version of a Cummins heavy-duty engine, a diesel simulation facility, a one-cylinder Caterpillar engine to evaluate combustion of alternative fuels, and a homogeneous-charge, compression-ignition (HCCI) engine. Recent experimental results of diesel combustion research will be discussed and a description will be given of our HCCI experimental program and of our HCCI modeling work.

To cope with regulatory standards, minimizing tailpipe emissions with rapid catalyst light-off during cold-start is critical. This requires catalyst-heating operation with increased exhaust enthalpy, typically by using late post injections for retarded combustion and, therefore, increased exhaust temperature. However, retardability of post injection(s) is constrained by acceptable pollutant emissions such as unburned hydrocarbon (UHC). This study provides further insight into the mechanisms that control the formation of UHC under catalyst-heating operation in a medium-duty diesel engine, and based on the understanding, develops combustion strategies to simultaneously improve exhaust enthalpy and reduce harmful emissions. Experiments were performed with a full boiling-range diesel fuel (cetane number of 45) using an optimized five-injections strategy (2 pilots, 1 main, and 2 posts) as baseline condition.

Clutches are commonly utilised in passenger type and off-road heavy-duty vehicles to disconnect the engine from the driveline and other parasitic loads. In off-road heavy-duty vehicles, along with fuel efficiency start-up functionality at extended ambient conditions, such as low temperature and intake absolute pressure are crucial. Off-road vehicle manufacturers can overcome the parasitic loads in these conditions by oversizing the engine. Caterpillar Inc. as the pioneer in off-road technology has developed a novel clutch design to allow for engine downsizing while vehicle’s performance is not affected. The tribological behaviour of the clutch will be crucial to start engagement promptly and reach the maximum clutch capacity in the shortest possible time and smoothest way in terms of dynamics. A multi-body dynamics model of the clutch system is developed in MSC ADAMS. The flywheel is introducing the same speed and torque as the engine (represents the engine input to the clutch).

For better understanding of soot formation and oxidation processes in a biodiesel spray flame, the morphology, microstructure and sizes of soot particles directly sampled in a spray flame fuelled with soy-methyl ester were investigated using transmission electron microscopy (TEM). The soot samples were taken at different axial locations in the spray flame, 40, 50 and 70 mm from injector nozzle, which correspond to soot formation, peak, and oxidation zones, respectively. The biodiesel spray flame was generated in a constant-volume combustion chamber under a diesel-like high pressure and temperature condition (6.7 MPa, 1000K). Density, diameter of primary particles and radius of gyration of soot aggregates reached a peak at 50 mm from the injector nozzle and was lower or smaller in the formation or oxidation zones of the spray.

For a better understanding of soot formation and oxidation processes in conventional diesel and biodiesel spray flames, the morphology, microstructure and sizes of soot particles directly sampled in spray flames fuelled with US#2 diesel and soy-methyl ester were investigated using transmission electron microscopy (TEM). The soot samples were taken at 50mm from the injector nozzle, which corresponds to the peak soot location in the spray flames. The spray flames were generated in a constant-volume combustion chamber under a diesel-like high pressure and high temperature condition (6.7MPa, 1000K). Direct sampling permits a more direct assessment of soot as it is formed and oxidized in the flame, as opposed to exhaust PM measurements. Density of sampled soot particles, diameter of primary particles, size (gyration radius) and compactness (fractal dimension) of soot aggregates were analyzed and compared. No analysis of the soot micro-structure was made.

The effects of thermal and chemical aging on the performance of cordierite-based and high-porosity mullite-based diesel particulate filters (DPFs), were quantified, particularly their filtration efficiency, pressure drop, and regeneration capability. Both catalyzed and uncatalyzed core-size samples were tested in the lab using a diesel fuel burner and a chemical reactor. The diesel fuel burner generated carbonaceous particulate matter with a pre-specified particle-size distribution, which was loaded in the DPF cores. As the particulate loading evolved, measurements were made for the filtration efficiency and pressure drop across the filter using, respectively, a Scanning Mobility Particle Sizer (SMPS) and a pressure transducer. In a subsequent process and on a different bench system, the regeneration capability was tested by measuring the concentration of CO plus CO2 evolved during the controlled oxidation of the carbonaceous species previously deposited on the DPF samples.

Fundamental engine research is primarily conducted under steady-state conditions, in order to better describe boundary conditions which influence the studied phenomena. However, light-duty automobiles are operated, and tested, under heavily transient conditions. This mismatch between studied conditions and in-use conditions is deemed acceptable due to the fundamental knowledge gained from steady-state experiments. Nonetheless, it is useful to characterize the conditions encountered during transient operation and determine if the governing phenomena are unduly influenced by the differences between steady-state and transient operation, and further, whether transient behavior can be reasonably extrapolated from steady-state behavior. The transient operation mode used in this study consists of 20 fired cycles followed by 80 motored cycles, operating on a continuous basis.

Mandated pollutant emission levels are shifting light-duty vehicles towards hybrid and electric powertrains. Heavy-duty applications, on the other hand, will continue to rely on internal combustion engines for the foreseeable future. Hence there remain clear environmental and economic reasons to further decrease IC engine emissions. Turbocharged diesels are the mainstay prime mover for heavy-duty vehicles and industrial machines, and transient performance is integral to maximizing productivity, while minimizing work cycle fuel consumption and CO2 emissions. 1D engine simulation tools are commonplace for “virtual” performance development, saving time and cost, and enabling product and emissions legislation cycles to be met. A known limitation however, is the predictive capability of the turbocharger turbine sub-model in these tools.

The accurate quantification and control of mixture stoichiometry is critical in many applications using new combustion strategies and fuels (e.g., homogeneous charge compression ignition, gasoline direct injection, and oxygenated fuels). The parameter typically used to quantify mixture stoichiometry (i.e., the proximity of a reactant mixture to its stoichiometric condition) is the equivalence ratio, ϕ. The traditional definition of ϕ is based on the relative amounts of fuel and oxidizer molecules in a mixture. This definition provides an accurate measure of mixture stoichiometry when the fuel molecule does not contain oxidizer elements and when the oxidizer molecule does not contain fuel elements. However, the traditional definition of ϕ leads to problems when the fuel molecule contains an oxidizer element, as is the case when an oxygenated fuel is used, or once reactions have started and the fuel has begun to oxidize.

The objective of this investigation is to verify and characterize the influence of fuel volatility on maximum liquid-phase fuel penetration for a variety of actual Diesel fuels under realistic Diesel engine operating conditions. To do so, liquid-phase fuel penetration was measured for a total of eight Diesel fuels using laser elastic-scatter imaging. The experiments were carried out in an optically accessible Diesel engine of the “heavy-duty” size class at a representative medium speed (1200 rpm) operating condition. In addition to liquid-phase fuel penetration, ignition delay was assessed for each fuel based on pressure-derived apparent heat release rate and needle lift data. For all fuels examined, it was observed that initially the liquid fuel penetrates almost linearly with increasing crank angle until reaching a maximum characteristic length. Beyond this characteristic length, the fuel is entirely vapor phase and not just smaller fuel droplets.

Fuel properties impact the engine-out emission directly. For some geographic regions where diesel engines can meet emission regulations without aftertreatment, the change of fuel properties will lead to final tailpipe emission variation. Aftertreatment systems such as Diesel Particulate Filter (DPF) and Selective Catalytic Reduction (SCR) are required for diesel engines to meet stringent regulations. These regulations include off-road Tier 4 Final emission regulations in the USA or the corresponding Stage IV emission regulations in Europe. As an engine with an aftertreatment system, the change of fuel properties will also affect the system conversion efficiency and regeneration cycle. Previous research works focus on prediction of engine-out emission, and many are based on chemical reactions. Due to the complex mixing, pyrolysis and reaction process in heterogeneous combustion, it is not cost-effective to find a general model to predict emission shifting due to fuel variation.

We present a parametric analysis of electric vehicle (EV) adoption rates and the corresponding contribution to greenhouse gas (GHG) reduction in the US light-duty vehicle (LDV) fleet through 2050. The analysis is performed with a system dynamics based model of the supply-demand interactions among the fleet, its fuels, and the corresponding primary energy sources. The differentiating feature of the model is the ability to conduct global sensitivity and parametric trade-space analyses. We find that many factors impact the adoption rates of EVs. These include, in particular, policy initiatives that encourage consumers to consider lifetime ownership costs, the price of oil, battery performance, as well as the pace of technological development for all powertrains (conventional internal combustion engines included). Widespread EV adoption can have noticeable impact on petroleum consumption and GHG emissions by the LDV fleet.

This study summarizes the peer-reviewed literature regarding the use of raw pyrolysis liquids (PLs) created from woody biomass as fuels for compression-ignition (CI) engines. First, a brief overview is presented of fast pyrolysis and the potential advantages of PLs as fuels for CI engines. Second, a discussion of the general composition and properties of PLs relative to conventional, petroleum-derived diesel fuels is provided, with emphasis on the differences that are most likely to affect PL performance in CI-engine applications. Next, a synopsis is given of the peer-reviewed literature describing experimental studies of CI engines operated using neat PLs and PLs combined in various ways with other fuels. This literature conclusively indicates that raw PLs and PL blends cannot be used as “drop-in replacements” for diesel fuel in CI engines, which is reflected in part by none of the cited studies reporting successful operation on PL fuels for more than twelve consecutive hours.

Engine-out CO emission and fuel conversion efficiency were measured in a highly-dilute, low-temperature diesel combustion regime over a swirl ratio range of 1.44-7.12 and a wide range of injection timing. At fixed injection timing, an optimal swirl ratio for minimum CO emission and fuel consumption was found. At fixed swirl ratio, CO emission and fuel consumption generally decreased as injection timing was advanced. Moreover, a sudden decrease in CO emission was observed at early injection timings. Multi-dimensional numerical simulations, pressure-based measurements of ignition delay and apparent heat release, estimates of peak flame temperature, imaging of natural combustion luminosity and spray/wall interactions, and Laser Doppler Velocimeter (LDV) measurements of in-cylinder turbulence levels are employed to clarify the sources of the observed behavior.

Homogeneous Charge Compression Ignition (HCCI) has been proposed for natural gas engines in heavy duty stationary power generation applications. A number of researchers have demonstrated, through simulation and experiment, the feasibility of obtaining high gross indicated thermal efficiencies and very low NOx emissions at reasonable load levels. With a goal of eventual commercialization of these engines, this paper sets forth some of the primary challenges in obtaining high brake thermal efficiency from production feasible engines. Experimental results, in conjunction with simulation and analysis, are used to compare HCCI operation with traditional lean burn spark ignition performance. Current HCCI technology is characterized by low power density, very dilute mixtures, and low combustion efficiency. The quantitative adverse effect of each of these traits is demonstrated with respect to the brake thermal efficiency that can be expected in real world applications.

The transportation industry has been scrutinized for its contribution towards the global greenhouse gas emissions over the years. While the automotive sector has been regulated by strict emission legislation globally, the emissions from marine transportation have been largely neglected. However, during the past decade, the international maritime organization focused on ways to lower the emission intensity of the marine sector by introducing several legislations. This sets limits on the emissions of different oxides of carbon, nitrogen and sulphur, which are emitted in large amounts from heavy fuel oil (HFO) combustion (the primary fuel for the marine sector). A 40% and 70% reduction per transport work compared to the levels of 2008 is set as target for CO2 emission for 2030 and 2050, respectively. To meet these targets, commonly, methanol, as a low-carbon fuel, and ammonia, as a zero-carbon fuel, are considered.