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The objectives of this project were to investigate the corrosivity of condensate in a stoichiometric spark-ignited (SI) engine when running exhaust gas recirculation (EGR) and to determine the effects of sulfur-in-fuel on corrosion. A 2.0 L turbocharged direct-injected SI engine was operated with low-pressure EGR for this study. The engine was instrumented for visual, thermodynamic, and electrochemical analyses to determine the potential for corrosion at locations where condensation was deemed likely in a low-pressure loop EGR (LPL-EGR) engine. The electrochemical analysis was performed using multi-electrode array (MEA) corrosion probes. Condensate was also collected and analyzed. These analyses were performed downstream of both the charge air cooler (CAC) and the EGR cooler. It was found that while conditions existed for sulfuric acid to form with high-sulfur fuel, no sulfuric acid was detected by any of the measurement methods.

Nitrites have long been added to heavy-duty coolant to inhibit iron cylinder liner corrosion initiated by cavitation. However, in heavy-duty use, nitrites deplete from the coolant, which then must be refortified using supplemental coolant additives (SCA's). Recently, carboxylates have also been found to provide excellent cylinder liner protection in heavy-duty application. Unlike nitrites, carboxylate inhibitors deplete slowly and thus do not require continual refortification with SCA's. In the present paper laboratory aging experiments shed light on the mechanism of cylinder liner protection by these inhibitors. The performance of carboxylates, nitrites and mixtures of the two inhibitors are compared. Results correlate well with previously published fleet data. Specifically, rapid nitrite and slow carboxylate depletion are observed. More importantly, when nitrite and carboxylates are used in combination, nitrite depletion is repressed while carboxylates deplete at a very slow rate.

The impact of additive and oil chemistry on low speed pre-ignition (LSPI) was evaluated. An additive metals matrix varied the levels of zinc dialkyldithiophosphate (ZDDP), calcium sulfonate, and molybdenum within the range of commercially available engine lubricants. A separate test matrix varied the detergent chemistry (calcium vs. magnesium), lubricant volatility, and base stock chemistry. All lubricants were evaluated on a LSPI test cycle developed by Southwest Research Institute within its Pre-Ignition Prevention Program (P3) using a GM LHU 2.0 L turbocharged GDI engine. It was observed that increasing the concentration of calcium leads to an increase in the LSPI rate. At low calcium levels, near-zero LSPI rates were observed. The addition of zinc and molybdenum additives had a negative effect on the LSPI rate; however, this was only seen at higher calcium concentrations.

For this latest SAE Fatigue Design and Evaluation project, fatigue tests were run by loading, in bending, both welded and machined T-Joint specimens that have the same geometry. The test rig setup consisted of a horizontally mounted actuator, with pinned joints at both ends, where the load is applied to the top of the vertical leg of the “upside down T” of a T-Joint specimen, while the horizontal legs of the “upside down T” were clamped to the bedplate. Specimens were tested until failure or until the specimen was unable to carry the commanded load. They were cycled under constant amplitude (at several load levels and R ratios), block cycle, and variable amplitude loadings. Welded and machined T-Joint specimens of the same geometry were included in the test plan such that fatigue life predictions could be compared to test lives for each case. Those comparisons would demonstrate the methodology’s relative predictive ability to manage welds, residual stress, etc...

This paper discusses the techniques and diagnostic significance of atomic absorption, atomic emission, and infrared spectrometric analysis of crankcase lubricants, with the use of supplementary data where pertinent. The parameters affecting used oil analytical data are discussed in terms of examples from Army general purpose vehicle test engines. Wear metals in used gear oils are also discussed and examples are given. Analytical methods and their applications are fully described, and the equipment and procedures for infrared spectroscopy and gas chromatography techniques are outlined.

Engineering new technology and products challenges managers to balance design innovation and program risk. To do this, managers need methods to judge future results to avoid program and product disasters. Besides the traditional prediction tools of schedule, simulations and “iron tests”, process control standards (with measurements) can also be applied to the development programs to mitigate risks. This paper briefly discusses the theory and case history behind some new process control methods and standards currently in place at Caterpillar's Electrical & Electronics department. Process standards reviewed in this paper include process mapping, ISO9001, process controls, and process improvement models (e.g. SEI's CMMs.)

This paper describes two independent studies on γ-alumina as a plasma-activated catalyst. γ-alumina (2.5 - 4.3 wt%) was coated onto the surface of mesoporous silica to determine the importance of aluminum surface coordination on NOx conversion in conjunction with nonthermal plasma. Results indicate that the presence of 5- and 6- fold aluminum coordination sites in γ-alumina could be a significant factor in the NOx reduction process. A second study examined the effect of changing the reducing agent on NOx conversion. Several hydrocarbons were examined including propene, propane, isooctane, methanol, and acetaldehyde. It is demonstrated that methanol was the most effective reducing agent of those tested for a plasma-facilitated reaction over γ-alumina.

Atmospheric corrosion of steels, aluminum alloys, and Al-clad aluminum alloys is a problem for many civil engineering structures, commercial and military vehicles, and aircraft. Paint is usually the primary means to prevent the corrosion of steel bridge components, automobiles, trucks, and aircraft. Under ideal conditions, the coating provides a continuous layer that is impervious to moisture. At present, maintenance cycles for commercial and military aircraft and ground vehicles, as well as engineered structures, is based on experience and appearance rather than a quantitative determination of coating integrity. To improve the maintenance process and reduce costs, sensors are often used to monitor corrosion. The present suite of sensors designed to detect corrosion and marketed to predict the lifetime of the engineered components, however, are not useful for determining the condition of the protective paint coatings.

A number of oxidation catalysts have been prepared using different types of advanced support materials such as ceria-zirconia, silica-titania, spinels and perovskites. Active metals such as Pd and Au-Pd were loaded by conventional impregnation techniques and/or deposition-precipitation methods. A liquid hydrocarbon delivery system was designed and implemented for the catalyst test benches in order to simulate the diesel engine exhaust environment. The activity of fresh (no degreening) catalysts was evaluated with traditional CO and light hydrocarbons (C2H4, C3H6) as well as with heavy hydrocarbons such as C10 H22.

Smaller locomotives often use mechanical transmissions instead of diesel-electric drive systems typically used in larger locomotives. This paper discusses how Model Based Design was used to develop the complete drive train control system for a 24 ton sugar cane locomotive. A complete MATLAB Simulink machine model was built to fully test and verify the shift control logic, traction control, vehicle speed limiting, and braking control for this locomotive application before it was commissioned. The model included the engine, torque converter, planetary transmission, drive line, and steel on steel driving surface. Simulation was used to debug all control code and test and refine control strategies so that the initial field commissioning in remote Australia was executed very quickly with minimal engineering support required.

In lightweight structures with dissimilar metal designs, structural adhesive joining is a potential joining method. Adhesives help in reducing galvanic corrosion by minimizing physical contact between two dissimilar metals. Along with adhesives, fasteners are often used as a secondary joining method to hold the assembly together during adhesive curing. Therefore, a hybrid joint which is a combination of adhesives and mechanical fasteners is potential joining method to join dissimilar metals. However, when two dissimilar metals such as aluminum to steel are joined with hybrid joint by adhesive curing at elevated temperature, the distortion of assembly is observed when cooled at room temperature. This is due to the mismatch between coefficients of thermal expansion of aluminum vs steel. The adhesive may also experience residual stress and fracture. In this study, adhesive curing induced distortion is studied using 1.1 meter-long specimens of aluminum to steel hybrid joint assembly.

This paper shows the results of an experimental investigation of the nature and characteristics of erosion of metals by high-speed impingement of airborne dust particles. The influence of various parameters upon the rate of erosion is shown. The manner in which the rate of erosion varies with certain of these parameters indicates that erosion occurs through the ductile displacement of the eroded material by the impinging dust particle.

Since the advent of P/M technology as a near net shape production process, millions of mechanical components of various shapes and sizes have been produced. Although P/M continues to be one of the fast growing shaping processes, it suffers from the inability to produce intricate geometry's such as internal tapers, threads or recesses perpendicular to pressing direction. In such cases application of machining as a secondary forming operation becomes the preferred alternative. However, machining of P/M parts due to their inherent porosity is known to decrease tool life and increase tool chatter and vibration. Consequently, several attempts have been made to improve the machinability of P/M materials by either addition of machinability enhancing elements such as sulfur, calcium, tellurium, selenium, etc., or by resin impregnation of P/M parts.

Copper ion exchange procedures were used to prepare zeolite-based catalysts for NOx reduction in lean (oxygen-rich) exhaust. Energy dispersive x-ray fluorescence and scanning electron microscopy analyses confirmed the presence of copper in the zeolite matrix. Zeolites were applied onto honeycomb and foam substrates, and evaluated for catalytic NOx reduction efficiency using engine exhaust. Copper-exchanged zeolite catalysts prepared for this study revealed NOx reduction of 95 percent for a period of seven minutes using previously adsorbed exhaust hydrocarbons as the reducing agent. Experiments using ethylene injection to supplement the exhaust suggest long-term and sustained NOx reduction, initially observed at 52 percent. Experimental results and performance comparisons of ZSM-5, mordenite, and Y-type zeolites are discussed. Zeolite catalysts based on Cu-mordenite showed high levels of initial NOx reduction, while results using Cu-ZSM-5 suggested better long-term activity.

Neat methanol fuel (M100) has many advantages for achieving low emission levels as an automotive fuel, but there are several items that require attention before this fuel can replace conventional fuels. One item involves the low flame luminosity of methanol. An extensive literature search and laboratory evaluation were conducted to identify potential additive candidates to improve the luminosity of a methanol flame. Potential compounds were screened based on their concentration, luminosity improvement, and duration of luminosity improvement during the burn. Three compounds were found to increase the flame luminosity for segments of the burn at relatively low concentrations: toluene, cyclopentene, and indan. In combination, these three compounds markedly improved the luminosity of methanol throughout the majority of the burn. The two combinations were 1) 4 percent toluene plus 2 percent indan and 2) 5 percent cyclopentene plus 5 percent indan in methanol.

The induction hardening process involves a complex interaction of electromagnetic heating, rapid cooling, metallurgical phase transformations, and mechanical behavior. Many factors including induction coil design, power, frequency, scanning velocity, workpiece geometry, material chemistry, and quench severity determine a process outcome. This paper demonstrates an effective application of a numerical analysis tool for understanding of induction hardening. First, an overview of the Caterpillar induction simulation tool is briefly discussed. Then, several important features of the model development are examined. Finally, two examples illustrating the use of the computer simulation tool for solving induction-hardening problems related to cracking and distortion are presented. These examples demonstrate the tool's ability to simulate changes in process parameters and latitude of modeling steel or cast iron.

It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil-derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter.

The fatigue properties of gray cast iron are presented. Included in these properties are monotonic tension and compression data and cyclic strain control fatigue data. Estimations of fatigue properties determined from the measured fatigue data are compared to predicted fatigue properties based on static properties. Samples with average hardnesses of 171 and 213 Bhn iron were tested and the results compared. The results of this investigation revealed that the strain amplitude cycles-to-failure plot of gray cast iron was independent of hardness of the iron.

An experimental program was designed to determine friction characteristics between brake pads and metal rotors that could indicate a brake fluid's propensity to cause chatter in wet-brakes. Friction was measured on a bench version of the John Deere wet-brake qualification system. Rotor and pad supports were made very rigid to avoid chatter in the simulator. One type of pad was run on cast-iron and mild steel rotors using two reference oils, one giving unacceptable levels of chatter and the other giving acceptable levels as previously determined in full-scale tests on the Deere system. The outstanding discriminating characteristic was the drop in friction from breakaway of the pad from the rotor. The ratio of the initial drop in the friction coefficient between unacceptable and acceptable oils for all conditions of the testing ranged from 1.7 to 2.0

The presence of residual stresses affects the fatigue response of welded components. In the present study of thick welded cantilever specimens, residual stresses were measured in two A36 steel samples, one in the as-welded condition, and one subjected to a short history of bending loads where substantial local plasticity is expected at the fatigue hot-spot weld toe. Extensive X-Ray Diffraction (XRD) measurements describe the residual stress state in a large region above the weld toe both in an untested as-welded sample and in a sample subjected to a short load history that generated an estimated 0.01 strain amplitude at the stress concentration zone at the weld toe. The results show that such a test will significantly alter the welding-induced residual stresses. Fatigue life prediction methods need to be aware that such alterations are possible and incorporate the effects of such cyclic stress relaxation in life computations.