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The confluence of fuel economy improvement requirements and increased use of ethanol as a gasoline blend component has led to various studies into the efficiency and performance benefits to be had when using high octane number, high ethanol content fuels in modern engines. As part of a comprehensive study of the autoignition of fuels in both the CFR octane rating engine and a modern, direct injection, turbocharged spark ignited engine, a series of fuel blends were prepared with market relevant ranges of octane numbers and ethanol blends levels. The paper reports on the first part of this study where fuel flow measurements were done on a single cylinder research engine, utilizing a GM LHU combustion system, and then used to predict drive cycle fuel economy. For a range of engine speeds and manifold air pressures, spark timing was adjusted to achieve either the maximum brake torque (MBT) or a matched 50 % mass fraction burnt location.

The use of alcohol as a supplemental fuel for a medium-speed diesel engine was investigated using a two-cylinder, two-stroke test engine. Both stabilized and unstabilized emulsions of methanol-in-diesel fuel and ethanol-in-diesel fuel were tested. Also, anhydrous ethanol/diesel fuel solutions were evaluated. Maximum alcohol content of the emulsions and solutions was limited by engine knocking due to a reduction in fuel cetane number. Engine power and thermal efficiency were slightly below baseline diesel fuel levels in the high and mid-speed ranges, but were somewhat improved at low speeds during tests of the unstabilized emulsions and the ethanol solutions. However, thermal efficiency of the stabilized emulsions fell below baseline levels at virtually all conditions.

Experiments were performed on a small displacement (< 2 L), high compression ratio, 4 cylinder, port injected gasoline engine equipped with Dedicated EGR® (D-EGR®) technology using fuels with varying anti-knock properties. Gasolines with anti-knock indices of 84, 89 and 93 anti-knock index (AKI) were tested. The engine was operated at a constant nominal EGR rate of ∼25% while varying the reformation ratio in the dedicated cylinder from a ϕD-EGR = 1.0 - 1.4. Testing was conducted at selected engine speeds and constant torque while operating at knock limited spark advance on the three fuels. The change in combustion phasing as a function of the level of overfuelling in the dedicated cylinder was documented for all three fuels to determine the tradeoff between the reformation ratio required to achieve a certain knock resistance and the fuel octane rating.

The use of biodiesel fuels derived from vegetable oils or animal fats as a substitute for conventional petroleum fuel in diesel engines has received increased attention. This interest is based on a number of properties of biodiesel including the fact that it is produced from a renewable resource, its biodegradability, and its potential beneficial effects on exhaust emissions. As part of Tier 1 compliance requirements for EPA's Fuel Registration Program, a detailed chemical characterization of the transient exhaust emissions from three modern diesel engines was performed, both with and without an oxidation catalyst. This characterization included several forms of hydrocarbon speciation, as well as measurement of aldehydes, ketones, and alcohols. In addition, both particle-phase and semivolatile-phase PAH and nitro-PAH compounds were measured. Unregulated emissions were characterized with neat biodiesel and with a blend of biodiesel and conventional diesel fuel.

The use of biodiesel fuels derived from vegetable oils or animal fats as a substitute for conventional petroleum fuel in diesel engines has received increased attention. This interest is based on a number of properties of biodiesel including the fact that it is produced from a renewable resource, its biodegradability, and its potential beneficial effects on exhaust emissions. Transient exhaust emissions from three modern diesel engines were measured during this study, both with and without an oxidation catalyst. Emissions were characterized with neat biodiesel and with a blend of biodiesel and conventional diesel fuel. Regulated emissions and performance data are presented in this paper, while the results of a detailed chemical characterization of exhaust emissions are presented in a companion paper. The use of biodiesel resulted in lower emissions of unburned hydrocarbons, carbon monoxide, and particulate matter, with some increase in emissions of oxides of nitrogen on some engines.

Forty-five cars were entered from 37 universities across the U.S. and Canada in the ninth annual Formula SAE Student Design Competition held on May 25, 26 and 27 at the University of Texas at San Antonio (UTSA). Thirty-six cars from 31 schools actually competed, but only 22 cars finished. The event included many firsts in Formula SAE. The SAE South Texas Section set a precedent by co-hosting the competition with the UTSA. The GM Sunraycer display and demonstration exhibited high technology and corporate support of Formula SAE. Total award funds (from various sponsors) exceeded those of previous events. New awards were given by new sponsors in 1989.

Regulated and unregulated emissions (individual hydrocarbons, ethanol, aldehydes and ketones, polynuclear aromatic hydrocarbons (PAH), nitro-PAH, and soluble organic fraction of particulate matter) were characterized in engines utilizing duplicate ISO 8178-C1 eight-mode tests and FTP smoke tests. Certification No. 2 diesel (400 ppm sulfur) and three ethanol/diesel blends, containing 7.7 percent, 10 percent, and 15 percent ethanol, respectively, were used. The three, Tier II, off-road engines were 6.8-L, 8.1-L, and 12.5-L in displacement and each had differing fuel injection system designs. It was found that smoke and particulate matter emissions decreased with increasing ethanol content. Changes to the emissions of carbon monoxide and oxides of nitrogen varied with engine design, with some increases and some decreases. As expected, increasing ethanol concentration led to higher emissions of acetaldehyde (increases ranging from 27 to 139 percent).

Biodiesel produced from soybean oil, canola oil, yellow grease, and beef tallow was tested in two heavy-duty engines. The biodiesels were tested neat and as 20% by volume blends with a 15 ppm sulfur petroleum-derived diesel fuel. The test engines were a 2002 Cummins ISB and 2003 DDC Series 60. Both engines met the 2004 U.S. emission standard of 2.5 g/bhp-h NOx+HC (3.35 g/kW-h) and utilized exhaust gas recirculation (EGR). All emission tests employed the heavy-duty transient procedure as specified in the U.S. Code of Federal Regulations. Reduction in PM emissions and increase in NOx emissions were observed for all biodiesels in all engines, confirming observations made in older engines. On average PM was reduced by 25% and NOx increased by 3% for the two engines tested for a variety of B20 blends. These changes are slightly larger in magnitude, but in the same range as observed in older engines.

To better understand real fuel effects on LSPI, a matrix was developed to vary certain chemical and physical properties of gasoline. The primary focus of the study was the impact of paraffinic, olefinic, and aromatic components upon LSPI. Secondary goals of this testing were to study the impact of ethanol content and fuel volatility as defined by the T90 temperature. The LSPI rate increased with ethanol content but was insensitive to olefin content. Additionally, increased aromatic content uniformly led to increased LSPI rates. For all blends, lower T90 temperatures resulted in decreased LSPI activity. The correlation between fuel octane (as RON or MON) suggests that octane itself does not play a role; however, the sensitivity of the fuel (RON-MON) does have some correlation with LSPI. Finally, the results of this analysis show that there is no correlation between the laminar flame speed of a fuel and the LSPI rate.

A literature evaluation of potential oxidative and thermal stability test methods for biodiesel and biodiesel blends with petrodiesel, as well as the known effects of stability related issues on performance in the field, has been completed. The advantages and disadvantages of the selected potential test methods were compiled to form a basis for further consideration and rating of the test methods. The literature search and rankings were peer reviewed by experts in the oleochemical, petroleum diesel, and diesel engine manufacturing fields. Based on the peer-reviewed rankings, limited bench scale testing was performed on selected test methods and various modifications to determine their applicability to biodiesel and biodiesel blends. For various reasons, none of the methods (as written) appeared to be reliable indicators of performance with biodiesel or its blends.

This paper describes two independent studies on γ-alumina as a plasma-activated catalyst. γ-alumina (2.5 - 4.3 wt%) was coated onto the surface of mesoporous silica to determine the importance of aluminum surface coordination on NOx conversion in conjunction with nonthermal plasma. Results indicate that the presence of 5- and 6- fold aluminum coordination sites in γ-alumina could be a significant factor in the NOx reduction process. A second study examined the effect of changing the reducing agent on NOx conversion. Several hydrocarbons were examined including propene, propane, isooctane, methanol, and acetaldehyde. It is demonstrated that methanol was the most effective reducing agent of those tested for a plasma-facilitated reaction over γ-alumina.

Fumigation, inline mixing, chemically stabilized emulsions and cetane improvers were evaluated as a means of using ethanol in diesel engines. Two turbocharged six-cylinder engines of identical bore and stroke were used, differing in combustion chamber type. Three alcohol proofs were evaluated: 200, 190, and 160. Alcohol was added at the following concentrations: 10, 25, and 50% except in the case of the cetane-improved alcohol. In the latter case a commercial ignition improver for diesel fuel, DII-3, was added to neat alcohol in the proportions of 10, 15, and 20%. Generally, the emissions of CO, total hydrocarbons, and oxides of nitrogen reflected the trends observed in the thermal efficiencies. At light loads, CO and HC emissions were higher than baseline, decreasing to near baseline levels at heavy loads accompanied with higher NOx.

Conventional diesel fuel has been in the market for decades and used successfully to run diesel engines of all sizes in many applications. In order to reduce emissions and to foster energy source diversity, new fuels such as alternative and renewable, as well as new fuel formulations have entered the market. These include biodiesel, gas-to-liquid, and alternative formulations by states such as California. Performance variations in fuel economy, emissions, and compatibility for these fuels have been evaluated and debated. In some cases contradictory views have surfaced. “Sustainable”, “Renewable”, and “Clean” designations have been interchanged. Adding to the confusion, results from one fuel in one type of engine such as an older heavy-duty engine, is at times compared to that of another type such as a modern light-duty. This study was an attempt to compare the performance of several fuels in an identical environment, using the same engine, for direct comparison.

Conventional diesel fuel has been in the market for decades and used successfully to run diesel engines of all sizes in many applications. In order to reduce emissions and to foster energy source diversity, new fuels such as alternative and renewable, as well as new fuel formulations have entered the market. These include biodiesel, gas-to-liquid, and alternative formulations by states such as California. Performance variations in fuel economy, emissions, and compatibility for these fuels have been evaluated and debated. In some cases contradictory views have surfaced. “Sustainable”, “Renewable”, and “Clean” designations have been interchanged. Adding to the confusion, results from one fuel in one type of engine such as an older heavy-duty engine, is at times compared to that of another fuel in another type such as a modern light-duty engine. This study was an attempt to compare the performance of several fuels in identical environments, using the same engine, for direct comparison.

Particulate mass (PM) emissions from DISI engines can be reduced via fuels additive technology that facilitates injector deposit clean-up. A significant drawback of DISI engines is that they can have higher particulate matter emissions than PFI gasoline engines. Soot formation in general is dependent on the air-fuel ratio, combustion chamber temperature and the chemical structure and thermo-physical properties of the fuel. In this regard, PM emissions and DISI injector deposit clean-up were studied in three identical high sales-volume vehicles. The tests compared the effects of a fuel (Fuel A) containing a market generic additive at lowest additive concentration (LAC) against a fuel formulated with a novel additive technology (Fuel B). The fuels compared had an anti-knock index value of 87 containing up to 10% ethanol. The vehicles were run on Fuel A for 20,000 miles followed by 5,000 miles on Fuel B using a chassis dynamometer.

It is generally recognized chat methanol is the best candidate for long-term replacement of petroleum-based fuels at soma time in the future. The transition from an established fuel to a new fuel, and vehicles that can use the new fuel, is difficult, however. This paper discusses two independent investigations of possible transition uses of methanol, which, when combined, may provide an option for introduction of methanol that takes advantage of the existing industrial base, and provides economic incentives to the consumer. The concept combines the intermediate blends of methanol and gasoline (50%-70% methanol) with the Flexible Fuel Vehicle. In addition to a possible maximum cost effectiveness, these fuels ease vehicle range restrictions due to refueling logistics, and mitigate cold starting problems, while at the same time providing most of the performance of the higher concentration blends.

In order to demonstrate the performance of a retrofitted selective catalytic reduction (SCR) system while also addressing the issues associated with greater use of biodiesel, a 2005 International 9200i tractor owned by the City of Santa Monica was retrofitted with a titania-vanadia-tungsten catalyst and a urea dosing system supplied by Extengine Systems, Inc. This tractor was operated under normal service conditions within the City of Santa Monica refuse collection and transportation fleet. An on-board emissions measurement system supplied by Engine, Fuel, and Emissions Engineering, Inc. was installed on the vehicle; it measured the emissions and fuel use of the vehicle while it operated on ultra-low-sulfur diesel (ULSD), 20% biodiesel (B20), and 99% biodiesel (B99) on consecutive days.

The dual-fuel combustion process of ethanol and n-heptane was characterized experimentally in an optically accessible engine and numerically through a chemical kinetic 3D-CFD investigation. Previously reported formaldehyde PLIF distributions were used as a tracer of low-temperature oxidation of straight-chained hydrocarbons and the numerical results were observed to be in agreement with the experimental data. The numerical and experimental evidence suggests that a change in the speed of flame propagation is responsible for the observed behavior of the dual-fuel combustion, where the energy release duration is increased and the maximum rate of pressure rise is decreased. Further, an explanation is provided for the asymmetrical energy release profile reported in literature which has been previously attributed to an increase in the diffusion-controlled combustion phase.

Alternative fuels such as methanol can significantly reduce greenhouse gas (GHG) emissions when used in internal combustion engines (ICEs). This study characterized the combustion of methanol, methanol/diesel, and methanol/renewable diesel numerically. Numerical findings were also compared with engine experiments using a single-cylinder engine (SCE). The engine was operated under a dual-fuel combustion mode: methanol was fumigated at the intake port, and diesel was injected inside the cylinder. The characteristic of ignition delay trend as methanol concentration increased is being described at low temperature (low engine load) and high temperature (high engine load) conditions.

A novel oxygenate, 5-methyl furoate ethyl ester (EF), was made by a chemical process from biomass and ethanol. This compound was then used as a renewable diesel additive at concentrations up to 10 percent by volume. This unique ester, which is similar in composition to a know food additive, was studied for engine performance in comparison with two other oxygenated alternatives (i.e. ethanol - EtOH and ethyl levulinate - EL) and with B20 (20 percent biodiesel). Tests were performed with a 2012 6.7 L Ford diesel engine using the heavy-duty Federal Test Procedure. The emission results indicated that a blend of the ester with diesel was comparable to the base fuel. In addition, the results also indicated that EF reduces the formation of particulate matter (PM) and carbon monoxide. Other properties of EF seem to improve the physical properties of the blended fuel such as lubricity and viscosity when compared to the base fuel.