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A combined, experimental and numerical program is presented. This work summarizes an internal research effort conducted at Southwest Research Institute. Meeting new, stringent emissions regulations for diesel engines requires a way to reduce NOx and soot emissions. Most emissions reduction strategies reduce one pollutant while increasing the other. Water injection is one of the few promising emissions reduction techniques with the potential to simultaneously reduce soot and NOx in diesel engines. While it is widely accepted that water reduces NOx via a thermal effect, the mechanisms behind the reduction of soot are not well understood. The water could reduce the soot via physical, thermal, or chemical effects. To aid in developing water injection strategies, this project's goal was to determine how water enters the soot formation chemistry.

Water injection is an effective method for knock control in spark-ignition engines. However, the requirement of a separate water source and the cost and complexity associated with a fully integrated system creates a limitation of this method to be used in volume production engines. The engine exhaust typically contains 10-15% water vapor by volume which could be condensed and potentially stored for future use. In this study, the exhaust condensate composition was assessed for its use as an effective replacement for distilled water. Specifically, condensate samples were collected pre and post-three-way catalyst (TWC) and analyzed for acidity and composition. The composition of the pre and post-TWC condensates was found to be similar however, the pre-TWC condensate was mildly acidic. The mild acidity has the potential to corrode certain components in the intake air circuit.