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All around the world, steps are being taken to improve the quality of our environment. Prominent among these are the definition, implementation, and attainment of increasingly stringent emissions regulations for all types of engines, including off-highway diesels. These rigorous regulations have driven use of technologies like after-treatment, advanced air systems, and advanced fuel systems. Fuel dispensed off-highway is routinely and significantly dirtier than fuel from on-highway outlets. Furthermore, fuels used in developing countries can be up to 30 times dirtier than the average fuels in North America. Poor fuel cleanliness, coupled with the higher pressures and performance demands of modern fuel systems, create life challenges greater than encountered with cleaner fuels. This can result in costly disruption of operations, loss of productivity, and customer dissatisfaction in the off-highway market.

Waterborne automotive OEM primer surfacers have been commercialized and available to European Assembly Plants since early 1990. Besides the advantage of low VOC, physical properties such as chip and impact resistance are excellent. Technical problems encountered are mostly application related such as sensitivity to high relative humidity. Pop and sag resistance at high film builds have been minimized by application technique and formula modifications. With solventborne high solids primer surfacers being pushed to their VOC limits by more stringent regulations in North America, waterborne primer surfacers are “primed” to meet the challenge.

A family of cross-linkable acrylic copolymer resins - which uniquely have a thermoplastic “B-stage” that enables thermoplastic prepregs and semi-finished goods to be produced - is providing the opportunity to manufacture durable automotive interior trim-panel substrates with comparable or higher performance at lower weight and fewer processing steps than common thermoplastic and thermoset composites long used in such applications. Owing to their special chemistry and very-low initial viscosity, the acrylic copolymers provide excellent wetout / impregnation of fibrous or particulate reinforcements, facilitating the production of composite parts with very-high fiber volume fractions (FVFs). Loading levels as high as 70-90% have already been achieved with natural fibers. In the presence of heat and pressure, the material cross-links to form durable copolymers with excellent thermo-mechanical properties.

Previous research has shown that the homogeneous charge compression ignition (HCCI) combustion concept holds promise for reducing pollutants (i.e. NOx, soot) while maintaining high thermal efficiency. However, it can be difficult to control the operation of the HCCI engines even under steady state running conditions. Power density may also be limited if high inlet air temperatures are used for achieving ignition. A methodology using a small pilot quantity of diesel fuel injected during the compression stroke to improve the power density and operation control is considered in this paper. Multidimensional computations were carried out for an HCCI engine based on a CAT3401 engine. The computations show that the required initial temperature for ignition is reduced by about 70 K for the cases of the diesel pilot charge and a 25∼35% percent increase in power density was found for those cases without adversely impacting the NOx emissions.

The history and state of the art use of pigments known as transparent titanium dioxides in automotive coatings is described. This pigment, also known as microfine TiO2, produces a unique and patented color effect in combination with Al flake pigments via Rayleigh light scattering. The potential for styling new “effect colors” has been investigated extensivley at BASF Corporation. Early feasibility and durability problems have been resolved with a better understanding of the mechanisms responsible for color effect and film degradation in sun light. Florida exposure data in both solventborne and waterborne coatings systems has shown this pigment to be very durable when used within certain formulating guide lines. Critical is the choice of pigment particle size and encapsulation chemistry. First used in 1989 in a color styled for the Ford Motor Company, production colors have expanded to other US and Japanese car manufacturers.

Fundamental understanding of the sources of fuel-derived Unburned Hydrocarbon (UHC) emissions in heavy duty diesel engines is a key piece of knowledge that impacts engine combustion system development. Current emissions regulations for hydrocarbons can be difficult to meet in-cylinder and thus after treatment technologies such as oxidation catalysts are typically used, which can be costly. In this work, Computational Fluid Dynamics (CFD) simulations are combined with engine experiments in an effort to build an understanding of hydrocarbon sources. In the experiments, the combustion system design was varied through injector style, injector rate shape, combustion chamber geometry, and calibration, to study the impact on UHC emissions from mixing-controlled diesel combustion.

Clutches are commonly utilised in passenger type and off-road heavy-duty vehicles to disconnect the engine from the driveline and other parasitic loads. In off-road heavy-duty vehicles, along with fuel efficiency start-up functionality at extended ambient conditions, such as low temperature and intake absolute pressure are crucial. Off-road vehicle manufacturers can overcome the parasitic loads in these conditions by oversizing the engine. Caterpillar Inc. as the pioneer in off-road technology has developed a novel clutch design to allow for engine downsizing while vehicle’s performance is not affected. The tribological behaviour of the clutch will be crucial to start engagement promptly and reach the maximum clutch capacity in the shortest possible time and smoothest way in terms of dynamics. A multi-body dynamics model of the clutch system is developed in MSC ADAMS. The flywheel is introducing the same speed and torque as the engine (represents the engine input to the clutch).

The effects of thermal and chemical aging on the performance of cordierite-based and high-porosity mullite-based diesel particulate filters (DPFs), were quantified, particularly their filtration efficiency, pressure drop, and regeneration capability. Both catalyzed and uncatalyzed core-size samples were tested in the lab using a diesel fuel burner and a chemical reactor. The diesel fuel burner generated carbonaceous particulate matter with a pre-specified particle-size distribution, which was loaded in the DPF cores. As the particulate loading evolved, measurements were made for the filtration efficiency and pressure drop across the filter using, respectively, a Scanning Mobility Particle Sizer (SMPS) and a pressure transducer. In a subsequent process and on a different bench system, the regeneration capability was tested by measuring the concentration of CO plus CO2 evolved during the controlled oxidation of the carbonaceous species previously deposited on the DPF samples.

Although soot-formation processes in diesel engines have been well characterized during the mixing-controlled burn, little is known about the distribution of soot throughout the combustion chamber after the end of appreciable heat release during the expansion and exhaust strokes. Hence, the laser-induced incandescence (LII) diagnostic was developed to visualize the distribution of soot within an optically accessible single-cylinder direct-injection diesel engine during this period. The developed LII diagnostic is semi-quantitative; i.e., if certain conditions (listed in the Appendix) are true, it accurately captures spatial and temporal trends in the in-cylinder soot field. The diagnostic features a vertically oriented and vertically propagating laser sheet that can be translated across the combustion chamber, where “vertical” refers to a direction parallel to the axis of the cylinder bore.

Mandated pollutant emission levels are shifting light-duty vehicles towards hybrid and electric powertrains. Heavy-duty applications, on the other hand, will continue to rely on internal combustion engines for the foreseeable future. Hence there remain clear environmental and economic reasons to further decrease IC engine emissions. Turbocharged diesels are the mainstay prime mover for heavy-duty vehicles and industrial machines, and transient performance is integral to maximizing productivity, while minimizing work cycle fuel consumption and CO2 emissions. 1D engine simulation tools are commonplace for “virtual” performance development, saving time and cost, and enabling product and emissions legislation cycles to be met. A known limitation however, is the predictive capability of the turbocharger turbine sub-model in these tools.

China has become the world’s largest vehicle market in terms of sales volume. Automobiles sales keep growing in recent years despite the declining economic growth rate. Due to the increasing attention given to the environmental impact, more stringent emission regulations are being drafted to control traditional internal combustion engine emissions. In order to reduce vehicle emissions, environmentally-friendly new-energy vehicles, such as electric vehicles and plug-in hybrid vehicles, are being promoted by government policies. The Chinese government plans to boost sales of new-energy cars to account for about five percent of China’s total vehicle sales. It is well known that more electric and electronic components will be integrated into a vehicle platform during vehicle electrification.

Fuel properties impact the engine-out emission directly. For some geographic regions where diesel engines can meet emission regulations without aftertreatment, the change of fuel properties will lead to final tailpipe emission variation. Aftertreatment systems such as Diesel Particulate Filter (DPF) and Selective Catalytic Reduction (SCR) are required for diesel engines to meet stringent regulations. These regulations include off-road Tier 4 Final emission regulations in the USA or the corresponding Stage IV emission regulations in Europe. As an engine with an aftertreatment system, the change of fuel properties will also affect the system conversion efficiency and regeneration cycle. Previous research works focus on prediction of engine-out emission, and many are based on chemical reactions. Due to the complex mixing, pyrolysis and reaction process in heterogeneous combustion, it is not cost-effective to find a general model to predict emission shifting due to fuel variation.

A heavy duty US 2010/Euro VI type emission control system typically consists of diesel oxidation catalyst (DOC), catalyzed soot filter (CSF), urea based selective catalytic NOx reduction (SCR) and NH3 slip control catalyst (AMOX - excluded for this study). The advent of the US 2014 Green House Gas (GHG) rules has established a limit for tailpipe N2O emissions for on-road heavy duty Diesel engines, thus creating new challenges for catalyst design and system/engine calibration. In this paper, we discuss the effects of both catalyst system design and engine calibration on the formation of N2O across SCR catalysts. This study consisted of system testing on engine, modeling and component reactor testing. These three tools were used to evaluate how NO2 to NOx ratio and ammonia to NOx ratio (ANR) affect N2O formation. The study showed that all of the reviewed factors affect tailpipe N2O emissions.

Catalytic converters have become a viable aftertreatment system for reducing emissions from on-highway diesel engines. This paper addresses the development and production qualification of a catalytic converter. The testing programs that were utilized to qualify the converter system for production included emissions performance, emissions durability, physical durability, and field test programs. This paper reports on the specific tests that were utilized for the emissions performance and emissions durability testing programs. An explanation on the development of an accelerated durability test program is also included. The physical durability section of the paper discusses the development and execution of laboratory bench tests to insure the catalytic converter/muffler maintains acceptable physical integrity.

An investigation has been carried out to examine the influence of up to 300 MPa injection pressure on engine performance and emissions. Experiments were performed on a 4 cylinder, 4 valve / cylinder, 4.5 liter John Deere diesel engine using the Ricardo Twin Vortex Combustion System (TVCS). The study was conducted by varying the injection pressure, Start of Injection (SOI), Variable Geometry Turbine (VGT) vane position and a wide range of EGR rates covering engine out NOx levels between 0.3 g/kWh to 2.5 g/kWh. A structured Design of Experiment approach was used to set up the experiments, develop empirical models and predict the optimum results for a range of different scenarios. Substantial fuel consumption benefits were found at the lowest NOx levels using 300 MPa injection pressure. At higher NOx levels the impact was nonexistent. In a separate investigation a Cambustion DMS-500 fast particle spectrometer, was used to sample and analyze the exhaust gas.

A slipstream of exhaust from a Caterpillar 3126B engine was diverted into a plasma-catalytic NOx control system in the space velocity range of 7,000 to 100,000 hr-1. The stream was first fed through a non-thermal plasma that was formed in a coaxial cylinder dielectric barrier discharge reactor. Plasma treated gas was then passed over a catalyst bed held at constant temperature in the range of 573 to 773 K. Catalysts examined consisted of γ-alumina, indium-doped γ-alumina, and silver-doped γ-alumina. Road and rated load conditions resulted in engine out NOx levels of 250 - 600 ppm. The effects of hydrocarbon level, catalyst temperature, and space velocity are discussed where propene and in one case ultra-low sulfur diesel fuel (late cycle injection) were the reducing agents used for NOx reduction. Results showed NOx reduction in the range of 25 - 97% depending on engine operating conditions and management of the catalyst and slipstream conditions.

Polyurethane dispersions (PUDs) have seen rapid growth in recent years as alternatives to their solvent-based analogs. They offer the advantages of enabling low VOC formulations while providing superior appearance and mechanical properties. Polyurethane-acrylic hybrids combine the advantages of a polyurethane dispersion with the benefits of an acrylic emulsion. This synergistic combination offers properties such as good hardness development and chemical resistance in addition to enhanced mechanical properties. In this paper, we discuss new PUD-acrylic hybrids that are NMP and solvent-free, have a pendulum hardness of 100 oscillations compared to a standard acrylic emulsion that has 80; and offer excellent scratch and chemical resistance equivalent to that of an acrylic system. In addition to these, the new polyurethane dispersions provide good haptic qualities and have excellent adhesion to plastic substrates such as ABS, PC and PVC.

Regulated and unregulated emissions (individual hydrocarbons, ethanol, aldehydes and ketones, polynuclear aromatic hydrocarbons (PAH), nitro-PAH, and soluble organic fraction of particulate matter) were characterized in engines utilizing duplicate ISO 8178-C1 eight-mode tests and FTP smoke tests. Certification No. 2 diesel (400 ppm sulfur) and three ethanol/diesel blends, containing 7.7 percent, 10 percent, and 15 percent ethanol, respectively, were used. The three, Tier II, off-road engines were 6.8-L, 8.1-L, and 12.5-L in displacement and each had differing fuel injection system designs. It was found that smoke and particulate matter emissions decreased with increasing ethanol content. Changes to the emissions of carbon monoxide and oxides of nitrogen varied with engine design, with some increases and some decreases. As expected, increasing ethanol concentration led to higher emissions of acetaldehyde (increases ranging from 27 to 139 percent).

Various gold catalysts were prepared using commercial and in-house fabricated advanced catalyst supports that included mesoporous silica, mesoporous alumina, sol-gel alumina, and transition metal oxides. Gold nanoparticles were loaded on the supports by co-precipitation, deposition-precipitation, ion exchange and surface functionalization techniques. The average gold particle size was ∼20nm or less. The oxidation activity of the prepared catalysts was studied using carbon monoxide and light hydrocarbons (ethylene, propylene and propane) in presence of water and CO2 and the results are presented.

Diesel engine downsizing aimed at reducing fuel consumption while meeting stringent exhaust emissions regulations is currently in high demand. The boost system architecture plays an essential role in providing adequate air flow rate for diesel fuel combustion while avoiding impaired transient response of the downsized engine. Electric Turbocharger Assist (ETA) technology integrates an electric motor/generator with the turbocharger to provide electrical power to assist compressor work or to electrically recover excess turbine power. Additionally, a variable geometry turbine (VGT) is able to bring an extra degree of freedom for the boost system optimization. The electrically-assisted turbocharger, coupled with VGT, provides an illuminating opportunity to increase the diesel engine power density and enhance the downsized engine transient response. This paper assesses the potential benefits of the electrically-assisted turbocharger with VGT to enable heavy-duty diesel engine downsizing.