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Controlling start of ignition in Homogenous Charge Compression Ignition (HCCI) engines remains a major challenge. Here we have investigated changes in intake charge composition and its effects on ignition delay for natural gas based HCCI engine operation. In particular, we have investigated the effects of small amounts of nitrogen dioxide (NO2) on operating characteristics. Previous research had shown that NOx presence might attenuate natural gas ignition. The hypothesized catalytic effect of NOx on methane ignition at HCCI conditions was experimentally confirmed in a custom built engine. The problem was further studied in both zero and multidimensional numerical engine simulations with detailed chemistry. The simulations were used to complete a reaction rate sensitivity analysis to elucidate the controlling chemistry, and further confirm that a significant shift in ignition phasing is produced with the addition of just several ppm by volume of NO2 or NOx (NO + NO2).

This paper examines the effect of charge cooling on the Research Octane Number (RON) of ethanol/gasoline blends. While gasoline is fully vaporized prior to entry into the engine in a standard RON test, significant charge cooling is observed for blends with high ethanol content, with the presence of a near-saturated and potentially two-phase air-fuel mixture during induction. Thus, the relative significance of the charge cooling and the autoignition chemistry cannot be determined from the standard RON test. In order to better delineate the effects of charge cooling and autoignition chemistry, a so-called ‘modified RON’ test is therefore devised in which the temperature of the air-fuel mixture entering the engine is fixed and representative of that observed for primary reference fuels (PRFs).

This paper describes two independent studies on γ-alumina as a plasma-activated catalyst. γ-alumina (2.5 - 4.3 wt%) was coated onto the surface of mesoporous silica to determine the importance of aluminum surface coordination on NOx conversion in conjunction with nonthermal plasma. Results indicate that the presence of 5- and 6- fold aluminum coordination sites in γ-alumina could be a significant factor in the NOx reduction process. A second study examined the effect of changing the reducing agent on NOx conversion. Several hydrocarbons were examined including propene, propane, isooctane, methanol, and acetaldehyde. It is demonstrated that methanol was the most effective reducing agent of those tested for a plasma-facilitated reaction over γ-alumina.

It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil-derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter.

This paper features an application study on the impact of different blend levels of commercially-supplied biodiesel on engine and aftertreatment systems' durability and reliability as well as the impact on owning and operating factors: service intervals and fuel economy. The study was conducted on a bus application with a 2007 on highway emissions equipped engine running biodiesel blends of B5, B20, and B99 for a total period approaching 4500 hours. Biodiesel of waste cooking grease feedstock was used for the majority of the testing, including B5 and B20 blends. Biodiesel of soybean feedstock was used for testing on B99 blend. No negative impacts on engine and aftertreatment performance and durability or indication of future potential issues were found when using B5 and B20. For B99 measurable impacts on engine and aftertreatment performance and owning and operating cost were observed.

Natural gas quality, in terms of the volume fraction of higher hydrocarbons, strongly affects the auto-ignition characteristics of the air-fuel mixture, the engine performance and its controllability. The influence of natural gas composition on engine operation has been investigated both experimentally and through chemical kinetic based cycle simulation. A range of two component gas mixtures has been tested with methane as the base fuel. The equivalence ratio (0.3), the compression ratio (19.8), and the engine speed (1000 rpm) were held constant in order to isolate the impact of fuel autoignition chemistry. For each fuel mixture, the start of combustion was phased near top dead center (TDC) and then the inlet mixture temperature was reduced. These experimental results have been utilized as a source of data for the validation of a chemical kinetic based full-cycle simulation.

Ethanol and other high heat of vaporization (HoV) fuels result in substantial cooling of the fresh charge, especially in direct injection (DI) engines. The effect of charge cooling combined with the inherent high chemical octane of ethanol make it a very knock resistant fuel. Currently, the knock resistance of a fuel is characterized by the Research Octane Number (RON) and the Motor Octane Number (MON). However, the RON and MON tests use carburetion for fuel metering and thus likely do not replicate the effect of charge cooling for DI engines. The operating conditions of the RON and MON tests also do not replicate the very retarded combustion phasing encountered with modern boosted DI engines operating at low-speed high-load. In this study, the knock resistance of a matrix of ethanol-gasoline blends was determined in a state-of-the-art single cylinder engine equipped with three separate fuel systems: upstream, pre-vaporized fuel injection (UFI); port fuel injection (PFI); and DI.

The objective of this study was to quantify the effect of pilot fuel injection on engine-out emissions of potentially toxic compounds from a modern diesel engine operated with different fuels including 15% v/v dimethoxy methane in a low-sulfur diesel fuel. Five diesel fuels were examined: a low-sulfur (∼1 ppm), low aromatic, hydrocracked fuel, the same low-sulfur fuel containing 15% v/v dimethoxy methane, a Fischer-Tropsch fuel, a California reformulated fuel, and a EPA number 2 certification fuel. A DaimlerChrysler OM611 CIDI engine was controlled with a SwRI Rapid Prototyping Electronic Control system. The pilot fuel injection was either turned off or turned on with engine control by either Location of Peak Pressure (LPP) of combustion or the original equipment manufacturer (OEM) calibration strategy. These three control strategies were compared over 2 speed-load modes run in triplicate. Thirty-three potentially toxic compounds were measured.

A weighted composite of four engine-operating modes, representative of typical operating modes found in the US FTP driving schedule, were used to compare engine-out emissions of toxic compounds using five diesel fuels. The fuels examined were: a low-sulfur low-aromatic hydrocracked diesel fuel, the same low-sulfur fuel containing 15% v/v dimethoxy methane, a Fischer-Tropsch fuel, a CARB fuel, and a EPA number 2 diesel certification fuel. A DaimlerChrysler OM611 CIDI engine was operated over 4 speed-load modes: mode 5, 2600 RPM, 8.8 BMEP; mode 6, 2300 RPM, 4.2 BMEP; mode 10, 2000 RPM, 2.0 BMEP; mode 11, 1500 RPM, 2.6 BMEP. The four engine operating modes were weighted as follows: mode 5, 25/1200; mode 6, 200/1200; mode 10, 375/1200; and mode 11, 600/1200. Each operating mode and fuel combination was run in triplicate.

The objective of this study was to quantify engine-out emissions of potentially toxic compounds from a modern diesel engine operated with different fuels including 15% v/v dimethoxy methane in a low sulfur diesel fuel. Five diesel fuels were examined: a low-sulfur, low-aromatic hydrocracked (∼1 ppm) fuel, the same low sulfur fuel containing 15% v/v dimethoxy methane, a Fischer-Tropsch fuel, a CARB fuel, and an EPA number 2 certification fuel. A DaimlerChrysler OM611 CIDI engine was controlled with a SwRI Rapid Prototyping Electronic Control system. The engine was operated over 4 speed-load modes. Each operating mode and fuel combination was run in triplicate. Thirty three potentially toxic compounds were measured for each fuel and mode.

The influence of the addition of oxygenated hydrocarbons to diesel fuels has been studied, using a detailed chemical kinetic model. Resulting changes in ignition and soot precursor production have been examined. N-heptane was used as a representative diesel fuel, and methanol, ethanol, dimethyl ether, dimethoxymethane and methyl butanoate were used as oxygenated fuel additives. It was found that addition of oxygenated hydrocarbons reduced the production of soot precursors. When the overall oxygen content in the fuel reached approximately 30-40 % by mass, production of soot precursors fell effectively to zero, in agreement with experimental studies. The kinetic factors responsible for these observations are discussed.

In July 1997, the Pacific Northwest and Alaska Regional Bioenergy Program, in cooperation with several industrial and institutional partners initiated a long-haul 322,000 km (200,000 mile) operational demonstration using a biodiesel and diesel fuel blend in a 324 kW (435 HP), Caterpillar 3406E Engine, and a Kenworth Class 8 heavy duty truck. This project was designed to: develop definitive biodiesel performance information, collect emissions data for both regulated and non-regulated compounds including mutagenic activity, and collect heavy-duty operational engine performance and durability information. To assess long-term engine durability and wear; including injector, valve and port deposit formations; the engine was dismantled for inspection and evaluation at the conclusion of the demonstration. The fuel used was a 50% blend of biodiesel produced from used cooking oil (hydrogenated soy ethyl ester) and 50% 2-D petroleum diesel.