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A laboratory wear test is used to evaluate the wear protection properties of new and used engine oils formulated for FFV service. Laboratory-blended mixtures of these oils with methanol and water have also been tested. The test consists of a steel ball rotating against three polished cast iron discs. Oil samples are obtained at periodic intervals from a fleet of 3.0L Taurus vehicles operating under controlled go-stop conditions. To account for the effects of fuel dilution, some oils are tested before and after a stripping procedure to eliminate gasoline, methanol and other volatile components. In addition to TAN and TBN measurements, a capillary electrophoresis technique is used to evaluate the formate content in the oils. The results suggest that wear properties of used FFV lubricants change significantly with their degree of usage.

Rheological measurements were performed on a series of lubricants for flexible fuel vehicles, and blends of water or methanol in these oils. A series of measurements, including kinematic viscosity, viscosity at low and high shear rates, low shear viscosity under borderline pumping conditions, and density were performed on all oils and blends. The effects of mixing conditions, such as mixing speed and temperature on these properties were also studied. Viscosity increases when water emulsifies in oils. Methanol exhibits limited solubility in all oils, but more so in synthetic base oils. Viscosity tests at 248 K (-25°C) do not indicate the onset of critical pumping conditions, even at high concentrations of water or methanol. Tests at high shear rates at 323 K (50°C) suggest that water-oil emulsions are quite stable, while methanol-oil blends lose their methanol content either due to evaporation or shear-induced separation.