Search Results

Engine oils and their additives are formulated to meet required performance areas such as lubrication, detergency, dispersancy, anti-wear, and so on. Understanding degradation of engine oil additives is important to formulate oils with long time durability. Engine oil additives have been found to affect abnormal combustion in turbocharged gasoline direct injection (TGDI) engines, called low speed pre-ignition (LSPI). Some of metal containing additives such as zinc dithiophosphates (ZnDTP) and molybdenum dithiocarbamates (MoDTC) have been found to reduce LSPI events. In this study, we investigated degradation of ZnDTP and MoDTC in gasoline engine operation and effects of the degradation on LSPI performance.

The continued rise in specific power output and thermal loading characteristics of the modern automotive diesel engine provides piston engineers and scientists with the challenge of continually improving their knowledge and understanding of thermomechanical loading and durability factors. The capacity to predict thermomechanical fatigue (TMF) effects with confidence at a pre-engineering stage will improve the technology selection and component design processes leading to a more efficient development phase. This paper reviews how the use of advanced instrumented engine testing and finite element modeling (FEM) techniques are helping engineers improve their understanding of transient thermal load regimes in automotive AlSiCuNiMg pistons. The investigations offer insightful observation of transient measured piston temperatures in the high and low frequency operating regimes for two diesel engine platforms.

Control and elimination of mobil-source particulate matter (PM) emissions is of increasing interest to engineers and scientists as regulators in industrialized countries promulgate lower emission levels in diesel engines. Relative to their gasoline engine counterparts, today's diesel engines, in general, still emit a higher mass of PM. While strictly speaking, this PM is an agglomeration of organic and inorganic particles, the predominant component is carbon and is commonly referred to as “soot”. For mobil-source PM control, one of the current preferred technologies is the ceramic closed-cell monolith Diesel Particulate Filter (DPF). Ideally, DPFs accumulate and store PM during low speed/temperature engine operation and burn the accumulated PM during high speed/temperature operation.

The heightened interest level in Fuel Economy for Heavy Duty Diesel Engines the industry has seen over the last few years continues to be high, and is not likely to change. Lowering the fuel consumption of all internal combustion engines remains a priority for years to come, driven by economic, legislative, and environmental reasons. While it is generally assumed that lower viscosity grade lubricants offer fuel economy benefits, there is a lot of confusion about exactly what drives the fuel economy benefits. Fuel Economy claims in trade literature vary over a broad range and it is difficult for the end user to determine what to expect when a change in lubricant viscosity is adopted for a fleet of vehicles in a certain type of operation. This publication makes an attempt at clarifying a number of these uncertainties with the help of additional engine test data, and more extensive data analysis.

The effects of fuel composition and engine operating parameters on high-pressure, direct injection gasoline (DIG) injector plugging and deposit formation have been studied. The engine used was a conventional dual-sparkplug, 2.2-liter Nissan engine modified for direct injection using one of the spark plug holes. The engine was run under 20% rich conditions to accelerate deposit formation. A ten-fuel test matrix was designed around T90, sulfur level, and olefin levels indicated in the European gasoline specifications for year 2000. The gasolines, containing no detergents, were formulated using refinery stream blends to match the specified targets. Injector flow loss was monitored by fuel flow to the engine and monitoring oxygen sensors on each of the four cylinders. The impact of fuel composition on deposit formation and injector plugging is discussed. Injector flow loss was strongly influenced by injector tip temperature.

This paper presents the findings of some fundamental characterisation of the deposits that form on the injectors of an air-assisted DISI automotive engine, including the effect of these deposits on engine performance when operated in different combustion modes, with varying fuel composition and additive content. A root cause analysis was undertaken, including an assessment of injector temperature and deposit chemistry. Fuels from a matrix designed around the European year 2000 gasoline specifications for T90, olefin and aromatic levels were used to study the effect of fuel composition on deposit formation. Two commercial gasoline detergent additives, of different chemistries, were used to investigate the impact on deposit formation. The results of the fuels study and deposit analysis are consistent with published theories concerning fuel composition impact on combustion chamber deposit (CCD).

A new casting process has been developed for the widely-used unplated aluminum-lead passenger car engine bearing alloy A1-6Pb-4Si. This new process, which imparts a very high quench rate to the alloy, results in a much finer metallurgical structure as compared to the current product. The fine structure is responsible for a significant improvement in bearing fatigue life. Data are presented which demonstrate this improvement both in dynamometer engine testing and in fatigue test machines. Score-seizure testing shows no loss in anti-seizure properties.

In this study, a green process was developed to synthesize a novel molybdenum disulfide (MoS₂)-based friction modifier (FM) for improving fuel economy performance of lubricants. These new materials were synthesized using less hazardous elemental sulfur as opposed to other sulfur sources like hydrogen sulfide (H₂S) and carbon disulfide (CS₂). Using various bench and motoring friction torque tests, it was shown that friction reduction was benefited by utilizing low molecular weight organic backbone when designing molybdenum FMs. Also, it was shown that newly synthesized molybdenum-based FMs were comparable to other well-known MoS₂ precursors.

A range of tools including analytical, bench, and engine tests have been used to investigate the viscosity increase mechanism and formulation appetite of the Sequence IIIG engine test. As commonly observed with high temperature tests, the Sequence IIIG has a strong appetite for antioxidants. Base oil also has a strong impact. Base oil volatility has a direct physical impact on viscosity due to the evaporation of light base oil components and the resultant increase of non-volatile additive components. Volatility characteristics are dependent on the distribution of volatile fractions. The relative oxidation and volatility contributions to viscosity increase have been compared between the Sequence IIIG and Sequence IIIF. The impact of base oil volatility is greater in the Sequence IIIG than the Sequence IIIF test.

A powder forged connecting rod has been developed by Federal-Mogul for use as a direct replacement in a General Motors V8 engine. Design modifications have facilitated the powder forging process, while maintaining the critical geometric and mass balance requirements of the existing rod. The powder forged connecting rod design was tested in a tension/compression, axial fatigue test. An electromagnetic resonance (EMR) test machine was employed. As a reference, current production General Motors rods were tested under similar conditions. The results indicate that the powder forged rods show improved fatigue life to that of the wrought rods at an elevated test load.

By 2014, all new on- and off-highway diesel engines in North America, Europe and Japan will employ diesel particulate filters (DPF) in the exhaust in order to meet particulate emission standards. If the pressure across the DPF increases due to incombustibles remaining after filter regeneration, the exhaust backpressure will increase, and this in turn reduces fuel economy and engine power, and increases emissions. Due to engine oil consumption, over 90% of the incombustibles in the DPF are derived from inorganic lubricant additives. These components are derived from calcium and magnesium detergents, zinc dithiophosphates (ZnDTP) and metal-containing oxidation inhibitors. They do not regenerate as they are non-volatile metals and salts. Consequently, the DPF has to be removed from the vehicle for cleaning. Ashless oil could eliminate the need for cleaning.

The Sequence IIIG is a newly developed 100 hour test used to evaluate the performance of crankcase engine oils in the areas of high temperature viscosity increase, wear, deposits, pumpability, and ring sticking for the North American GF-4 standard. Data from the ASTM Precision Matrix, completed in the spring of 2003, along with early reference data from the Lubricant Test Monitoring System (LTMS) showed unexpected test results for selected oils and indicated that percent viscosity increase and pumpability were highly correlated with oil consumption. This correlation led to an intensive study of the factors that influence oil consumption and an attempt to compensate for non-oil related oil consumption through a model based adjustment of the results. The study and scrutiny of the IIIG data has led to more uniform oil consumption in the test and improved test precision, and has eliminated the need for a correction equation based on non-oil related oil consumption.

Several makes and models of cars were modified for lean-burn operation using the Turbulent Flow Manifold (TFM), a unique intake manifold that provides improved preparation and distribution of the fuel-air mixture. Operation of the TFM is described, and exhaust emissions and fuel economy data are presented for the various cars. Exhaust port liners and thermal reactors were shown to be effective devices for reducing emissions from the basic lean-burn system. One car equipped with the TFM, port liners, and reactors was operated for 50,000 miles on an EPA-type durability test and had emissions well below the 1975 standards for California. Emissions, fuel economy, and durability data are presented.

Modern Passenger Car Motor Oils (PCMOs) are formulated to provide superior wear, oxidation, and deposit control under the most demanding driving conditions. In most PCMOs, zinc dialkyldithiophosphate (ZnDTP) has been the dominant antiwear and antioxidant agent for well over 50 years. Unfortunately, the phosphorus in ZnDTP may partially deactivate the exhaust emission catalyst. To ensure that the catalysts function for at least 120,000 miles, engine manufacturers are exploring phosphorus limitations for upcoming PCMO performance categories. This paper explores the antiwear film formation of low phosphorus engine oils using the Electrical Contact Resistance bench test. A prototype ILSAC GF-4 formulation blended with varying amounts and types of ZnDTP was tested at temperatures typical of operating engines. Secondary ZnDTP was found to produce the best films under the broadest temperature range.

Emissions regulations for 2007 will likely require engine manufacturers to use a diesel particulate filter (DPF) to meet particulate matter (PM) emission requirements. With the lower operating temperatures of light-duty diesel engines, some form of catalyst will be required to facilitate oxidation of accumulated soot PM to regenerate the DPF. This catalyst can either be permanently applied to the filter substrate in the manufacturing process, or be continuously delivered via the diesel fuel. In this study we examined the impact of using both forms of catalyst. A recently published study of the fuel-borne catalyst additive MMT [1] (Methylcyclopentadienyl Manganese Tricarbonyl), reviewed the performance of MMT in conjunction with an uncatalyzed DPF [2].

The fuel economy performance of passenger car vehicles has been an area of keen focus due to recent environmental regulations. Various efforts such as the development of new engine technologies have been undertaken to improve the fuel economy performance of these vehicles. Engine oils have also been targeted to contribute to better fuel efficiency. This has been done by introducing new lubricant additive technologies and low viscosity grade oils. In the latter case, passenger car motor oils are about to enter into a new generation in which the lower viscosity grade SAE 16 has been approved and discussion has started on the specification of viscosity grades lower than SAE 16, although SAE 0W-20 viscosity grade is the lowest in the SAE J300 specification during last decade. Nevertheless, additive technology is also important, as we previously reported that simple reduction of viscosity grade is not a solution to improve fuel economy performance in the Sequence VID test.

The Ethanol-Boosted Direct Injection (EBDI) demonstrator engine is a collaborative project led by Ricardo targeted at reducing the fuel consumption of a spark-ignited engine. This paper describes the design challenges to upgrade an existing engine architecture and the synergistic use of a combination of technologies that allows a significant reduction in fuel consumption and CO₂ emissions. Features include an extremely reduced displacement for the target vehicle, 180 bar cylinder pressure capability, cooled exhaust gas recirculation, advanced boosting concepts and direct injection. Precise harmonization of these individual technologies and control algorithms provide optimized operation on gasoline of varying octane and ethanol content.

Additive control of DIG injector coking was investigated on two dynamometer-operated engines and validated in a vehicle. The first engine was a Nissan research “mule” engine designed to severely coke the injectors so that additive effect could be more easily discriminated. Initial additive screening and optimization was carried out in this engine and a few chosen candidates of the Mannich chemistry-type were further optimized in the second engine, and in a vehicle. The second engine, which was also dynamometer operated, was an advanced wall-guided design capable of both homogeneous and stratified operation. On this engine we were able to optimize the Mannich additive “Man C-2” separately in two different carrier systems to show a carrier effect, and by manipulating the purity of the base detergent Man C-2 to show a detergent activity modulation by trace co-products.

The temporal and spatial evolution of the ignition and premixed-burn phases of a direct-injection (DI) diesel spray were investigated under quiescent conditions. The diagnostics used included temporally resolved measurements of natural light emission and pressure, and spatially resolved images of natural light emission. Temporally resolved natural light emission measurements were made with a photo-multiplier tube and a photodiode, while the images were acquired with an intensified CCD camera. The experiments were conducted in an optically accessible, constant-volume combustion vessel over a range of ambient gas temperatures and densities: 800-1100 K and 7.3-45.0 kg/m3. The fuel used was a ternary blend of single-component fuels representative of diesel fuel with a cetane number of 45. The fuel was injected with a common-rail injector at high pressure (140 MPa). The results provide new information on the evolution of the two-stage ignition/premixed-burn phases of DI diesel sprays.

More stringent emission legislation has been a driver for changes in the design of Heavy Duty Diesel engines since the 1980s. Significant gains have been made over the years but, in 2007 and again in 2010, diesel engines in North America will have to meet even more stringent requirements for particulate matter and nitrogen oxide emissions. A reduction of the sulfur level in diesel fuel to a maximum of 15 mg/kg has been mandated as an enabler for new diesel engine exhaust gas after-treatment systems. Many studies have been published on the impact of the use of low sulfur diesel fuel. The focus of most of these studies has been on the possible impact on exhaust gas after-treatment system durability, but little has been documented on lubricant degradation and on the long term impact on engine durability. The objectives of the field test discussed in this paper were to evaluate the impact of low sulfur fuel and of a reduction in the TBN of the lubricant on lubricant degradation.