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This paper explores the extent to which standard dilution tunnel measurements of motor vehicle exhaust particulate matter modify particle number and size. Steady state size distributions made directly at the tailpipe, using an ejector pump, are compared to dilution tunnel measurements for three configurations of transfer hose used to transport exhaust from the vehicle tailpipe to the dilution tunnel. For gasoline vehicles run at a steady 50 - 70 mph, ejector pump and dilution tunnel measurements give consistent results of particle size and number when using an uninsulated stainless steel transfer hose. Both methods show particles in the 10 - 100 nm range at tailpipe concentrations of the order of 104 particles/cm3.

As vehicle tailpipe emission levels decrease with improvements in emission control technology and reformulation of gasolines, exhaust hydrocarbon levels begin to approach the levels in ambient air. Hydrocarbon speciation at these low levels requires high sensitivity capillary gas chromatography methods. In this study, a mixture of “synthetic” exhaust was prepared at two concentration levels (approximately 5 ppm C and 10 ppm C), and was analyzed by the widely-used Auto/Oil Air Quality Improvement Research Program (AQIRP) Phase II (gas chromatography) speciation method with a sensitivity of 0.005 ppm C for individual species. The mixture at each concentration level, along with a sample of ambient air, was analyzed a total of 20 times on 10 separate days over a 2½ week period. Concentrations of total hydrocarbons (HCs) and individual species (using the AQIRP library) were measured; averages and standard deviations were calculated.

The feasibility of using experimentally determined flow fields at intake valve closing, IVC, as initial conditions for computing the in-cylinder flow dynamics during the compression stroke is demonstrated by means of a computer simulation of the overall approach. A commercial CFD code, STAR-CD, was used for this purpose. The study involved two steps. First, in order to establish a basis for comparison, the in-cylinder flow field throughout the intake and compression strokes, from intake valve opening, IVO, to top dead center, TDC, was computed for a simple engine geometry. Second, experimental initial conditions were simulated by randomly selecting and perturbing a set of velocity vectors from the computed flow field at IVC.

The change in the resistance of titanium dioxide with oxygen partial pressure is utilized to obtain an air-to-fuel ratio sensor. TiO2 material properties, sensor components and performance characteristics are discussed. Some results of engine dynamometer and vehicle tests of sensor performance and durability are presented.

In this study, the particle emission characteristics of 10% alternative diesel fuel blends (Rapeseed Methyl Ester and Gas-to-Liquid) were investigated through the tests carried out on a light duty common-rail Euro 4 diesel engine. Under steady engine conditions, the study focused on particle number concentration and size distribution, to comply with the particle metrics of the European Emission Regulations (Regulation NO 715/2007, amended by 692/2008 and 595/2009). The non-volatile particle characteristics during the engine warming up were also investigated. They indicated that without any modification to the engine, adding selected alternative fuels, even at a low percentage, can result in a noticeable reduction of the total particle numbers; however, the number of nucleation mode particles can increase in certain cases.

Speciation of sulfurous acid, sulfuric acid and ammonium sulfate collected from the aerosol phase on a Fluoropore filter has been readily accomplished using techniques of chemical ionization mass spectrometry combined with thermal separation. Thermal separation of ammonium hydrogen sulfate from ammonium sulfate was not possible. Spectral separation of these species by selective ionization is proposed. Analysis of sulfate aerosols collected from ambient air and catalyzed vehicle emissions is described. It was found that sulfuric acid aerosol was rapidly converted to ammonium sulfate or ammonium hydrogen sulfate in the presence of ambient concentrations of ammonia. Ambient samples collected in the Detroit metropolitan area have been found to contain only trace quantities of sulfuric aicd. Sulfate samples collected from a dilution tube into which catalyzed vehicle exhaust was injected were found to contain significant quantities of ammonium sulfate in addition to sulfuric acid.

Gas carburized and quenched low alloy steels typically produce surface microstructures which contain martensite, retained austenite and often NMTP's (non-martensitic transformation products). The NMTP's are caused by a reduction of surface hardenability in the carburizing process from loss of alloying elements to oxidation. Gas carburized low alloy steels such as SAE 8620 with NMTP's on the surface have been shown to have inferior bending fatigue properties when compared to more highly alloyed steels which do not form NMTP's, such as SAE 4615M. One method of minimizing the formation of oxides and eliminating NMTP formation during carburizing and quenching is to use plasma carburizing instead of conventional gas carburizing. In this study the microstructures and bending fatigue performance of plasma carburized SAE 8620 and SAE 4615M is compared to the same alloys conventionally gas carburized and quenched.

New European emissions legislation (Euro5) specifies a limit for Particle Number (PN) emissions and therefore drives measurement of PN during vehicle development and homologation. Concurrently, the use of biofuel is increasing in the marketplace, and Euro5 specifies that reference fuel must contain a bio-derived portion. Work was carried out to test the effect of fuels containing different levels of Fatty Acid Methyl Ester (FAME) on particle number, size, mass and composition. Measurements were conducted with a Cambustion Differential Mobility Spectrometer (DMS) to time-resolve sub-micron particles (5-1000nm), and a Horiba Solid Particle Counting System (SPCS) providing PN data from a Euro5-compliant measurement system. To ensure the findings are relevant to the modern automotive business, testing was carried out on a Euro4 compliant passenger car fitted with a high-pressure common-rail diesel engine and using standard homologation procedures.

The Ford PROCO stratified charge engine combines the desirable characteristics of premixed charge and Diesel engines. The outstanding characteristics of premixed charge engines are their high specific output, wide speed range, light weight and easy startability but they exhibit only modest fuel economy and relatively high exhaust emissions. The desirable characteristic of the Diesel engine is its outstanding fuel economy. However, the disadvantages of the Diesel, which include noisy operation, limited speed range, exhaust odor, smoke, hard startability, and particulate emissions have tended to limit their acceptance. In the gasoline fueled, PROCO stratified charge engine, direct cylinder fuel injection permits operation at overall lean mixture ratios and higher compression ratio. These features enable the PROCO engine to achieve brake specific fuel consumption values in the range of prechamber diesel engines.

Erosion damage to automotive car bodies caused by stones and small sand particles and road debris significantly affects the appearance of paint. Painted engineering plastics as well as precoated sheet steel are affected by erosion phenomenon. Erosion of painted plastic substrates results in cosmetic concerns while that on metal substrates results in cosmetic to perforation corrosion. This work describes a laboratory simulation of erosion of painted plastic substrates by small particles on various paint and substrate types. Gloss loss was used to quantitatively evaluate erosion of painted surfaces. Wear behavior of painted plastic substrates to slag sand impact was evaluated as a function of several variables including paint type (one-component melamine crosslinked (1K) vs. two-component isocyanate crosslinked (2K)), thermal history, and coating modulus. The effect of slag sand type (particle size and chemical composition) was studied.

Vehicle emissions have been measured and the results statistically evaluated for a vehicle test fleet consisting of four Escorts and four Explorers using both a fully formulated durability fuel doped with methylcyclopentadienyl manganese tricarbonyl (MMT) at 1/32 gram Mn/gallon and the same fully formulated durability fuel without the MMT. The fleet was divided in half -- half with MMT and half without MMT doped fuel. This report covers emission measurement results at 5,000; 15,000; 50,000 and 100,000 miles of exposure to MMT doped fuel. A modified paired t-test is used to analyze the emission data obtained from all the fleet vehicles. The statistical evaluation of both feedgas and tailpipe emissions indicate that the use of MMT is detrimental to emissions of HC at the 15,000 mile; 50,000 mile and 100,000 mile levels of MMT exposure. As mileage is accumulated, the pronounced the effect on HC by the fuel additive MMT.

A number of tests were conducted on a 2.5 litre, high-speed, direct-injection diesel engine running at various loads and speeds. The aim of the tests was to gain understanding which would lead to more effective use of exhaust gas recirculation (EGR) for controlling exhaust NOx whilst minimising the penalties of increased smoke emission and fuel consumption. In addition to exhaust emission measurements, in-cylinder sampling of combustion gases was carried out using a fast-acting, snatch-sampling valve. The results showed that the effectiveness of EGR was enhanced considerably by cooling the EGR. In addition to more effective NOx control, this measure also improved volumetric efficiency which assisted in the control of smoke emission and fuel consumption. This second of two papers on the use of EGR in diesel engines deals with the effects of EGR on soot emission and on the engine fuel economy.

A number of tests were conducted on a 2.5 litre, high-speed, direct-injection diesel engine running at various loads and speeds. The aim of the tests was to gain understanding which would lead to more effective use of exhaust gas recirculation (EGR) for controlling exhaust NOx. In addition to exhaust emission measurements, extensive in-cylinder sampling of combustion gases was carried out using a fast-acting, snatch-sampling valve. The results showed that the effectiveness of EGR in suppressing NOx was enhanced considerably by intercooling the inlet charge and by cooling the EGR. A companion paper (SAE 960841) deals with the effects of EGR on soot formation and emission [1].

The paper reviews our problems of energy availability in the middle and long-term future as well as our problems of environmental pollution and materials availability. Against this background the ceramic gas turbine engine is examined and shown to have potential as an attractive candidate powerplant for both the middle and long-term future. The paper reports on Ford's ceramic gas turbine program which is a systems development program encompassing all aspects of turbine ceramics technology---design, materials, fabrication processes, testing and evaluation.

Automotive three-way catalysts (TWC) were characterized using temperature-programmed reduction (TPR), x-ray diffraction (XRD), Raman spectroscopy, chemisorption measurements and laboratory activity measurements. Capabilities and limitations of these standard analytical techniques for the characterization of production-type automotive catalysts are pointed out. With the exception of chemisorption techniques, all appear to have general utility for analyzing exhaust catalysts. The techniques were used to show that the noble metals and ceria in fresh Pt/Rh and Pd/Rh catalysts are initially highly dispersed and contain a mixture of interacting and non-interacting species. Thermal aging of these catalysts (in the reactor or vehicle) caused both precious metal and ceria particles to sinter, thereby decreasing the interaction between the two.

A small-bore 4-stroke single-cylinder stratified-charge DISI engine using an air-forced fuel injection system has been designed and tested under various operating conditions. At light loads, fuel consumption was improved by 16∼19% during lean, stratified-charge operation at an air-fuel ratio of 37. NOx emissions, however, were tripled. Using EGR during lean, stratified-charge operation significantly reduced NOx emissions while fuel consumption was as low as the best case without EGR. It was also found that combustion and emissions near the lean limit were a strong function of the combination of injection and spark timings, which affect the mixing process. Injection pressure, air injection duration, and time delay between fuel and air injections also played a role. Generating in-cylinder air swirl motion slightly improved fuel economy.

A study has been conducted to measure the particle number emissions from a current-generation 1.6-liter, Euro IV-compliant turbo-charged Gasoline Direct Injection (GDI) passenger car engine. A fast-response particle size spectrometer was used along with a PMP-compliant particulate measurement system to measure the effect of various engine parameters on the particulate emissions during the New European Drive Cycle (NEDC). Overall particle number is shown along with further analysis of the transient particle emissions. The cold start clearly affects particle formation with approximately 50% of the cumulative particle number being emitted within 200 seconds of the start. Even beyond 200 seconds, the particle number emissions fall as the test progresses and are generally consistent with increases in engine coolant temperature indicating that cold engine fuel preparation issues are contributing to the particle number count.

Results of laboratory studies of the static characteristics of several different commercially available heated exhaust gas oxygen sensors are described. In these studies, the emf of the sensors was measured as a function of temperature and of the composition of calibrated gas mixtures. Several different binary gas mixtures (H2/N2, CO/N2, C3H6/N2, C3H8/N2, and CH4/N2) were used together with a variable amount of O2. In addition to laboratory studies, the same sensors were also studied in the exhaust gas of an engine. Whereas at high temperatures thermodynamic equilibrium appears to prevail, clear departures from thermodynamic equilibrium are observed at some lower temperatures (the value of which depends on the specific sensor and the specific gas mixture used). This behavior is manifested by shifts of the emf step away from stoichiometry, broadening of the step, abnormally high emf values in excess oxygen mixtures, and abnormally low emf values in reducing gas mixtures.

Spark knock pressure oscillations can be detected by a cylinder pressure transducer or by an accelerometer mounted on the engine block. Accelerometer-based detection is lower cost but is affected by extraneous mechanical vibrations and the frequency response of the engine block and accelerometer. The knock oscillation frequency changes during the expansion stroke because the chamber geometry is changing due to the piston motion and the burned gases are cooling. Spectrogram analysis shows the time-dependent frequency content of the pressure and acceleration signals, revealing characteristic signatures of knock and mechanical vibrations. Illustrative spectrograms are presented which yield physical insight into accelerometer-based knock detection.

With the use of a simulated exhaust system, the sulfuric acid and sulfur dioxide emission from a monolith noble-metal oxidation catalyst (Engelhard IIB) is measured. It was found that the storage rate of sulfur onto an initially sulfur-free catalyst decreases to a few percent of the sulfur rejection rate within 3-4 h. The amount of sulfur on the catalyst when the catalyst is in equilibrium with 20 ppm sulfur in the gas phase varies between 0.3 weight percent of the catalyst at about 400°C to 0.1 weight percent at 600°C. The sulfur can readily desorb from the catalyst if the gas phase sulfur content is lowered or if the catalyst temperature is increased. It was found that the conversion of sulfur dioxide to sulfuric acid reaches thermodynamic equilibrium at temperatures of 400-500°C and space velocities of 30,000 h-1. These conditions correspond approximately to a small V8 engine at 20 mph cruise.