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The recent development of TiAl-based alloys by the aerospace community has provided an excellent material alternative for hot components in automotive engines. The low density combined with an elevated temperature strength similar to that of Ni-base superalloys make TiAl-based alloys very attractive for exhaust valve applications. Lighter weight valvetrain components improve performance and permit the use of lower valve spring loads which reduce noise and friction and enhance fuel economy. However, difficult fabricability and a perception that TiAl alloys are high cost, low volume aerospace materials must be overcome in order to permit consideration for use in high-volume automotive applications. This paper provides a comparison of properties for several exhaust valve alternative materials. The density of TiAl alloys is lower than Ti alloys with creep and fatigue properties equivalent to IN-751, a current high performance exhaust valve material.

Gas carburized and quenched low alloy steels typically produce surface microstructures which contain martensite, retained austenite and often NMTP's (non-martensitic transformation products). The NMTP's are caused by a reduction of surface hardenability in the carburizing process from loss of alloying elements to oxidation. Gas carburized low alloy steels such as SAE 8620 with NMTP's on the surface have been shown to have inferior bending fatigue properties when compared to more highly alloyed steels which do not form NMTP's, such as SAE 4615M. One method of minimizing the formation of oxides and eliminating NMTP formation during carburizing and quenching is to use plasma carburizing instead of conventional gas carburizing. In this study the microstructures and bending fatigue performance of plasma carburized SAE 8620 and SAE 4615M is compared to the same alloys conventionally gas carburized and quenched.