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A laboratory wear test is used to evaluate the wear protection properties of new and used engine oils formulated for FFV service. Laboratory-blended mixtures of these oils with methanol and water have also been tested. The test consists of a steel ball rotating against three polished cast iron discs. Oil samples are obtained at periodic intervals from a fleet of 3.0L Taurus vehicles operating under controlled go-stop conditions. To account for the effects of fuel dilution, some oils are tested before and after a stripping procedure to eliminate gasoline, methanol and other volatile components. In addition to TAN and TBN measurements, a capillary electrophoresis technique is used to evaluate the formate content in the oils. The results suggest that wear properties of used FFV lubricants change significantly with their degree of usage.

This paper explores the extent to which standard dilution tunnel measurements of motor vehicle exhaust particulate matter modify particle number and size. Steady state size distributions made directly at the tailpipe, using an ejector pump, are compared to dilution tunnel measurements for three configurations of transfer hose used to transport exhaust from the vehicle tailpipe to the dilution tunnel. For gasoline vehicles run at a steady 50 - 70 mph, ejector pump and dilution tunnel measurements give consistent results of particle size and number when using an uninsulated stainless steel transfer hose. Both methods show particles in the 10 - 100 nm range at tailpipe concentrations of the order of 104 particles/cm3.

As vehicle tailpipe emission levels decrease with improvements in emission control technology and reformulation of gasolines, exhaust hydrocarbon levels begin to approach the levels in ambient air. Hydrocarbon speciation at these low levels requires high sensitivity capillary gas chromatography methods. In this study, a mixture of “synthetic” exhaust was prepared at two concentration levels (approximately 5 ppm C and 10 ppm C), and was analyzed by the widely-used Auto/Oil Air Quality Improvement Research Program (AQIRP) Phase II (gas chromatography) speciation method with a sensitivity of 0.005 ppm C for individual species. The mixture at each concentration level, along with a sample of ambient air, was analyzed a total of 20 times on 10 separate days over a 2½ week period. Concentrations of total hydrocarbons (HCs) and individual species (using the AQIRP library) were measured; averages and standard deviations were calculated.

Liquid fuels and the fuel vapors in equilibrium with them typically differ in composition. These differences impact automotive fuel systems in several ways. Large compositional differences between liquid and vapor phases affect the composition of species taken up within the evaporative emission control canister, since the canister typically operates far from saturation and doesn't reach equilibrium with the fuel tank. Here we discuss how these differences may be used to diagnose the mode of emission from a sealed container, e.g., a fuel tank. Liquid or vapor leaks lead to particular compositions (reported here) that depend on the fuel components but are independent of the container material. Permeation leads to emissions whose composition depends on the container material. If information on the relative permeation rates of the different fuel components is available, the results given here provide a tool to decide whether leakage or permeation is the dominant mode of emission.

The worldwide automotive industry is currently preparing for a market introduction of hydrogen-fueled powertrains. These powertrains in fuel cell electric vehicles (FCEVs) offer many advantages: high efficiency, zero tailpipe emissions, reduced greenhouse gas footprint, and use of domestic and renewable energy sources. To realize these benefits, hydrogen vehicles must be competitive with conventional vehicles with regards to fueling time and vehicle range. A key to maximizing the vehicle's driving range is to ensure that the fueling process achieves a complete fill to the rated Compressed Hydrogen Storage System (CHSS) capacity. An optimal process will safely transfer the maximum amount of hydrogen to the vehicle in the shortest amount of time, while staying within the prescribed pressure, temperature, and density limits. The SAE J2601 light duty vehicle fueling standard has been developed to meet these performance objectives under all practical conditions.

As part of a general EGR system model, an adiabatic thermodynamic vacuum EGR valve actuator model was developed and validated. The long term goal of the work is improved system operation by correctly specifying and allocating EGR system component requirements.

A novel non-phosphorus antiwear additive, NP-1, was evaluated as a partial substitute for zinc dialkyldithiophosphate (ZDTP). ZDTP, an antiwear/antioxidant engine oil additive may under certain conditions cause three way catalyst (TWC) deactivation due to formation of an amorphous zinc pyrophosphate, Zn2P2O7, glaze. Antiwear and antioxidant properties of NP-1 alone and in combination with ZDTP were compared with ZDTP only containing formulations. The effects of NP-1 on TWC activity during pulsator modulation and steady-state conditions showed that the TWC maintained good overall activity during 24,000 simulated miles.

The feasibility of using experimentally determined flow fields at intake valve closing, IVC, as initial conditions for computing the in-cylinder flow dynamics during the compression stroke is demonstrated by means of a computer simulation of the overall approach. A commercial CFD code, STAR-CD, was used for this purpose. The study involved two steps. First, in order to establish a basis for comparison, the in-cylinder flow field throughout the intake and compression strokes, from intake valve opening, IVO, to top dead center, TDC, was computed for a simple engine geometry. Second, experimental initial conditions were simulated by randomly selecting and perturbing a set of velocity vectors from the computed flow field at IVC.

This paper compares the emissions performance of four ultra thin wall ceramic substrates with standard wall thickness product on a chassis dynamometer for two different substrate volumes. This comparison helps establish performance trends and provides useful information for selection of substrates in designing catalytic converter systems. This experimental study tests and compares four ultra thin wall products (400/4, 600/3, 600/4, and 900/2) with a standard wall product (400/6.5) at two different substrate volumes. Engine bench aging is used to simulate typical aged conditions. Temperature data as well as second by second and bag emissions data for hydrocarbons, carbon monoxide and oxides of nitrogen were used to evaluate the relative performances of the substrates. The US FTP and US06 driving cycles were used as protocols for the comparison. Results suggest that lower bulk density and higher geometric surface area interact to lead to lower emissions.

This paper describes two types of dielectric-effect sensors that may be used as alternatives to a dielectric-effect sensor using a single capacitor. In the first type, three capacitors are mounted in a compact module inserted into a vehicle fuel line. The three capacitors are connected together to form an electrical pi-filter network. This approach provides a large variation of output signal as the fuel changes from gasoline to methanol. The sensor can be designed to operate in the 1 to 20 MHz frequency range. The second type of sensor investigated uses a resonant-cavity structure. Ordinarily, sensors based on resonant cavities are useful only if the operating frequency is several hundred MHz or higher. The high relative dielectric constant of methanol allows useful sensors to be built using relatively short lengths of metal tubing for the cavities. For example, a sensor built using a fuel rail only 38.7 cm long operated in a frequency range from 31 to 52 MHz.

The objective of this study is to investigate the removal of methane (CH4), nitric oxide (NO), and carbon monoxide (CO) from simulated natural gas vehicle (NGV) exhaust over a palladium catalyst. The effects of changes in space velocity and natural gas sulfur (S) content were studied. The study suggests that the NGV has to be operated slightly rich of stoichiometry to achieve simultaneous removal of the three constituents. The CH4 conversion decreases with an increase in the space velocity. The CO and NO conversions remain unaffected over the space velocity range (10,000 hr-1 to 100,000 hr-1) investigated. The presence of sulfur dioxide in the exhaust lowers the CH4 conversion and increases the CO conversion in the rich region. The NO conversion remains unaffected. Studies were conducted over model catalysts to investigate the modes of CH4 removal from the simulated NGV exhaust.

Modern diesel engines employ a multitude of strategies for oxides of nitrogen (NOx) emission abatement, with exhaust gas recirculation (EGR) being one of the most effective technique. The need for a precise control on the intake charge dilution (as a result of EGR) is paramount since small fluctuations in the intake charge dilution at high EGR rates may cause larger than acceptable spikes in NOx/soot emissions or deterioration in the combustion efficiency, especially at low to mid-engine loads. The control problem becomes more pronounced during transient engine operation; currently the trend is to momentarily close the EGR valve during tip-in or tip-out events. Therefore, there is a need to understand the transient EGR behaviour and its impact on the intake charge development especially under unstable combustion regimes such as low temperature combustion.

A new estimator for IC engine A/F ratio is described. A/F ratio is important for engine operation since it determines the quantities of engine emissions, such as HC, CO, NOx, the conversion efficiency of catalyst systems, and the engine combustion stability. The A/F ratio estimator described in this paper is based on a fundamental metric that relies on inducing and detecting crankshaft speed fluctuations caused by modulating the engine's fuel injection pulse widths. Fuel pulse width modulation varies the instantaneous combustion A/F ratio crankshaft velocity. Synchronous measurement of crankshaft velocity provides a metric that, when used with other engine state variables as inputs to a conventional neural network, can accurately estimate A/F ratio. The estimator provides A/F information when a physical sensor is not available.

Aftertreatment system design involves multiple tradeoffs between engine performance, fuel economy, regulatory emission levels, packaging, and cost. Selection of the best design solution (or “architecture”) is often based on an assumption that inherent catalyst activity is unaffected by location within the system. However, this study acknowledges that catalyst activity can be significantly impacted by location in the system as a result of varying thermal exposure, and this in turn can impact the selection of an optimum system architecture. Vehicle experiments with catalysts aged over a range of mild to moderate to severe thermal conditions that accurately reflect select locations on a vehicle were conducted on a chassis dynamometer. The vehicle test data indicated CO and NOx could be minimized with a catalyst placed in an intermediate location.

Speciated HC emissions from the exhaust system of a production engine without an active catalyst have been obtained with 3 sec time resolution during a 70°F cold start using two control strategies. For the conventional cold start, the emissions were initially enriched in light fuel alkanes and depleted in heavy aromatic species. The light alkanes fell rapidly while the lower vapor pressure aromatics increased over a period of 50 sec. These results indicate early retention of low vapor pressure fuel components in the intake manifold and exhaust system. Loss of higher molecular weight HC species does occur in the exhaust system as shown by experiments in which the exhaust system was preheated to 100° C. The atmospheric reactivity of the exhaust HC emissions for photochemical smog formation increases as the engine warms.

A simplified method was developed to obtain three-way catalyst performance data to be used for predicting vehicle CVS-H emissions. This method involves engine dynamometer aging of catalysts and characterization of their performance as a function of four variables, namely, redox potential, temperature, space velocity and a modulation parameter. In the process of reducing the number of variables, several simplifications were made. The simplifications, their limitations and the characteristic trends in the performance of a 11 Pt/Rh catalyst are discussed.

Carbon dioxide (CO2)-based refrigeration systems have been proposed as environmentally benign alternatives to current automotive air conditioners. The CO2 vapor-compression system requires very high operating pressures and complicated control strategies. Recent experimental results indicate that operating pressures comparable to those of current automotive air conditioners can be attained by the inclusion of a secondary carrier fluid (a “co-fluid”), with solution and desolution of the CO2 from the co-fluid substituting for condensation and vaporization of pure CO2. In this work, modeling tools have been developed to optimize the CO2/co-fluid cycle, including the selection of a co-fluid, the CO2/co-fluid ratio (the “loading”), and the operating conditions.

Thermal reactor systems have been designed to assist in the development of a low emission concept vehicle to meet exhaust emission goals of 0.82 gm/mile hydrocarbon, 7.1 gm/mile carbon monoxide, and 0.68 gm/mile nitrogen oxides established by the Inter-Industry Emission Control (IIEC) Program. The reactor includes design features required for acceptable life characteristics, together with the quick warm-up necessary to achieve the emission targets. Exhaust gas recirculation and enrichened carburetion are used to reduce the oxides of nitrogen. Associated problems defined during development of several thermal reactor systems are described. The primary problem was achieving durability at the typically high operating exhaust gas temperatures (1600-1800 F) necessary for concurrent HC, CO, and NOx control.

Measurements of oxygen storage capacity (OSC) and HC conversion efficiency for 17 catalysts were carried out in the laboratory. All catalysts with steady state HC efficiency below 90% were found to have roughly equivalent and very low capacities to store oxygen. However, catalyst oxygen storage capacity was seen to rise sharply with HC conversion efficiency in excess of 90 percent. These results parallel the trends which are observed between rear HEGO/EGO indexes for OBD-II catalyst monitoring and HC conversion efficiency. In addition, temperature programed reduction (TPR) was found to lend insight into the relationship between catalyst OSC and HC conversion efficiency by providing a qualitative understanding of the mechanisms by which OSC deteriorates. TPR profiles showed that most of the usable oxygen storage is derived from surface ceria which is interacted with precious metals.

The pulse flame combustor was adapted by researchers at Ford Motor Company in the early 1970s in order to produce exhaust gas simulating the combustion products of the internal combustion engine for the evaluation of automotive catalysts. Over the years, the pulse flame combustor has found application in a wide variety of research oriented tasks associated with automotive catalysts and emissions. More recent research and development efforts which have resulted due to elevated demands toward lower vehicle emission levels have prompted continuing refinements of the apparatus and effected innovative approaches to the study of emerging automotive catalyst and emission control issues with the pulse flame combustor. This report provides an overview of the operation and design evolution of the pulse flame combustor. In addition, recent applications of this laboratory device for studying automotive catalysts, alternative fuels, and other automotive emission control topics are reviewed.