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Modern diesel engines employ a multitude of strategies for oxides of nitrogen (NOx) emission abatement, with exhaust gas recirculation (EGR) being one of the most effective technique. The need for a precise control on the intake charge dilution (as a result of EGR) is paramount since small fluctuations in the intake charge dilution at high EGR rates may cause larger than acceptable spikes in NOx/soot emissions or deterioration in the combustion efficiency, especially at low to mid-engine loads. The control problem becomes more pronounced during transient engine operation; currently the trend is to momentarily close the EGR valve during tip-in or tip-out events. Therefore, there is a need to understand the transient EGR behaviour and its impact on the intake charge development especially under unstable combustion regimes such as low temperature combustion.

A new estimator for IC engine A/F ratio is described. A/F ratio is important for engine operation since it determines the quantities of engine emissions, such as HC, CO, NOx, the conversion efficiency of catalyst systems, and the engine combustion stability. The A/F ratio estimator described in this paper is based on a fundamental metric that relies on inducing and detecting crankshaft speed fluctuations caused by modulating the engine's fuel injection pulse widths. Fuel pulse width modulation varies the instantaneous combustion A/F ratio crankshaft velocity. Synchronous measurement of crankshaft velocity provides a metric that, when used with other engine state variables as inputs to a conventional neural network, can accurately estimate A/F ratio. The estimator provides A/F information when a physical sensor is not available.

Aftertreatment system design involves multiple tradeoffs between engine performance, fuel economy, regulatory emission levels, packaging, and cost. Selection of the best design solution (or “architecture”) is often based on an assumption that inherent catalyst activity is unaffected by location within the system. However, this study acknowledges that catalyst activity can be significantly impacted by location in the system as a result of varying thermal exposure, and this in turn can impact the selection of an optimum system architecture. Vehicle experiments with catalysts aged over a range of mild to moderate to severe thermal conditions that accurately reflect select locations on a vehicle were conducted on a chassis dynamometer. The vehicle test data indicated CO and NOx could be minimized with a catalyst placed in an intermediate location.

Thermal reactor systems have been designed to assist in the development of a low emission concept vehicle to meet exhaust emission goals of 0.82 gm/mile hydrocarbon, 7.1 gm/mile carbon monoxide, and 0.68 gm/mile nitrogen oxides established by the Inter-Industry Emission Control (IIEC) Program. The reactor includes design features required for acceptable life characteristics, together with the quick warm-up necessary to achieve the emission targets. Exhaust gas recirculation and enrichened carburetion are used to reduce the oxides of nitrogen. Associated problems defined during development of several thermal reactor systems are described. The primary problem was achieving durability at the typically high operating exhaust gas temperatures (1600-1800 F) necessary for concurrent HC, CO, and NOx control.

New European emissions legislation (Euro5) specifies a limit for Particle Number (PN) emissions and therefore drives measurement of PN during vehicle development and homologation. Concurrently, the use of biofuel is increasing in the marketplace, and Euro5 specifies that reference fuel must contain a bio-derived portion. Work was carried out to test the effect of fuels containing different levels of Fatty Acid Methyl Ester (FAME) on particle number, size, mass and composition. Measurements were conducted with a Cambustion Differential Mobility Spectrometer (DMS) to time-resolve sub-micron particles (5-1000nm), and a Horiba Solid Particle Counting System (SPCS) providing PN data from a Euro5-compliant measurement system. To ensure the findings are relevant to the modern automotive business, testing was carried out on a Euro4 compliant passenger car fitted with a high-pressure common-rail diesel engine and using standard homologation procedures.

A laboratory study was performed to assess the effects of sulfur poisoning and desulfation temperature on the NO conversion of a LNT+(Cu/SCR) in-situ system. Four LNT+(Cu/SCR) systems were aged for 4.5 hours without sulfur at 600, 700, 750, and 800°C using A/F ratio modulations to represent 23K miles of desulfations at different temperatures. NO conversion tests were performed on the LNT alone and on the LNT+SCR system using a 60 s lean/5 s rich cycle. The catalysts were then sulfur-poisoned at 400°C and desulfated four times and re-evaluated on the 60/5 tests. This test sequence was repeated 3 more times to represent 100K miles of desulfations. After simulating 23K miles of desulfations, the Cu-based SCR catalysts improved the NO conversion of the LNT at low temperatures (e.g., 300°C), although the benefit decreased as the desulfation temperature increased from 600°C to 800°C.

A number of tests were conducted on a 2.5 litre, high-speed, direct-injection diesel engine running at various loads and speeds. The aim of the tests was to gain understanding which would lead to more effective use of exhaust gas recirculation (EGR) for controlling exhaust NOx. In addition to exhaust emission measurements, extensive in-cylinder sampling of combustion gases was carried out using a fast-acting, snatch-sampling valve. The results showed that the effectiveness of EGR in suppressing NOx was enhanced considerably by intercooling the inlet charge and by cooling the EGR. A companion paper (SAE 960841) deals with the effects of EGR on soot formation and emission [1].

An advanced diesel aftertreatment system utilizing Selective Catalytic Reduction (SCR) with urea for lean nitrogen oxides (NOx) control was tested on a 2.7L V6 Land Rover vehicle to demonstrate the capability of achieving Tier 2 Bin 5 and lower emission standards for light-duty trucks. SCR washcoat was applied to a diesel particulate filter (DPF) to perform NOx and particulate reduction simultaneously. Advanced SCR systems employed both traditional SCR catalysts and SCR-coated filters (SCRF) to improve the NOx reduction efficiency. The engine-out NOx level was adjusted by modifying the EGR (Exhaust Gas Recirculation) calibration. Cold start NOx performance was improved by SCR warm-up strategy and urea over injection. This study showed the advanced SCR system could tolerate higher NH₃ storage in the SCR catalyst, resulting in overall higher NOx conversion on the FTP-75 test cycle.

Lean NOx traps are being extensively examined (Ref. 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11 and 12) because they can be efficiently used to reduce the NOx emissions from port fuel injected and direct fuel injected spark ignited gasoline engines. A lean NOx trap (LNT) stores NOx during lean A/F engine operation. However, its storage capacity is limited and the LNT must be regenerated periodically by subjecting the LNT to momentary rich A/F operation for several seconds. The regeneration process releases the NOx that is chemically bonded to the washcoat and subsequently reduces it to N2 and O2. Fuel that contains a non-zero amount of sulfur will contaminate an LNT by significantly reducing its NOx storage capacity. Therefore, except for the case of a zero level of sulfur in the fuel, the LNT must be desulfated on a periodic basis. The desulfation process requires that the temperature of the LNT be raised to a temperature of about 650°C for several minutes.

A small-bore 4-stroke single-cylinder stratified-charge DISI engine using an air-forced fuel injection system has been designed and tested under various operating conditions. At light loads, fuel consumption was improved by 16∼19% during lean, stratified-charge operation at an air-fuel ratio of 37. NOx emissions, however, were tripled. Using EGR during lean, stratified-charge operation significantly reduced NOx emissions while fuel consumption was as low as the best case without EGR. It was also found that combustion and emissions near the lean limit were a strong function of the combination of injection and spark timings, which affect the mixing process. Injection pressure, air injection duration, and time delay between fuel and air injections also played a role. Generating in-cylinder air swirl motion slightly improved fuel economy.

The catalytic activity of selected materials (BaY and NaY zeolites, and γ-alumina) for selective NOx reduction in combination with a non-thermal plasma was investigated. Our studies suggest that aldehydes, formed during the plasma treatment of simulated diesel exhaust, are the important species for the reduction of NOx to N2. Indeed, all materials that are active in plasma-assisted catalysis were found to be very effective for the thermal reduction of NOx in the presence of aldehydes. For example, the thermal catalytic activity of a BaY zeolite with aldehydes gives 80-90% NOx removal at 250°C with 200ppm NOx at the inlet and a VHSV=12,000 h-1. The hydrocarbon reductants, n-octane and 1-propyl alcohol, have also shown high thermal catalytic activity for NOx removal over BaY, NaY and γ-alumina.

A single-cylinder OKP (optimized kinetic process) engine, which uses homogeneous-charge compression-ignition (HCCI) technology, was tested, following a previous study, to evaluate the combustion system robustness and to improve the engine performance near the boundaries of the HCCI operating regime at light loads, high loads and high speed. To evaluate the robustness of HCCI combustion control, gasoline fuels with different RON were used, and the engine was tested at different coolant temperatures. It was demonstrated that the proposed HCCI control approaches could control the OKP engine system to operate robustly using different fuels and at different coolant temperatures. The effects of fuel injection timing and residual gas fraction on HCCI combustion and emissions, especially CO emissions and combustion efficiency, were tested at light loads; and the mechanisms were analyzed.

Exhaust gas recirculation (EGR) coolers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases in order to reduce NOX emissions. Engine coolant is used to cool EGR coolers. The presence of a cold surface in the cooler causes fouling due to particulate soot deposition, condensation of hydrocarbon, water and acid. Fouling experience results in cooler effectiveness loss and pressure drop. In this study, possible soot deposition mechanisms are discussed and their orders of magnitude are compared. Also, probable removal mechanisms of soot particles are studied by calculating the forces acting on a single particle attached to the wall or deposited layer. Our analysis shows that thermophoresis in the dominant mechanism for soot deposition in EGR coolers and high surface temperature and high kinetic energy of soot particles at the gas-deposit interface can be the critical factor in particles removal.

Controlled Auto-Ignition (CAI) combustion has been achieved in a production type 4-stroke multi-cylinder gasoline engine. The engine was based on a Ford 1.7L Zetec-SE 16V engine with a compression ratio of 10.3, using substantially standard components modified only in design dimensions to control the gas exchange process in order to significantly increase the trapped residuals. The engine was also equipped with Variable Cam Timing (VCT) on both the intake and exhaust camshafts. It was found that the largely increased trapped residuals alone were sufficient to achieve CAI in this engine and with VCT, a range of loads between 0.5 and 4 bar BMEP and engine speeds between 1000 and 3500 rpm were mapped for CAI fuel consumption and exhaust emissions. The measured CAI results were compared with those of Spark Ignition (SI) combustion in the same engine but with standard camshafts at the same speeds and loads.

Robust on-board diagnosis of emission catalyst performance requires the development of artificially damaged "threshold" catalysts that accurately mimic the performance of damaged catalysts in customer use. The threshold catalysts are used by emissions calibrators to determine fore-aft exhaust oxygen sensor responses that indicate catalyst failure. Rather than rely on traditional trial-and-error processes to generate threshold catalysts, we have used a DFSS (Design For Six-Sigma) approach that explores, at a research level, the relationship between oxygen storage capacity (OSC) of the catalyst (i.e., the fundamental property dictating the response of the aft oxygen sensor) and key process input variables: high-temperature exposure, phosphorus poisoning, and catalyst "recovery."

A simulated diesel exhaust is treated with a nonthermal plasma discharge under steady state conditions. The plasma effluent is then passed through a sodium zeolite-Y (NaY) catalyst followed by a platinum oxidation catalyst. Detailed FTIR measurements of gas composition are taken before, between, and after the treatment stages. The plasma discharge causes oxidation of NO primarily to NO2, with methyl nitrate and nitric acid byproducts. At the same time, HC is partially oxidized, creating species such as formaldehyde, acetaldehyde, CO and other partial oxidation products. When this mixture passes over the NaY catalyst, part of the NOx is reduced to N2, with the remainder primarily in the form of NO. Methyl nitrate decomposes to form methanol and NOx, and nitric acid is consumed. There is little HC conversion on this catalyst. Small quantities of HCN and N2O are formed. When the mixture then passes over the platinum catalyst, further NOx conversion occurs.

Hydrogen fueled internal combustion engines have potential for high thermal efficiencies; however, high efficiency conditions can produce high nitrogen oxide emissions (NOx) that are challenging to treat using conventional 3-way catalysts. This work presents the results of an experimental study to reduce NOx emissions while retaining high thermal efficiencies in a single-cylinder research engine fueled with hydrogen. Specifically, the effects on engine performance of the injection of water into the intake air charge were explored. The hydrogen fuel was injected into the cylinder directly. Several parameters were varied during the study, including the amount of water injected into the intake charge, the amount of fuel injected, the phasing of the fuel injection, the number of fuel injection events, and the ignition timing. The results were compared with expectations for a conventionally operated hydrogen engine where load was controlled through changes in equivalence ratio.

Presented in this paper is an on-line method for estimating the sulfation levels within a lean NOx trap (LNT). Sulfur poisoning plays a major role in the reduction of oxygen and NOx storage capacity in an LNT. Indicators of LNT degradation are LNT NOx absorption efficiency and capacity. The estimation of LNT oxygen and NOx storage capacity is an on-line method of monitoring LNT NOx absorption efficiency and capacity. The estimation provides information regarding the sulfation level of the LNT. This estimate may be used in conjunction with lean burn strategies to initiate an LNT sulfur purging mechanism and maintain maximum fuel economy. In addition, the estimation of LNT oxygen and NOx storage capacity may be used for on-board diagnostics, LNT NOx absorption efficiency estimation, NOx purge fuel estimation, and many other applications.

IIEC efforts to develop NOx catalysts with improved durability have continued. Properties of several nickel oxide catalysts on pelleted, monolithic ceramic, and metallic supports are discussed and the engineering requirements for their effective use are defined. Some promoted nickel oxide, pelleted catalysts show good low-temperature activity, and produce minimal amounts of ammonia but are strongly deactivated by sulfur in the feed gas. Monolithic and metallic catalysts, on the other hand, although not active at temperatures below 1000 F, are very active at higher temperatures where deactivation by sulfur and ammonia formation are not troublesome.

There is a need for an efficient, durable technology to reduce NOx emissions from oxidative exhaust streams such as those produced by compression-ignition, direct-injection (CIDI) diesel or lean-burn gasoline engines. A partnership formed between the DOE Office of Advanced Automotive Technology, Pacific Northwest National Laboratory, Oak Ridge National Laboratory and the USCAR Low Emission Technologies Research and Development Partnership is evaluating the effectiveness of a non-thermal plasma in conjunction with catalytic materials to mediate NOx and particulate emissions from diesel fueled light duty (CIDI) engines. Preliminary studies showed that plasma-catalyst systems could reduce up to 70% of NOx emissions at an equivalent cost of 3.5% of the input fuel in simulated diesel exhaust. These studies also showed that the type and concentration of hydrocarbon play a key role in both the plasma gas phase chemistry and the catalyst surface chemistry.