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Hydrogen Internal Combustion Engines (H2-ICEs) are being investigated due to their minimal criteria pollutant and zero CO2 tailpipe emissions. However, oil filters and non-hot joint gaskets have rubber material that can be damaged and deteriorate due to direct or indirect exposure to the high temperature and high-pressure hydrogen in a H2-ICE. Thus, the effects on the properties of a rubber exposed to a hydrogen environment need to be reviewed. In this review paper, the transportation, chemical and mechanical properties of a rubber exposed directly or indirectly to high temperature and high-pressure hydrogen in a H2-ICE have been reviewed. The compatibility of rubber materials used in H2-ICE has been explored. The effects of high-pressure hydrogen on the transportation, chemical and mechanical properties of NBR and HNBR have been reviewed.

High cycle-to-cycle variations (CTCV) in a Hydrogen-Fueled Internal Combustion Engine (H2-ICE), especially in the lean-burn condition, not only lower the engine’s efficiency but also increase emissions and torque variations. High CTCV are mainly due to the variations in: mixture motion within the cylinder at the time of spark, amount of air and fuel fed to the cylinder, and mixing of the fresh mixture and residual gases within the cylinder during each cycle. In this article, multiple cycle-based methodologies were compared and analyzed specifically for H2-ICEs based on systematic experimentation. The experimental test campaign was performed on a Port Fuel Injection (PFI) H2-ICE designed by PUNCH Torino and data is processed with MATLAB. A MATLAB code is also proposed as a tool for comparing multiple methodologies for the analysis of CTCV specifically for H2-ICE.

Methanol is currently being evaluated as a promising alternative fuel for internal combustion engines, due to being attainable by carbon neutral or negative pathways (renewable energy and carbon capture technology). The low ignitability of methanol has made it attractive mostly as a fuel for spark ignition engines, however the low sooting properties of the fuel could potentially reduce the NOx-soot tradeoff present in compression ignition engines. In this work, using a 4-cylinder engine with compression ratio modified from 16:1 to 19:1, methanol combustion is evaluated under five operating conditions in terms of fuel consumption, criteria pollutants, CO2 emissions and engine efficiency in addition to the qualitative assessment of the combustion stability. It was found that combustion is stable at medium to high loads, with medium load NOx emissions levels at least 30% lower than the original diesel engine and comparable emissions at maximum load conditions.

Hydrogen Internal Combustion Engines (H2-ICEs) are subject to increased attention thanks to their extremely low criteria pollutant emission and near-zero CO2 tailpipe emissions. However, to further minimize exhaust emissions and increase the efficiency of a H2-ICE, it is important to carefully control the relative air-fuel ratio of operation, i.e. Lambda (λ), which will lead in turn to an optimal combustion process. The precise λ control mainly relies upon the methodology to calculate λ on board of the engine, where the availability of reliable sensors specifically-developed for hydrogen combustion is currently limited. In this article, a comparative analysis of different methodologies for the calculation of λ is performed, comparing four methodologies: exhaust gas analysis through a Spindt-Brettschneider approach (λEMI), raw Universal Exhaust Gas Oxygen (λR-UEGO), processed Universal Exhaust Gas Oxygen (λP-UEGO) and speed-density (λSD) outputs.