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All previous correlations of the ignition delay (ID) period in diesel combustion show a positive activation energy, which means that shorter ID periods are achieved at higher charge temperatures. This is not the case in the autoignition of most homogeneous hydrocarbons-air mixtures where they experience the NTC (Negative Temperature Coefficient ) regime in the intermediate temperature range, from about 800 K to 1000 K). Here, the autoignition reactions slow down and longer ID periods are experienced at higher temperatures. Accordingly the global activation energy for the autoignition reactions of homogeneous mixtures should vary from positive to negative values.

The presence of OH radicals as a marker of the high temperature reaction region usually has been used to determine the lift-off length (LOL) in diesel engines. Both OH Laser Induced Fluorescence (LIF) and OH* chemiluminescence diagnostics have been widely used in optical engines for measuring the LOL. OH* chemiluminescence is radiation from OH being formed in the exited states (OH*). As a consequence OH* chemiluminescence imaging provides line-of-sight information across the imaged volume. In contrast, OH-LIF provides information on the distribution of radicals present in the energy ground state. The OH-LIF images only show OH distribution in the thin cross-section illuminated by the laser. When both these techniques have been applied in earlier work, it has often been reported that the chemiluminescence measurements result in shorter lift-off lengths than the LIF approach.

The introduction of new light-duty vehicle emission limits to comply under real driving conditions (RDE) is pushing the diesel engine manufacturers to identify and improve the technologies and strategies for further emission reduction. The latest technology advancements on the after-treatment systems have permitted to achieve very low emission conformity factors over the RDE, and therefore, the biggest challenge of the diesel engine development is maintaining its competitiveness in the trade-off “CO2-system cost” in comparison to other propulsion systems. In this regard, diesel engines can continue to play an important role, in the short-medium term, to enable cost-effective compliance of CO2-fleet emission targets, either in conventional or hybrid propulsion systems configuration. This is especially true for large-size cars, SUVs and light commercial vehicles.