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This paper explores the extent to which standard dilution tunnel measurements of motor vehicle exhaust particulate matter modify particle number and size. Steady state size distributions made directly at the tailpipe, using an ejector pump, are compared to dilution tunnel measurements for three configurations of transfer hose used to transport exhaust from the vehicle tailpipe to the dilution tunnel. For gasoline vehicles run at a steady 50 - 70 mph, ejector pump and dilution tunnel measurements give consistent results of particle size and number when using an uninsulated stainless steel transfer hose. Both methods show particles in the 10 - 100 nm range at tailpipe concentrations of the order of 104 particles/cm3.

The feasibility of using experimentally determined flow fields at intake valve closing, IVC, as initial conditions for computing the in-cylinder flow dynamics during the compression stroke is demonstrated by means of a computer simulation of the overall approach. A commercial CFD code, STAR-CD, was used for this purpose. The study involved two steps. First, in order to establish a basis for comparison, the in-cylinder flow field throughout the intake and compression strokes, from intake valve opening, IVO, to top dead center, TDC, was computed for a simple engine geometry. Second, experimental initial conditions were simulated by randomly selecting and perturbing a set of velocity vectors from the computed flow field at IVC.

Modern diesel engines employ a multitude of strategies for oxides of nitrogen (NOx) emission abatement, with exhaust gas recirculation (EGR) being one of the most effective technique. The need for a precise control on the intake charge dilution (as a result of EGR) is paramount since small fluctuations in the intake charge dilution at high EGR rates may cause larger than acceptable spikes in NOx/soot emissions or deterioration in the combustion efficiency, especially at low to mid-engine loads. The control problem becomes more pronounced during transient engine operation; currently the trend is to momentarily close the EGR valve during tip-in or tip-out events. Therefore, there is a need to understand the transient EGR behaviour and its impact on the intake charge development especially under unstable combustion regimes such as low temperature combustion.

In this study, the particle emission characteristics of 10% alternative diesel fuel blends (Rapeseed Methyl Ester and Gas-to-Liquid) were investigated through the tests carried out on a light duty common-rail Euro 4 diesel engine. Under steady engine conditions, the study focused on particle number concentration and size distribution, to comply with the particle metrics of the European Emission Regulations (Regulation NO 715/2007, amended by 692/2008 and 595/2009). The non-volatile particle characteristics during the engine warming up were also investigated. They indicated that without any modification to the engine, adding selected alternative fuels, even at a low percentage, can result in a noticeable reduction of the total particle numbers; however, the number of nucleation mode particles can increase in certain cases.

Speciation of sulfurous acid, sulfuric acid and ammonium sulfate collected from the aerosol phase on a Fluoropore filter has been readily accomplished using techniques of chemical ionization mass spectrometry combined with thermal separation. Thermal separation of ammonium hydrogen sulfate from ammonium sulfate was not possible. Spectral separation of these species by selective ionization is proposed. Analysis of sulfate aerosols collected from ambient air and catalyzed vehicle emissions is described. It was found that sulfuric acid aerosol was rapidly converted to ammonium sulfate or ammonium hydrogen sulfate in the presence of ambient concentrations of ammonia. Ambient samples collected in the Detroit metropolitan area have been found to contain only trace quantities of sulfuric aicd. Sulfate samples collected from a dilution tube into which catalyzed vehicle exhaust was injected were found to contain significant quantities of ammonium sulfate in addition to sulfuric acid.

New European emissions legislation (Euro5) specifies a limit for Particle Number (PN) emissions and therefore drives measurement of PN during vehicle development and homologation. Concurrently, the use of biofuel is increasing in the marketplace, and Euro5 specifies that reference fuel must contain a bio-derived portion. Work was carried out to test the effect of fuels containing different levels of Fatty Acid Methyl Ester (FAME) on particle number, size, mass and composition. Measurements were conducted with a Cambustion Differential Mobility Spectrometer (DMS) to time-resolve sub-micron particles (5-1000nm), and a Horiba Solid Particle Counting System (SPCS) providing PN data from a Euro5-compliant measurement system. To ensure the findings are relevant to the modern automotive business, testing was carried out on a Euro4 compliant passenger car fitted with a high-pressure common-rail diesel engine and using standard homologation procedures.

The Ford PROCO stratified charge engine combines the desirable characteristics of premixed charge and Diesel engines. The outstanding characteristics of premixed charge engines are their high specific output, wide speed range, light weight and easy startability but they exhibit only modest fuel economy and relatively high exhaust emissions. The desirable characteristic of the Diesel engine is its outstanding fuel economy. However, the disadvantages of the Diesel, which include noisy operation, limited speed range, exhaust odor, smoke, hard startability, and particulate emissions have tended to limit their acceptance. In the gasoline fueled, PROCO stratified charge engine, direct cylinder fuel injection permits operation at overall lean mixture ratios and higher compression ratio. These features enable the PROCO engine to achieve brake specific fuel consumption values in the range of prechamber diesel engines.

Erosion damage to automotive car bodies caused by stones and small sand particles and road debris significantly affects the appearance of paint. Painted engineering plastics as well as precoated sheet steel are affected by erosion phenomenon. Erosion of painted plastic substrates results in cosmetic concerns while that on metal substrates results in cosmetic to perforation corrosion. This work describes a laboratory simulation of erosion of painted plastic substrates by small particles on various paint and substrate types. Gloss loss was used to quantitatively evaluate erosion of painted surfaces. Wear behavior of painted plastic substrates to slag sand impact was evaluated as a function of several variables including paint type (one-component melamine crosslinked (1K) vs. two-component isocyanate crosslinked (2K)), thermal history, and coating modulus. The effect of slag sand type (particle size and chemical composition) was studied.

Vehicle emissions have been measured and the results statistically evaluated for a vehicle test fleet consisting of four Escorts and four Explorers using both a fully formulated durability fuel doped with methylcyclopentadienyl manganese tricarbonyl (MMT) at 1/32 gram Mn/gallon and the same fully formulated durability fuel without the MMT. The fleet was divided in half -- half with MMT and half without MMT doped fuel. This report covers emission measurement results at 5,000; 15,000; 50,000 and 100,000 miles of exposure to MMT doped fuel. A modified paired t-test is used to analyze the emission data obtained from all the fleet vehicles. The statistical evaluation of both feedgas and tailpipe emissions indicate that the use of MMT is detrimental to emissions of HC at the 15,000 mile; 50,000 mile and 100,000 mile levels of MMT exposure. As mileage is accumulated, the pronounced the effect on HC by the fuel additive MMT.

Diesel exhaust gas dilution and odor intensity were measured in the immediate vicinity of a transit bus equipped with a rear-mounted horizontal exhaust pipe, a rear-mounted vertical exhaust pipe, and a roof-top diffusion system. Exhaust dilution ratios were measured indoors during vehicle idle operation, using propane added to the exhaust gas as a tracer. Exhaust odor intensities were measured also indoors during vehicle idle operation by a human panel, using a threshold odor measurement technique. On the average, the dilution of the exhaust gas around the bus with the vertical exhaust pipe was about eight times greater than it was with the horizontal pipe. Odor intensity, as measured by the threshold response distance, was about 35% less with the vertical pipe than with the horizontal pipe. The roof-top diffuser was not as effective as the vertical exhaust pipe in increasing exhaust gas dilution or in reducing exhaust odor intensity.

A number of tests were conducted on a 2.5 litre, high-speed, direct-injection diesel engine running at various loads and speeds. The aim of the tests was to gain understanding which would lead to more effective use of exhaust gas recirculation (EGR) for controlling exhaust NOx whilst minimising the penalties of increased smoke emission and fuel consumption. In addition to exhaust emission measurements, in-cylinder sampling of combustion gases was carried out using a fast-acting, snatch-sampling valve. The results showed that the effectiveness of EGR was enhanced considerably by cooling the EGR. In addition to more effective NOx control, this measure also improved volumetric efficiency which assisted in the control of smoke emission and fuel consumption. This second of two papers on the use of EGR in diesel engines deals with the effects of EGR on soot emission and on the engine fuel economy.

A number of tests were conducted on a 2.5 litre, high-speed, direct-injection diesel engine running at various loads and speeds. The aim of the tests was to gain understanding which would lead to more effective use of exhaust gas recirculation (EGR) for controlling exhaust NOx. In addition to exhaust emission measurements, extensive in-cylinder sampling of combustion gases was carried out using a fast-acting, snatch-sampling valve. The results showed that the effectiveness of EGR in suppressing NOx was enhanced considerably by intercooling the inlet charge and by cooling the EGR. A companion paper (SAE 960841) deals with the effects of EGR on soot formation and emission [1].

Automotive three-way catalysts (TWC) were characterized using temperature-programmed reduction (TPR), x-ray diffraction (XRD), Raman spectroscopy, chemisorption measurements and laboratory activity measurements. Capabilities and limitations of these standard analytical techniques for the characterization of production-type automotive catalysts are pointed out. With the exception of chemisorption techniques, all appear to have general utility for analyzing exhaust catalysts. The techniques were used to show that the noble metals and ceria in fresh Pt/Rh and Pd/Rh catalysts are initially highly dispersed and contain a mixture of interacting and non-interacting species. Thermal aging of these catalysts (in the reactor or vehicle) caused both precious metal and ceria particles to sinter, thereby decreasing the interaction between the two.

A small-bore 4-stroke single-cylinder stratified-charge DISI engine using an air-forced fuel injection system has been designed and tested under various operating conditions. At light loads, fuel consumption was improved by 16∼19% during lean, stratified-charge operation at an air-fuel ratio of 37. NOx emissions, however, were tripled. Using EGR during lean, stratified-charge operation significantly reduced NOx emissions while fuel consumption was as low as the best case without EGR. It was also found that combustion and emissions near the lean limit were a strong function of the combination of injection and spark timings, which affect the mixing process. Injection pressure, air injection duration, and time delay between fuel and air injections also played a role. Generating in-cylinder air swirl motion slightly improved fuel economy.

A study has been conducted to measure the particle number emissions from a current-generation 1.6-liter, Euro IV-compliant turbo-charged Gasoline Direct Injection (GDI) passenger car engine. A fast-response particle size spectrometer was used along with a PMP-compliant particulate measurement system to measure the effect of various engine parameters on the particulate emissions during the New European Drive Cycle (NEDC). Overall particle number is shown along with further analysis of the transient particle emissions. The cold start clearly affects particle formation with approximately 50% of the cumulative particle number being emitted within 200 seconds of the start. Even beyond 200 seconds, the particle number emissions fall as the test progresses and are generally consistent with increases in engine coolant temperature indicating that cold engine fuel preparation issues are contributing to the particle number count.

The catalytic activity of selected materials (BaY and NaY zeolites, and γ-alumina) for selective NOx reduction in combination with a non-thermal plasma was investigated. Our studies suggest that aldehydes, formed during the plasma treatment of simulated diesel exhaust, are the important species for the reduction of NOx to N2. Indeed, all materials that are active in plasma-assisted catalysis were found to be very effective for the thermal reduction of NOx in the presence of aldehydes. For example, the thermal catalytic activity of a BaY zeolite with aldehydes gives 80-90% NOx removal at 250°C with 200ppm NOx at the inlet and a VHSV=12,000 h-1. The hydrocarbon reductants, n-octane and 1-propyl alcohol, have also shown high thermal catalytic activity for NOx removal over BaY, NaY and γ-alumina.

In order to meet progressively stringent regulations on particulate emission from diesel engines, GM has developed and tested a variety of trap oxidizer systems over the years. A particulate trap system for a light duty diesel engine has been selected and developed based on this experience, with particular emphasis on production feasibility. The system components have been designed and developed in collaboration with potential suppliers, to the extent possible. The technical performance of this system has been demonstrated by successful system durability testing in the test cell and vehicle experience in computer controlled automatic operation mode. Although the system shows promise, its production readiness will require more development and extensive vehicle validation under all operating conditions.

Exhaust gas recirculation (EGR) coolers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases in order to reduce NOX emissions. Engine coolant is used to cool EGR coolers. The presence of a cold surface in the cooler causes fouling due to particulate soot deposition, condensation of hydrocarbon, water and acid. Fouling experience results in cooler effectiveness loss and pressure drop. In this study, possible soot deposition mechanisms are discussed and their orders of magnitude are compared. Also, probable removal mechanisms of soot particles are studied by calculating the forces acting on a single particle attached to the wall or deposited layer. Our analysis shows that thermophoresis in the dominant mechanism for soot deposition in EGR coolers and high surface temperature and high kinetic energy of soot particles at the gas-deposit interface can be the critical factor in particles removal.

There is a clearly demonstrated need to develop “real-time” methods for the measurement of diesel vehicle particulate emissions. Optical techniques provide One alternative for such methodology because of the rapid data acquisition times involved and the relatively simple sampling methods that can be used. This report describes two different approaches to this problem. The first, the spectrophone, measures light absorption by the diluted exhaust plume using photoacoustic spectroscopy, and the second, the long pathlength smokemeter, determines total light extinction across the diluted exhaust plume. For the measurement of total mass emissions, both techniques show estimated errors of ±15% for specific vehicles, while for a multi-vehicle diesel fleet the estimated errors are ±20% and ±30% for the long pathlength smokemeter and the spectrophone, respectively.

A new methodology for rapidly characterizing the in-cylinder flow field at spark ignition for internal combustion engines is described in this paper. The process involves the use of 3-D particle tracking velocimetry to measure the flow field at intake valve closing (IVC) in a water analog engine simulation, and the use of CFD to compute the evolution of the measured flow field during the compression stroke, by using the experimental 3-D PTV results at IVC as the initial condition for the calculations. The technique has been applied to investigate the in-cylinder flow field of a typical 4 valve engine operating in two different modes; one or two intake ports active. The results indicate that in either mode the flow field at IVC is dominated by a different large scale structure: tumble in the case where both intake ports are active and swirl in the case where only one port is active. The results also indicate that these structures evolve differently during the compression stroke.