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Technical Paper

“Active Mass Absorber” at a 4×4 Transmition System

2003-11-18
2003-01-3682
The extensive use of rotative machines in the diverse branches of the modern world has made the rising undesirable mechanical and acoustic vibration levels to be a problem of special importance for the machines normal operation as for the communities that are each time more affected by the problem. It makes the study of vibration and acoustic phenomena also to be even more important and the applications of its concepts more sophisticated. Several are the concepts used for decreasing vibration levels, like common dampers, hydraulic dampers, active dampers, natural frequencies changes and others. The choice of use of one or another depends greatly on the engineering possibilities (weight, energy, physical space, other components functional interference, vibration levels, etc.) as well as the cost of implementation of each one.
Technical Paper

Washcoat Technology and Precious Metal Loading Study Targeting the California LEV MDV2 Standard

1996-10-01
961904
Meeting the California Medium-Duty truck emissions standards presents a significant challenge to automotive engineers due to the combination of sustained high temperature exhaust conditions, high flow rates and relatively high engine out emissions. A successful catalyst for an exhaust treatment system must be resistant to high temperature deactivation, maintain cold start performance and display high three-way conversion efficiencies under most operating conditions. This paper describes a catalyst technology and precious metal loading study targeting a California Medium-Duty truck LEV (MDV2) application. At the same time a direction is presented for optimizing toward the Federal Tier 1 standard through reduction of precious metal use. The paper identifies catalytic formulations for a twin substrate, 1.23 L medium-coupled converter. Two are used per vehicle, mounted 45 cm downstream of each manifold on a 5.7 L V8 engine.
Technical Paper

Virtual Exhaust Gas Temperature Measurement

2017-03-28
2017-01-1065
Exhaust temperature models are widely used in the automotive industry to estimate catalyst and exhaust gas temperatures and to protect the catalyst and other vehicle hardware against over-temperature conditions. Modeled exhaust temperatures rely on air, fuel, and spark measurements to make their estimate. Errors in any of these measurements can have a large impact on the accuracy of the model. Furthermore, air-fuel imbalances, air leaks, engine coolant temperature (ECT) or air charge temperature (ACT) inaccuracies, or any unforeseen source of heat entering the exhaust may have a large impact on the accuracy of the modeled estimate. Modern universal exhaust gas oxygen (UEGO) sensors have heaters with controllers to precisely regulate the oxygen sensing element temperature. These controllers are duty cycle based and supply more or less current to the heating element depending on the temperature of the surrounding exhaust gas.
Technical Paper

Using Artificial Ash to Improve GPF Performance at Zero Mileage

2019-04-02
2019-01-0974
Gasoline particulate filters (GPF) with high filtration efficiency (>80%) at zero mileage are in growing demand to meet increasingly tight vehicle emission standards for particulate matter being implemented in US, EU, China and elsewhere. Current efforts to achieve high filter performance mainly focus on fine-tuning the filter structure, such as the pore size distribution and porosity of the bare substrate, or the washcoat loading and location of catalyzed substrates. However, high filtration efficiency may have a cost in high backpressure that negatively affects engine power. On the other hand, it has been recognized in a few reports that very low amounts of ash deposits (from non-combustible residue in the exhaust) can significantly increase filtration efficiency with only a mild backpressure increase.
Journal Article

Uncertainty Analysis of Model Based Diesel Particulate Filter Diagnostics

2008-10-07
2008-01-2648
This paper analyzes the potential benefit of a model based DPF leakage monitor over a conventional DPF leakage monitor that checks pressure drop after a complete regeneration. We analyze the most important noise factors involved in both approaches and demonstrate that the model based leakage monitor does not improve on the conventional leakage monitor in accuracy. It does improve on completion frequency, but at the expense of a great modeling effort.
Journal Article

Twin-LNT System for Advanced Diesel Exhaust Gas Aftertreatment

2017-03-28
2017-01-0935
The most significant challenge in emission control for compression ignited internal combustion engines is the suppression of NOx. In the US, NOx-levels have faced a progressive reduction for several years, but recently the introduction of the Real Driving Emissions legislation (RDE) in Europe has not only significantly increased the severity of the required emission reduction but now is in the advent of stretching technology to its limits. Emission control is based on engine-internal optimization to reduce the engine-out emissions in conjunction with aftertreatment technologies, that are either Selective Catalytic Reduction (SCR) or Lean NOx Trap (LNT) based systems. Due to its ability to control high amounts of NOx, SCR is widely used in heavy-duty applications and is becoming more popular in light-duty and passenger car applications as well.
Technical Paper

Turbocharging the 1983½-1984 Ford 2.3L OHC Engine

1984-02-01
840251
Successful application of turbocharger technology to the Ford 2.3L OHC engine requires management of thermal loading. The 1979/1980 2.3L draw-thru carbureted engine was octane and spark advance limited, requiring calibration to worse case 91 RON conditions. Since no adaptive calibration control was possible relatively late ignition timing compromised engine performance. To improve performance, driveability, fuel economy and emission control, work was initiated in mid 1980 on a blow-thru electronic fuel injected engine scheduled for 1983½ production. Program assumptions were issued specifying a tuned EFI blow-thru inlet system, exhaust manifold mounted AiResearch T03 turbocharger with integral wastegate and 8.0:1 compression ratio with a dished piston. Also included were base engine revisions to accommodate increased thermal and mechanical loads.
Technical Paper

Transient Non-linear FEA and TMF Life Estimates of Cast Exhaust Manifolds

2003-03-03
2003-01-0918
A transient nonlinear Finite Element Analysis (FEA) method has been developed to simulate the inelastic deformation and estimate the thermo-mechanical fatigue life of cast iron and cast steel exhaust manifolds under dynamometer test conditions. The FEA uses transient heat transfer analysis to simulate the thermal loads on the manifold, and includes the fasteners, gasket and portion of the cylinder head. The analysis incorporates appropriate elastic-plastic and creep material models. It is shown that the creep deformation is the most single critical component of inelastic deformation for cast iron manifold ratcheting, gasket sealing, and crack initiation. The predicted transient temperature field and manifold deformation of the FEA model compares exceptionally well with two experimental tests for a high silicon-molybdenum exhaust manifold.
Technical Paper

Transient Fuel Modeling and Control for Cold Start Intake Cam Phasing

2006-04-03
2006-01-1049
Advancing intake valve timing shortly after engine crank and run-up can potentially reduce vehicle cold start hydrocarbon (HC) emissions in port fuel injected (PFI) engines equipped with intake variable cam timing (iVCT). Due to the cold metal temperatures, there can be significant accumulation of liquid fuel in the intake system and in the cylinder. This accumulation of liquid fuel provides potential sources for unburned hydrocarbons (HCs). Since the entire vehicle exhaust system is cold, the catalyst will not mitigate the release of unburned HCs. By advancing the intake valve timing and increasing valve overlap, liquid fuel vaporization in the intake system is enhanced thereby increasing the amount of burnable fuel in the cylinder. This increase in burnable HCs must be countered by a reduction in injector-delivered fuel via a compensator that reacts to cam movement.
Journal Article

Tier 2 Test Fuel Impact to Tier 3 Aftertreatment Systems and Calibration Countermeasures

2018-04-03
2018-01-0941
During the course of emissions and fuel economy (FE) testing, vehicles that are calibrated to meet Tier 3 emissions requirements currently must demonstrate compliance on Tier 3 E10 fuel while maintaining emissions capability with Tier 2 E0 fuel used for FE label determination. Tier 3 emissions regulations prescribe lower sulfur E10 gasoline blends for the U.S. market. Tier 3 emissions test fuels specified by EPA are required to contain 9.54 volume % ethanol and 8-11 ppm sulfur content. EPA Tier 2 E0 test fuel has no ethanol and has nominal 30 ppm sulfur content. Under Tier 3 rules, Tier 2 E0 test fuel is still used to determine FE. Tier 3 calibrations can have difficulty meeting low Tier 3 emissions targets while testing with Tier 2 E0 fuel. Research has revealed that the primary cause of the high emissions is deactivation of the aftertreatment system due to sulfur accumulation on the catalysts.
Technical Paper

Threshold Monitoring of Urea SCR Systems

2006-10-31
2006-01-3548
To meet stringent 2010 NOx emissions, many manufacturers are expected to deploy urea selective catalytic reduction systems. Indications from ARB are that a threshold monitor must be developed to monitor their performance. The most capable monitoring technology at this time relies on NOx sensors. This paper assesses the capability of the NOx sensor as an SCR monitoring device. To this end, the NOx sensor must be able to distinguish between a marginal and a threshold catalyst with enough separation to allow for variability. We present the noise factors associated with the NOx conversion of the SCR system, and analyze what NOx sensor accuracy we need to preserve separation in the face of those noise factors. It is shown that a 1.75 threshold monitor is not feasible with current NOx sensor technology. We analyze the benefit of a partial volume monitor, and show there is no advantage unless the slope error of the NOx sensor is drastically reduced from current levels.
Technical Paper

Three-Way Catalyst Diagnostics and Prognostics Based on Support Vector Machines

2017-03-28
2017-01-0975
A three-way catalytic converter (TWC) is an emissions control device, used to treat the exhaust gases in a gasoline engine. The conversion efficiency of the catalyst, however, drops with age or customer usage and needs to be monitored on-line to meet the on board diagnostics (OBD II) regulations. In this work, a non-intrusive catalyst monitor is developed to diagnose the track the remaining useful life of the catalyst based on measured in-vehicle signals. Using air mass and the air-fuel ratio (A/F) at the front (upstream) and rear (downstream) of the catalyst, the catalyst oxygen storage capacity is estimated. The catalyst capacity and operating exhaust temperature are used as an input features for developing a Support Vector Machine (SVM) algorithm based classifier to identify a threshold catalyst. In addition, the distance of the data points in hyperspace from the calibrated threshold plane is used to compute the remaining useful life left.
Technical Paper

Three-Dimensional Simulations of Automotive Catalytic Converter Internal Flow

1991-02-01
910200
The three-dimensional non-reacting flow field inside a typical dual-monolith automotive catalytic converter was simulated using finite difference analysis. The monolithic brick resistance was formulated from the pressure gradient of fully developed laminar duct-flow and corrected for the entrance effect. This correlation was found to agree with experimental pressure drop data, and was introduced as an additional source term into the non-dimensional momentum governing equation within the brick. Flow distribution within the monolith was found to depend strongly on the diffuser performance, which is a complex function of flow Reynolds number, brick resistance, and inlet pipe length and bending angles. A distribution index was formulated to quantify the degree of non-uniformity at selected test cases covering ranges of flow conditions, brick types, and inlet conditions.
Technical Paper

The Influence of Ammonia to NOX Ratio on SCR Performance

2007-04-16
2007-01-1581
It is likely that use of urea-based selective catalytic reduction (SCR) will be needed to meet U.S. Tier 2 diesel emission standards for oxides of nitrogen (NOx). The ideal ratio of ammonia (NH3) molecules to NOx molecules (known as alpha) is 1:1 based on urea consumption and having NH3 available for reaction of all of the exhaust NOx. However, SCR efficiency can be less than 100% at low temperatures in general, and at higher temperatures with high exhaust SCR catalyst space velocities. At the low temperatures where NOx conversion efficiency is low, it may be advantageous to reduce the alpha ratio to values less than one (less NH3 than is needed to convert 100% of the NOx emissions) to avoid NH3 slip. At higher space velocities and high temperatures, the NOx conversion efficiency may be higher with alpha ratios greater than 1. There is however concern that the additional NH3 will be slipped under these conditions.
Technical Paper

The Influence of Ammonia Slip Catalysts on Ammonia, N2O and NOX Emissions for Diesel Engines

2007-04-16
2007-01-1572
The use of urea-based selective catalytic reduction (SCR) is a promising method for achieving U.S. Tier 2 diesel emission standards for NOx. To meet the Tier 2 standards for Particulate Matter (PM), a catalyzed diesel particulate filter (CDPF) will likely be present and any ammonia (NH3) that is not consumed over an SCR catalyst would pass over the CDPF to make nitrous oxide (N2O) emissions and/or oxides of nitrogen (NOx), or exit the exhaust system as NH3. N2O is undesirable due to its high greenhouse gas potential, while NOx production from the slipped NH3 would reduce overall system NOx conversion efficiency. This paper reviews certain conditions where NH3 slip past an SCR system may be a concern, looks at what would happen to this slipped NH3 over a CDPF, and evaluates the performance of various supplier NH3 slip catalysts under varied space velocities, temperatures and concentrations of NH3 and NOx.
Technical Paper

The Effects of Aging Temperature and PGM Loading on the NOx Storage Capacity of a Lean NOx Trap

2005-04-11
2005-01-1117
A laboratory aging study was performed on samples of a lean NOx trap with platinum group metal (PGM) loadings of 0.53, 1.06, 2.12, and 3.18 g/liter. The LNT samples were aged at inlet temperatures of 650°C, 750°C, 800°C, and 850°C behind samples of a three-way catalyst that were aged on a pulse-flame combustion reactor with a Ford-proprietary durability schedule representing 80,000 km of customer use. For all aging temperatures, higher PGM loadings were beneficial for low temperature NOx performance, attributable to an increase in the oxidation of NO to NO2. Conversely, lower PGM loadings were beneficial for high temperature NOx performance after aging at 650°C and 750°C, as higher loadings promoted the decomposition of the nitrates during lean operation and thereby decreased the NOx storage capability at high temperatures. Also, higher PGM loadings increased the OSC of the trap and thereby increased the purge requirements.
Journal Article

The Effect of Hydrocarbons on the Selective Catalyzed Reduction of NOx over Low and High Temperature Catalyst Formulations

2008-04-14
2008-01-1030
Selective Catalytic Reduction of NOx is a promising technology to enable diesel engines to meet certification under Tier 2 Bin 5 emissions requirements. SCR catalysts for vehicle use are typically zeolitic materials known to store both hydrocarbons and ammonia. Ammonia storage on the zeolite has a beneficial effect on NOx conversion; hydrocarbons however, compete with ammonia for storage sites and may also block access to the interior of the zeolites where the bulk of the catalytic processes take place. This paper presents the results of laboratory studies utilizing surrogate hydrocarbon species to simulate engine-out exhaust over catalysts formulated to operate in both low (≈175-500°C) and high temperature (≈250-600°C) regimes. The effects of hydrocarbon exposure of these individual species on the SCR reaction are examined and observations are made as to necessary conditions for the recovery of SCR activity.
Technical Paper

The Effect of Exhaust System Geometry on Exhaust Dilution and Odor Intensity

1971-02-01
710219
Diesel exhaust gas dilution and odor intensity were measured in the immediate vicinity of a transit bus equipped with a rear-mounted horizontal exhaust pipe, a rear-mounted vertical exhaust pipe, and a roof-top diffusion system. Exhaust dilution ratios were measured indoors during vehicle idle operation, using propane added to the exhaust gas as a tracer. Exhaust odor intensities were measured also indoors during vehicle idle operation by a human panel, using a threshold odor measurement technique. On the average, the dilution of the exhaust gas around the bus with the vertical exhaust pipe was about eight times greater than it was with the horizontal pipe. Odor intensity, as measured by the threshold response distance, was about 35% less with the vertical pipe than with the horizontal pipe. The roof-top diffuser was not as effective as the vertical exhaust pipe in increasing exhaust gas dilution or in reducing exhaust odor intensity.
Technical Paper

The Effect of Different Ageing Conditions on Spatial Variations in Emissions Across the Radius of a Close-coupled After-treatment System

2005-04-11
2005-01-1095
Using local emissions measurements immediately downstream of a close-coupled catalyst, spatial variations in emissions have been analysed for close-coupled catalysts with different ageing histories. Comparison of the radial emissions profiles between a uniformly-aged (oven-aged) catalyst and two vehicle-aged parts suggests that the vehicle-aged parts have substantial variations in catalyst damage across the radius of the catalyst. The radial variations in damage were confirmed by bench reactor and post-mortem studies. The radial catalyst damage profiles inferred from engine-based evaluations of vehicle aged catalysts show broad correlation with high flow areas identified by CFD predictions and high temperature regions as measured during engine tests.
Technical Paper

The Development of Low Temperature Three-Way Catalysts for High Efficiency Gasoline Engines of the Future: Part II

2018-04-03
2018-01-0939
It is anticipated that future gasoline engines will have improved mechanical efficiency and consequently lower exhaust temperatures at low load conditions, although the exhaust temperatures at high load conditions are expected to remain the same or even increase due to the increasing use of downsized turbocharged engines. In 2014, a collaborative project was initiated at Ford Motor Company, Oak Ridge National Lab, and the University of Michigan to develop three-way catalysts with improved performance at low temperatures while maintaining the durability of current TWCs. This project is funded by the U.S. Department of Energy and is intended to show progress toward the USDRIVE target of 90% conversion of hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx) at 150 °C after high mileage aging. The testing protocols specified by the USDRIVE ACEC team for stoichiometric S-GDI engines were utilized during the evaluation of experimental catalysts at all three facilities.
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