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Weld lines occur when melt flow fronts meet during the injection molding of plastic parts. It is important to investigate the weld line because the weld line area can induce potential failure of structural application. In this paper, a weld line factor (W-L factor) was adopted to describe the strength reduction to the ultimate strength due to the appearance of weld line. There were two engineering thermoplastics involved in this study, including one neat PP and one of talc filled PP plastics. The experimental design was used to investigate four main injection molding parameters (melt temperature, mold temperature, injection speed and packing pressure). Both the tensile bar samples with/without weld lines were molded at each process settings. The sample strength was obtained by the tensile tests under two levels of testing speed (5mm/min and 200mm/min) and testing temperatures (room temperature and -30°C). The results showed that different materials had various values of W-L factor.

Meeting the California Medium-Duty truck emissions standards presents a significant challenge to automotive engineers due to the combination of sustained high temperature exhaust conditions, high flow rates and relatively high engine out emissions. A successful catalyst for an exhaust treatment system must be resistant to high temperature deactivation, maintain cold start performance and display high three-way conversion efficiencies under most operating conditions. This paper describes a catalyst technology and precious metal loading study targeting a California Medium-Duty truck LEV (MDV2) application. At the same time a direction is presented for optimizing toward the Federal Tier 1 standard through reduction of precious metal use. The paper identifies catalytic formulations for a twin substrate, 1.23 L medium-coupled converter. Two are used per vehicle, mounted 45 cm downstream of each manifold on a 5.7 L V8 engine.

This paper proposes a film dynamics model for liquid film resulting from fuel spray impinging on a wall surface. It is based on a thin film assumption and uses numerical particles to represent the film to be compatible with the particle spray models developed previously. The Lagrangian method is adopted to govern the transport of the film particles. A new, statistical treatment was introduced of the momentum exchange between the impinging spray and the wall film to account for the directional distribution of the impinging momentum. This model together with the previously published models for outgoing droplets constitutes a complete description of the spray wall impingement dynamics. For model validation, films resulting from impinging sprays on a flat surface with different impingement angles were calculated and the results were compared with the corresponding experimental measurements.

Exhaust temperature models are widely used in the automotive industry to estimate catalyst and exhaust gas temperatures and to protect the catalyst and other vehicle hardware against over-temperature conditions. Modeled exhaust temperatures rely on air, fuel, and spark measurements to make their estimate. Errors in any of these measurements can have a large impact on the accuracy of the model. Furthermore, air-fuel imbalances, air leaks, engine coolant temperature (ECT) or air charge temperature (ACT) inaccuracies, or any unforeseen source of heat entering the exhaust may have a large impact on the accuracy of the modeled estimate. Modern universal exhaust gas oxygen (UEGO) sensors have heaters with controllers to precisely regulate the oxygen sensing element temperature. These controllers are duty cycle based and supply more or less current to the heating element depending on the temperature of the surrounding exhaust gas.

Gasoline particulate filters (GPF) with high filtration efficiency (>80%) at zero mileage are in growing demand to meet increasingly tight vehicle emission standards for particulate matter being implemented in US, EU, China and elsewhere. Current efforts to achieve high filter performance mainly focus on fine-tuning the filter structure, such as the pore size distribution and porosity of the bare substrate, or the washcoat loading and location of catalyzed substrates. However, high filtration efficiency may have a cost in high backpressure that negatively affects engine power. On the other hand, it has been recognized in a few reports that very low amounts of ash deposits (from non-combustible residue in the exhaust) can significantly increase filtration efficiency with only a mild backpressure increase.

Unregulated emissions, i.e., emissions which are not currently regulated by EPA, have been measured from a 7.5 L (460 CID) PROCO engine powered vehicle operating at 50 kph on a chassis dynamometer. A dilution tube was used. Emphasis was on particulate emissions, which were characterized physically and chemically. A comparison is made to recent similar measurements on Diesel and conventional gasoline powered vehicles.

Meeting EPA Tier 2 emission standards presents a great challenge to engine manufacturers. In addition to having an actively controlled aftertreatment system, engine-out NOx emission needs to be reduced significantly to achieve regulatory compliance. Using advanced combustion methods, such as low temperature combustion and/or HCCI, has been shown to reduce engine-out NOx emissions. However, all this new combustion technologies are yet to permeate down into any production system. In current practice, large amount of exhaust gas recirculation (EGR) into the cylinders is widely used to reduce emissions. However, NOx emission from transient engine operation still constitutes a very large percentage of the total NOx output during a Federal Test Procedure (FTP) cycle and has yet to be adequately addressed. Currently, the EGR flow is controlled using the intake mass airflow (MAF) measurement.

A methodology is developed that incorporates high resolution CFD flowfield information and a particle trajectory simulation, aimed at addressing Paint Transfer Efficiency (PTE) for bell sprayers. Given a solid model for the bell sprayer, the CFD simulation, through automeshing, determines a high resolution Cartesian volume mesh (14-20 million cells). With specified values of the initial shaping air, transient and steady-state flow field information is obtained. A particle trajectory visualization tool called SpraySIM uses this complicated flowfield information to determine the particle trajectories of the paint particles under the influence of drag, gravity and electrostatic potential. The sensitivity of PTE on shaping air velocity, charge-to-mass ratio, potential, and particle diameter are examined.

During the course of emissions and fuel economy (FE) testing, vehicles that are calibrated to meet Tier 3 emissions requirements currently must demonstrate compliance on Tier 3 E10 fuel while maintaining emissions capability with Tier 2 E0 fuel used for FE label determination. Tier 3 emissions regulations prescribe lower sulfur E10 gasoline blends for the U.S. market. Tier 3 emissions test fuels specified by EPA are required to contain 9.54 volume % ethanol and 8-11 ppm sulfur content. EPA Tier 2 E0 test fuel has no ethanol and has nominal 30 ppm sulfur content. Under Tier 3 rules, Tier 2 E0 test fuel is still used to determine FE. Tier 3 calibrations can have difficulty meeting low Tier 3 emissions targets while testing with Tier 2 E0 fuel. Research has revealed that the primary cause of the high emissions is deactivation of the aftertreatment system due to sulfur accumulation on the catalysts.

A three-way catalytic converter (TWC) is an emissions control device, used to treat the exhaust gases in a gasoline engine. The conversion efficiency of the catalyst, however, drops with age or customer usage and needs to be monitored on-line to meet the on board diagnostics (OBD II) regulations. In this work, a non-intrusive catalyst monitor is developed to diagnose the track the remaining useful life of the catalyst based on measured in-vehicle signals. Using air mass and the air-fuel ratio (A/F) at the front (upstream) and rear (downstream) of the catalyst, the catalyst oxygen storage capacity is estimated. The catalyst capacity and operating exhaust temperature are used as an input features for developing a Support Vector Machine (SVM) algorithm based classifier to identify a threshold catalyst. In addition, the distance of the data points in hyperspace from the calibrated threshold plane is used to compute the remaining useful life left.

Pilot injection has been used widely in diesel engines for its NOx and noise reducing characteristics. In this paper, its impacts to the particle emissions were studied using a light-duty common-rail Euro 4 diesel engine with different pilot injection strategies. Three steady-state engine modes were selected from the EU legislative diesel engine test cycle to represent low, medium and high engine speeds and loads. The quantities and injection timings of the pilot injection strategies were then varied. The particle number concentration and size distributions were investigated along with the smoke and regulated gas emissions such as the NOx trade-off. These results indicate how a pilot injection alongside a main injection can increase the particle size compared to a single main injection event. Furthermore, the split injection was closely related to the engine mode.

The use of urea-based selective catalytic reduction (SCR) is a promising method for achieving U.S. Tier 2 diesel emission standards for NOx. To meet the Tier 2 standards for Particulate Matter (PM), a catalyzed diesel particulate filter (CDPF) will likely be present and any ammonia (NH3) that is not consumed over an SCR catalyst would pass over the CDPF to make nitrous oxide (N2O) emissions and/or oxides of nitrogen (NOx), or exit the exhaust system as NH3. N2O is undesirable due to its high greenhouse gas potential, while NOx production from the slipped NH3 would reduce overall system NOx conversion efficiency. This paper reviews certain conditions where NH3 slip past an SCR system may be a concern, looks at what would happen to this slipped NH3 over a CDPF, and evaluates the performance of various supplier NH3 slip catalysts under varied space velocities, temperatures and concentrations of NH3 and NOx.

Exhaust gas recirculation (EGR) coolers are used on diesel engines to reduce peak in-cylinder flame temperatures, leading to less NOx formation during the combustion process. There is an ongoing concern with soot and hydrocarbon fouling inside the cold surface of the cooler. The fouling layer reduces the heat transfer efficiency and causes pressure drop to increase across the cooler. A number of experimental studies have demonstrated that the fouling layer tends to asymptotically approach a critical height, after which the layer growth ceases. One potential explanation for this behavior is the removal mechanism derived by the shear force applied on the soot and hydrocarbon deposit surface. As the deposit layer thickens, shear force applied on the fouling surface increases due to the flow velocity growth. When a critical shear force is applied, deposit particles start to get removed.

A laboratory aging study was performed on samples of a lean NOx trap with platinum group metal (PGM) loadings of 0.53, 1.06, 2.12, and 3.18 g/liter. The LNT samples were aged at inlet temperatures of 650°C, 750°C, 800°C, and 850°C behind samples of a three-way catalyst that were aged on a pulse-flame combustion reactor with a Ford-proprietary durability schedule representing 80,000 km of customer use. For all aging temperatures, higher PGM loadings were beneficial for low temperature NOx performance, attributable to an increase in the oxidation of NO to NO2. Conversely, lower PGM loadings were beneficial for high temperature NOx performance after aging at 650°C and 750°C, as higher loadings promoted the decomposition of the nitrates during lean operation and thereby decreased the NOx storage capability at high temperatures. Also, higher PGM loadings increased the OSC of the trap and thereby increased the purge requirements.

Selective Catalytic Reduction of NOx is a promising technology to enable diesel engines to meet certification under Tier 2 Bin 5 emissions requirements. SCR catalysts for vehicle use are typically zeolitic materials known to store both hydrocarbons and ammonia. Ammonia storage on the zeolite has a beneficial effect on NOx conversion; hydrocarbons however, compete with ammonia for storage sites and may also block access to the interior of the zeolites where the bulk of the catalytic processes take place. This paper presents the results of laboratory studies utilizing surrogate hydrocarbon species to simulate engine-out exhaust over catalysts formulated to operate in both low (≈175-500°C) and high temperature (≈250-600°C) regimes. The effects of hydrocarbon exposure of these individual species on the SCR reaction are examined and observations are made as to necessary conditions for the recovery of SCR activity.

Swirl plane Particle Image Velocimetry (PIV) measurements were performed in a single-cylinder optically accessible gasoline direct injection (DISI) engine using a borescope introduced through the spark plug hole. This allowed the use of a contoured piston and the visualization of the flow field in and around the piston bowl. The manifold absolute pressure (MAP) was fixed at 90 kPa and the engine speed was varied in increments of 250 rpm from 750 rpm to 2000 rpm. Images were taken from 270° to 320° bTDC of compression at 10° intervals to study the evolution of the velocity fluctuations. Measurements were performed with and without fuel injection to study its effect on the in-cylinder flow fields. Fuel was injected at 10 MPa and 5 MPa. The 2-D spatial mean velocities of individual flow fields and their decompositions were averaged over 100 cycles and used to investigate the effects of engine speed and image timing on the flow field.

FTP emissions tests on a passenger vehicle equipped with a 1.8 L IDI turbo-charged diesel engine show that the mass emissions of particles decrease by (36±8)% when 16.6% dimethoxymethane (DMM) by volume is added to a diesel fuel. Particle size measurements reveal log-normal accumulation mode distributions with number weighted geometric mean diameters in the 80 - 100 nm range. The number density is comparable for both base fuel and the DMM/diesel blend; however, the distributions shift to smaller particle diameter for the blend. This shift to smaller size is consistent with the observed reduction in particulate mass. No change is observed in NOx emissions. Formaldehyde emissions increase by (50±25)%, while emissions of other hydrocarbons are unchanged to within the estimated experimental error.

Using local emissions measurements immediately downstream of a close-coupled catalyst, spatial variations in emissions have been analysed for close-coupled catalysts with different ageing histories. Comparison of the radial emissions profiles between a uniformly-aged (oven-aged) catalyst and two vehicle-aged parts suggests that the vehicle-aged parts have substantial variations in catalyst damage across the radius of the catalyst. The radial variations in damage were confirmed by bench reactor and post-mortem studies. The radial catalyst damage profiles inferred from engine-based evaluations of vehicle aged catalysts show broad correlation with high flow areas identified by CFD predictions and high temperature regions as measured during engine tests.

It is anticipated that future gasoline engines will have improved mechanical efficiency and consequently lower exhaust temperatures at low load conditions, although the exhaust temperatures at high load conditions are expected to remain the same or even increase due to the increasing use of downsized turbocharged engines. In 2014, a collaborative project was initiated at Ford Motor Company, Oak Ridge National Lab, and the University of Michigan to develop three-way catalysts with improved performance at low temperatures while maintaining the durability of current TWCs. This project is funded by the U.S. Department of Energy and is intended to show progress toward the USDRIVE target of 90% conversion of hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx) at 150 °C after high mileage aging. The testing protocols specified by the USDRIVE ACEC team for stoichiometric S-GDI engines were utilized during the evaluation of experimental catalysts at all three facilities.

In anticipation that future gasoline engines will have improved fuel efficiency and therefore lower exhaust temperatures during low load operation, a project was initiated in 2014 to develop three-way catalysts (TWC) with improved activity at lower temperatures while maintaining the durability of current TWCs. This project is a collaboration between Ford Motor Company, Oak Ridge National Laboratory, and the University of Michigan and is funded by the U.S. Department of Energy. The ultimate goal is to show progress towards the USDRIVE goal of 90% conversion of hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx) at 150°C after high mileage aging. A reactor was set up at Ford to follow the catalyst testing protocols established by the USDRIVE ACEC tech team for evaluating catalysts for stoichiometric gasoline direct-injection (S-GDI) engines; this protocol specifies a stoichiometric blend of CO/H2, NO, C3H6, C2H4, C3H8, O2, H2O, and CO2 for the evaluations.