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As automotive exhaust emission levels reduce, there is a need for increased sensitivity of the NOx measurement. This paper documents work performed to increase the sensitivity of the existing Rosemount NGA 2000 CLD Analyzer. The effects of sample flow rate, ozone flow rate and ozone supply gas were explored. Limit of Detection (LOD) and Converter Efficiency were evaluated. The goal of this optimization has been to provide a cost effective and expeditious method to improve the low level NOx measurement. Changing the ozone generator supply gas from air to oxygen and increasing the sample and ozone flow rates resulted in a LOD improvement from 17 ppb to 8 ppb.

Diesel engines offer better fuel economy compared to their gasoline counterpart, but simultaneous control of NOx and particulates is very challenging. The blended 2-way SCR/DPF is recently emerging as a compact and cost-effective technology to reduce NOx and particulates from diesel exhaust using a single aftertreatment device. By coating SCR catalysts on and inside the walls of the conventional wall-flow filter, the 2-way SCR/DPF eliminates the volume and mass of the conventional SCR device. Compared with the conventional diesel aftertreatment system with a SCR and a DPF, the 2-way SCR/DPF technology offers the potential of significant cost saving and packaging flexibility. In this study, an engine dynamometer test cell was set up to repeatedly load and regenerate the SCR/DPF devices to mimic catalyst aging experienced during periodic high-temperature soot regenerations in the real world.

When hydrogen is added to a gasoline fueled spark ignition engine the lean limit of the engine can be extended. Lean running engines are inherently more efficient and have the potential for significantly lower NOx emissions. In the engine concept examined here, supplemental hydrogen is generated on-board the vehicle by diverting a fraction of the gasoline to a plasmatron where a partial oxidation reaction is initiated with an electrical discharge, producing a plasmatron gas containing primarily hydrogen, carbon monoxide, and nitrogen. Two different gas mixtures were used to simulate the plasmatron output. An ideal plasmatron gas (H2, CO, and N2) was used to represent the output of the theoretically best plasmatron. A typical plasmatron gas (H2, CO, N2, and CO2) was used to represent the current output of the plasmatron. A series of hydrogen addition experiments were also performed to quantify the impact of the non-hydrogen components in the plasmatron gas.

A fully flexible valve actuation (FFVA) system was developed for a single cylinder research engine to investigate high efficiency clean combustion (HECC) in a diesel engine. The main objectives of the study were to examine the emissions, performance, and combustion characteristics of the engine using late intake valve closing (LIVC) to determine the benefits and limitations of this strategy to meet Tier 2 Bin 5 NOx requirements without after-treatment. The most significant benefit of LIVC is a reduction in particulates due to the longer ignition delay time and a subsequent reduction in local fuel rich combustion zones. More than a 95% reduction in particulates was observed at some operating conditions. Combustion noise was also reduced at low and medium loads due to slower heat release. Although it is difficult to assess the fuel economy benefits of LIVC using a single cylinder engine, LIVC shows the potential to improve the fuel economy through several approaches.

Three-way catalysts provide a means of catalytically achieving lower NOx emission levels while maintaining good control of HC and CO emissions. However, very accurate control of air-fuel ratio is necessary. The precise air-fuel ratio control required is accomplished by employing a closed loop fuel metering system in conjunction with an exhaust gas sensor and an electronic control unit. To gain production experience with this type of system, General Motors is introducing it on two 1978 engine families sold in California. One is a 2.5 litre L-4 engine and the other is a 3.8 litre V-6 engine. Closed loop controlled carburetors are used on both systems. This paper discusses these 1978 systems. The components used on both systems are described and emission and fuel economy results are reviewed.

The stringent 1978 emission standards of 0.41 gm/mi HC, 3.4 gm/mile CO, and 0.4 gm/mi NOx may require the use of a dual catalytic converter system (reducing and oxidizing catalyst). These emission requirements have been achieved at low mileage with such a system, but it is complex and has exhibited poor durability. This system also results in the loss of fuel economy at the 1978 emission levels.

The Automotive Industry/Government Emissions Research CRADA (AIGER) has been working to develop a new methodology for the direct determination of nonmethane hydrocarbons (DNMHC) in vehicle testing. This new measurement technique avoids the need for subtraction of a separately determined methane value from the total hydrocarbon measurement as is presently required by the Code of Federal Regulations. This paper will cover the historical aspects of the development program, which was initiated in 1993 and concluded in 2002. A fast, gas chromatographic (GC) column technology was selected and developed for the measurement of the nonmethane hydrocarbons directly, without any interference or correction being caused by the co-presence of sample methane. This new methodology chromatographically separates the methane from the nonmethane hydrocarbons, and then measures both the methane and the backflushed, total nonmethane hydrocarbons using standard flame ionization detection (FID).

Superior fuel economy was achieved for a small-displacement spark-ignition direct-injection (SIDI) engine by optimizing the stratified combustion operation. The optimization was performed using computational analyses and subsequently testing the most promising configurations experimentally. The fuel economy savings are achieved by the use of a multihole injector with novel spray shape, which allows ultra-lean stratification for a wide range of part-load operating conditions without compromising smoke and hydrocarbon emissions. In this regard, a key challenge for wall-controlled SIDI engines is the minimization of wall wetting to prevent smoke, which may require advanced injection timings, while at the same time minimizing hydrocarbon emissions, which may require retarding injection and thereby preventing over-mixing of the fuel vapor.

Experimentally obtained combustion responses of a typical reverse-tumble wall-controlled direct-injection stratified-charge engine to operating variables are described. During stratified-charge operation, the injection timing, ignition timing, air-fuel ratio, and levels of exhaust gas recirculation (EGR) generally determine the fuel economy and emissions performance of the engine. A detailed heat-release analysis of the experimental cylinder-pressure data was conducted. It was observed that injection and ignition timings determine the thermal efficiency of the engine by controlling primarily the combustion efficiency of the stratified charge. Hence, combustion phasing is determined by a compromise between work-conversion efficiency and combustion efficiency. To reduce nitric-oxide (NOx) emissions, a reduction in overall air-fuel ratio as well as EGR addition is required.

The equipment for collecting dilute exhaust samples involves the use of bag materials (i.e., Tedlar®) that emit hydrocarbons that contaminate samples. This study identifies a list of materials and treatments to produce bags that reduce contamination. Based on the average emission rates, baked Tedlar®, Capran® treated with alumina deposition, supercritical CO2 extracted Kynar® and supercritical CO2 extracted Teflon NXT are capable of achieving the target hydrocarbon emission rate of less than 15 ppbC per 30 minutes. CO2 permeation tests were also performed. Tedlar, Capran, Kynar and Teflon NXT showed comparable average permeation rates. Based on the criteria of HC emission performance, changes in measured CO2 concentration, ease of sealing, and ease of surface treatment, none of the four materials could be distinguished from one another.