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Biodiesel has become a major alternative fuel for automotive applications demonstrated by its increasing presence in the market place. This paper summarizes test results for recently collected retail samples of biodiesel (B100) and blended biodiesel from the U.S. and the European Union to provide a snap shot of current fuel quality in each market. Properties reported included biodiesel content, oxidation stability, acid number, water, metals, and glycerin content. For B100, only total contamination measured as particulates was significantly lower for the EU than the U.S. For blends containing up to 5% biodiesel, there were significant differences between the U.S. and the EU in sulfur content, oxidation stability (Rancimat), cetane number, and cloud point. For blends higher than B5, present only in the U.S., pump labeling was found to be a poor indicator of biodiesel content.

A seat belt usability study was conducted to investigate factors associated with seat belt comfort and convenience related to shoulder belt contact pressure, shoulder belt fit, and seat belt upper anchorage location. Two major objectives were addressed in this study: (1) Determine the shift in the contact pressure while changing the seat back angle and seat belt attachment points / B-pillar location by utilizing a body pressure measurement system; (2) Identify how seat belt contact pressure and fit affect users' subjective feeling of comfort. Results from the statistical analysis shows that the seat belt contact pressure increases when the D-ring moves away from the driver in the fore-aft direction (X-axis) whereas height adjustment of the D-ring (Z-axis) is not statistically significant in terms of pressure distribution.

The E-35 “Running Loss” program was planned in the fall of 1996, and conducted in the summer of 1997, as the third part of a series of Coordinating Research Council (CRC) sponsored evaporative emission test programs. One hundred and fifty vehicles (half cars - half light duty trucks) were recruited at a local I/M lane, and tested for running loss emissions at the ATL Facility in Mesa, AZ. The previous CRC programs had studied hot soak, and then diurnal emissions. Running loss emissions were measured in a Running Loss SHED (RL-SHED) for a 25 minute, 7.5 mile trip on a hot summer day (95°F). Vehicles from model years 1971 through 1991 were tested. A wide range in emission levels was observed - from a low of 0.13 g/mile to 43 g/mile. The test results were not able to establish whether car emissions are different, or the same, as light duty trucks. The major causes of the high emissions were liquid leaks on carburetor equipped models.

As part of the Auto/Oil Air Quality Improvement Research Program (AQIRP), a fleet of 299 1983-1993 “real world” light duty vehicles and trucks were acquired from inspection and maintenance (I/M) lanes and tested at prevailing ambient temperatures for their hot soak emissions for the first hour after the engine was turned off. When found, high-emitters were repaired and retested to quantify the effectiveness of the repairs. Also, I/M pressure-purge tests were performed to determine whether such tests could properly identify high-emitting vehicles. Measured hot soak emissions ranged from less than 0.1g HC to as high as 49g HC. Twenty percent of the vehicles tested accounted for nearly 80 percent of the total hot soak emissions, with no single common hardware component identified as the primary cause.

Segmented, Silicon-Carbide Diesel Particulate Filters appear to be automotive industry's popular choice for reducing particulate emissions of Diesel Engines, particularly for light duty platforms. Since flow resistance represents an important performance feature of a filter, it is important that reasonable prediction tools for such filters are developed for use in their development, design, applications and regeneration control. A model for predicting pressure drop of segmented filters is presented here: an existing, well-accepted pressure drop model for monolithic (non-segmented) filters is customized to one for a segmented filter using a ‘weighted number of inlet channels’ based on equivalent filtration wall area of a monolithic filter. Flow resistance data collected experimentally on segmented filters are used to demonstrate the accuracy of the new model.

A new single-brick Ba + alkali metals NOx-Trap catalyst has been developed to replace a two-brick NOx-Trap system containing a downstream three-way catalyst. Major development efforts include: 1) platinum group metals selection for higher HC oxidation with potassium-containing washcoat, 2) alumina and ceria selection, and Rh architecture design for more efficient NOx reduction and 3) NiO to suppress H2S odor. Mitsubishi Motors' 1.8L GDI™ with this Delphi new NOx-Trap catalyst with H2S control achieves J-LEV standard with less cost and lower backpressure compared to the previous model. It is further discovered that incorporation of NiO into the NOx-Trap washcoat is effective for H2S control during sulfur purge but has a negative impact on thermal durability and sulfur resistance. Further study to improve this trade-off has been made and preliminary results of an advanced washcoat design are presented in this paper. Details will be reported in a future publication.

The intensity of a combustion flame ionization current signal (ionsense) can be used to monitor and control combustion in individual cylinders during a cold engine start. The rapid detection of poor or absence of combustion can be used to determine fuel delivery corrections that may prevent engine stalls. With the ionsense cold start control active, no start failures were recorded even when the initially (prior to ionsense correction) commanded fueling had failed to produce a combustible mixture. This new dimension in fuel control allows for leaner cold start calibrations that would still be robust against the possible use of low volatility gasoline. Consequently, when California Phase 2 fuel is used, cold start hydrocarbon emissions could be lowered without the risk of an engine stall if the appropriate fuel is replaced with a less volatile one.

The causes of Unburned Hydrocarbon (UHC) emissions from a premixed compression ignited engine were investigated for both homogeneous and stratified charge conditions. A fast response Flame Ionization Detector (fast FID) was used to provide cycle-resolved UHC exhaust emission measurements. These fast FID UHC measurements were coupled with numerical flow simulation results to provide quantitative and qualitative insight into the sources of UHC emissions. The combined results were used to evaluate the effects of engine load, local gas temperatures, fuel stratification, and crevice quenching on UHC emissions.

As diesel emission regulations continue to increase, the use of exhaust aftertreatment systems containing, for example the diesel oxidation catalyst (DOC) and diesel particulate filter (DPF) will become necessary in order to meet these stringent emission requirements. The addition of a DOC and DPF in conjunction with utilizing biodiesel fuels requires extensive research to study the implications that biodiesel blends have on emissions as well as to examine the effect on aftertreatment devices. The proceeding work discusses results from a 2006 VM Motori four-cylinder 2.8L direct injection diesel engine coupled with a diesel oxidation catalyst and catalyzed diesel particulate filter. Tests were done using ultra low sulfur diesel fuel blended with 20% choice white grease biodiesel fuel to evaluate the effects of biodiesel emission products on the performance and effectiveness of the aftertreatment devices and the effect of low temperature combustion modes.

Zinc dithiophosphate, or ZDP, for over 60 years has been used as an additive in engine oils to provide wear protection and oxidation stability in an efficient and cost effective manner. Unfortunately, ZDP contains phosphorus, and phosphorus is a widely known and accepted poison of automotive catalysts and other emissions system components. Because of this, phosphorus (and ZDP) levels in automotive engine oils have been gradually reduced by about 35% over the last 10-15 years, and further reductions are likely in the future. This paper traces the history of ZDP use in automotive engine oils, and addresses the issue of how much (if any) ZDP is actually required to provide wear protection in today's, as well as yesterday's, engines. The focus in the paper is on wear (including scuffing) protection, and not on the other aspects of ZDP performance, such as providing oxidation stability of the oil.

With increasingly stringent emissions regulations and concurrent requirements for enhanced engine thermal efficiency, a comprehensive characterization of the automotive gasoline fuel spray has become essential. The acquisition of accurate and repeatable spray data is even more critical when a combustion strategy such as gasoline direct injection is to be utilized. Without industry-wide standardization of testing procedures, large variablilities have been experienced in attempts to verify the claimed spray performance values for the Sauter mean diameter, Dv90, tip penetration and cone angle of many types of fuel sprays. A new SAE Recommended Practice document, J2715, has been developed by the SAE Gasoline Fuel Injection Standards Committee (GFISC) and is now available for the measurement and characterization of the fuel sprays from both gasoline direct injection and port fuel injection injectors.

A single-cylinder engine was used to study the potential of a high-efficiency combustion concept called gasoline direct-injection compression-ignition (GDCI). Low temperature combustion was achieved using multiple injections, intake boost, and moderate EGR to reduce engine-out NOx and PM emissions engine for stringent emissions standards. This combustion strategy benefits from the relatively long ignition delay and high volatility of regular unleaded gasoline fuel. Tests were conducted at 6 bar IMEP - 1500 rpm using various injection strategies with low-to-moderate injection pressure. Results showed that triple injection GDCI achieved about 8 percent greater indicated thermal efficiency and about 14 percent lower specific CO2 emissions relative to diesel baseline tests on the same engine. Heat release rates and combustion noise could be controlled with a multiple-late injection strategy for controlled fuel-air stratification. Estimated heat losses were significantly reduced.

A direct injection-gasoline (DI-G) system was applied to a heavy-duty diesel-type engine to study the effects of charge stratification on the performance of premixed compression ignited combustion. The effects of the fuel injection parameters on combustion phasing were of primary interest. The simultaneous effects of the fuel stratification on Unburned Hydrocarbon (UHC), Oxides of Nitrogen (NOx), Carbon Monoxide (CO), and smoke emissions were also measured. Engine tests were conducted with altered injection parameters covering the entire load range of normally aspirated Homogeneous Charge Compression Ignited (HCCI) combustion. Combustion phasing tests were also conducted at several engine speeds to evaluate its effects on a fuel stratification strategy.

The focus of this paper is to understand, from experimental data, the R134a refrigerant emission rates of various hose materials due to permeation. This paper focuses on four main points for hose assembly emission of R134a: (1) characteristics of hose permeation in response to the effect of oil in R134a and the characteristics of hose permeation of vapor vs. liquid refrigerant; (2) conditioning of the hose material over time to reach steady state R134a emission; (3) the relative contribution of hose permeation and coupling emission to the overall hose assembly refrigerant emission; (4) transient emission rates due to transient temperature and pressure conditions. Studies include hoses with different materials and constructions resulting in various levels of R134a permeation.

With the requirements for reducing the emissions and improving the fuel economy, the automotive companies are developing hybrid, 42 V and fuel cell vehicles. Power electronics is an enabling technology for the development of environmental friendly vehicles, and to implement the various vehicle electrical architectures to obtain the best performance. In this paper, the requirements of the power semiconductor devices and the criteria for selecting the power devices for various types of low emission vehicles are presented. A comparative study of the most commonly used power devices is presented. A brief review of the future power devices that would enhance the performance of the automotive power conversion systems is also presented.

Tier 2 Emission standards enacted by the U.S. Environmental Protection Agency (EPA) require substantial emission reductions for new vehicles, including those with diesel engines. The standards are fuel neutral, and all light duty vehicles must eventually meet a fleet averaged emission level of Bin 5. To improve the emission capability for diesel engines, several advanced technologies have been investigated. These technologies include: common rail FIE with multi-injection capability, enhanced cooled EGR system with increased flow capability, variable geometry turbo charger, and a lower compression ratio piston. A new combustion approach using premixed diesel combustion was applied in the low load area for improving NOx and soot emissions significantly in the FTP-75 test cycle. Applying these technologies, engine out NOx was substantially reduced while maintaining similar soot levels.

Global demand for alternative fuels to combat rising energy costs has sparked a renewed interest in catalysts that can effectively remediate NOx emissions resulting from combustion of a range of HC based fuels. Because many of these new engine technologies rely on lean operating environments to produce efficient power, the resulting emissions are also present in a lean atmosphere. While HCs are easily controlled in such environments, achieving high NOx conversion to N2 has continued to elude fully satisfactory solution. Until recently, most approaches have relied on catalysts with precious metals to either store NOx and subsequently release it as N2 under rich conditions, or use NH3 SCR catalysts with urea injection to reduce NOx under lean conditions. However, new improvements in Ag based technologies also look very promising for NOx reduction in lean environments.

Regulatory and market pressures continue to challenge the automotive industry to develop technologies focused on reducing exhaust emissions and improving fuel economy. This paper introduces a practical model, which evaluates the economic value of various technologies based on their ability to reduce fuel consumption, improve emissions or provide consumer benefits such as improved performance. By evaluating the individual elements of economic value as viewed by the OEM manufacturer, while keeping the end consumer in mind, technology selection decisions can be made. These elements include annual fuel usage, vehicle performance, mass reduction and emissions, among others. The following technologies are discussed and evaluated: gasoline direct injection, variable valvetrain technologies, common-rail diesel and hybrid vehicles.

Low-cost lean NOx aftertreatment is one of the main challenges facing high-efficiency gasoline and diesel engines operating with lean mixtures. While there are many candidate technologies, they all offer tradeoffs. We have investigated a multi-component Dual SCR aftertreatment system that is capable of obtaining NOx reduction efficiencies of greater than 90% under lean conditions, without the use of precious metals or urea injection into the exhaust. The Dual SCR approach here uses an Ag HC-SCR catalyst followed by an NH3-SCR catalyst. In bench reactor studies from 150 °C to 500 °C, we have found, for modest C/N ratios, that NOx reacts over the first catalyst to predominantly form nitrogen. In addition, it also forms ammonia in sufficient quantities to react on the second NH3-SCR catalyst to improve system performance. The operational window and the formation of NH3 are improved in the presence of small quantities of hydrogen (0.1–1.0%).

Computer controls are increasingly being employed in systems ranging from simple to very complex. A new trend is to extend these computer systems to include monitoring schemes to detect malfunctions. An example is provided by new automobiles sold in the US, Canada, and Europe. By law they must include “on-board diagnostics” designed to detect certain malfunctions in the powertrain system that may cause excessive emissions. The present article outlines some of the fundamental concepts of system's monitoring and general principles for the design of such monitors.