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A new heat-resistant cast iron alloy has been developed for the exhaust manifolds of new passenger-car diesel engines. This development occurred because operating demands on exhaust manifolds have increased significantly over the past decade. These demands are due to higher exhaust gas temperatures resulting from tighter emission requirements, improved fuel efficiencies, and designs for higher specific engine power. These factors have led to much higher elevated temperature strength and oxidation resistance requirements on exhaust manifold alloys. Additionally, thermal fatigue that occurs directly as a result of thermal expansions and mechanical constraint has become an increasingly important issue. The research detailed in this paper focused on the optimization of the chemical composition of a Si-Mo ductile iron to improve the mechanical and physical properties for use in an engine exhaust manifold.

The present study focused on CrN-Cu nanocoatings composed of nano-meter grains with CrN, Cr and Cu functioning low-friction, anti-wear and heat resistance. The coatings were synthesized by hybrid PVD including metal arc source, magentron sputter source and ion-gun source. Although Cu has low hardness, the hardness of CrNCu is not declined because it was composed of below 20nm sized grains of CrN, Cr, and Cu. However, CrN-Cu had lower friction than CrN owing to Cu’s low shear strength. CrN-Cu films optimized using the Reaction Surface Method (RSM) showed the excellent tribological behavior and low coefficient of friction compared with DLC. The tribological properties of the Cr-Cu-N demonstrated superior wear resistance and low friction at normal and high temperature conditions. The CrN-Cu nanocoatings can be used for the downsizing automotive engines working at severe tribological conditions.