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As the late combustion phase in SI engines is of high importance for a further reduction of fuel consumption and especially emissions, the impacts of unburnt mass, located in a small volume with a relatively large surface near the wall and in the top land volume, is of high relevance throughout the range of operation. To investigate and quantify the respective interactions, a state of the art Mercedes-Benz single cylinder research SI-engine was equipped with extensive measurement technology. To detect the axial and radial temperature distribution, several surface thermocouples were applied in two layers around the top land volume. As an additional reference, multiple surface thermocouples in the cylinder head complement the highly dynamic temperature measurements in the boundary zones of the combustion chamber.