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Engines and fuels for transport as well as off-road applications are facing a double challenge: bring local pollution to the level requested by the most stringent city air quality standard reduce CO2 emission in order to minimize the global warming risk. These goals stimulate new developments both of conventional and alternative engines and fuels technologies. New combustion processes known as Controlled Auto-Ignition (CAI™) for gasoline engine and Homogeneous Charge Compression Ignition (HCCI) for Diesel engine are the subject of extensive research world wide and particularly at IFP for various applications such as passenger cars, heavy-duty trucks and buses as well as small engines. Because of the thermo-chemistry of the charge, the thermal NOx formation and the soot production are in principle much lower than in flames typical of conventional engines.