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From the point of global and local environment, internal combustion engine is facing the need for significant improvement of exhaust emission. Especially, important is the reduction of unburned hydrocarbon (HC) from fuel film on liner under cold condition. In this study, at first, quantitative fuel film measurement technique by using Laser Induced Exciplex Fluorescence (LIEF) was developed. For the light source, 4th harmonic pulse yttrium aluminum garnet (YAG) laser (266nm) was used. For the tracer, the combination of N,N-Dimethylaniline (DMA) and naphthalene was used and quantitative concentration was decided by calibration test. With LIEF, the distribution of fuel film can be obtained by measuring the fluorescence only from the liquid phase. In order to evaluate the effect of fuel film on exhaust HC emission from engine, the film distribution was measured using quartz glass liner. For the injector, a prototype 6-hole gasoline injector was used.

To prevent global warming, many countries are making efforts to reduce CO2 emissions toward achieving 2050 carbon neutrality. In order to reduce CO2 concentration quickly, in addition to spread of renewable energy and expansion of BEV, it is also important to reduce CO2 emissions by improving thermal efficiency of ICE (internal combustion engine) and utilizing carbon neutral fuels such as synthetic fuels and biofuels. It is well known that lean burn is an effective technology to increase thermal efficiency of engine highly. However, since NOx emission from lean burn engine cannot be reduced with three-way catalyst, there have been issues such as complicated system configuration due to the addition of NOx reduction catalyst or limiting lean operation to narrow engine speed and load in order to meet emission regulation of each country.

Combustion of a lean air-fuel mixture diluted with a large amount of air or Exhaust Gas Recirculation (EGR) gas is one of the important technologies that can reduce thermal NOx and improve gasoline engine fuel economy by reducing cooling loss. On the other hand, lean combustion increases unburned Hydro Carbon (HC) and unburned loss compared to stoichiometric combustion. This is because lean combustion reduces the burning rate of the air-fuel mixture and forms a thick quenching layer near the wall surface. In this study, the relationship between the thickness of the unburned HC and the excess air ratio is analyzed using Laser Induced Fluorescence (LIF) method and Computational Fluid Dynamic (CFD) of combustion. The HC distribution near the engine liner when the excess air ratio is increased is investigated by LIF. As a result, it is found that the quenching distance of the flame in the cylinder is larger for lean conditions than the general single-wall quenching relationship.