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Technical Paper

Lubricants Formulation Technology for Fuel Saving Performance in Automatic Transmissions

2015-09-01
2015-01-2037
The use of Automatic Transmission Fluids (ATFs) with lower viscosity and excellent anti-shudder durability for wet clutch system will be effective for improving fuel saving performance in automatic transmissions. In this study, two ATF formulation techniques were examined. The first trial formulation is to improve fatigue life in gear components even if a lower viscosity ATF is used. The second one is to improve anti-shudder durability for wet lock-up clutch system in AT units. As to fatigue life performance, the relation between molecular weight of Viscosity Index Improver (VII) and film formation property in EHL contact regions were experimentally investigated. ATFs containing VIIs with lower molecular weight tend to increasing EHL film thickness, resulting in a longer gear pitting fatigue life. Calcium detergents and ashless friction modifiers in ATFs were found to give a great impact on the anti-shudder performance.
Technical Paper

Development of a Rh-Intelligent Catalyst

2006-04-03
2006-01-0851
We have developed a Pd-intelligent catalyst with a self-regenerative function that is realized by the passage of Pd through consecutive solid solution and segregation states in and out of a perovskite crystal, and commercialized it for the first time in the world [1, 2, 3, 4, 5, 6, 7, 8 and 9]. In this study, we investigated the self-regenerative function of Rh as an alternative for Pd, in two types of Rh-perovskite (LaFeRhO3 and CaTiRhO3), and found that a CaTiRhO3 perovskite has an excellent capacity for the self-regenerative function of Rh. In a LaFeRhO3 perovskite with a composition similar to the Pd-perovskite (LaFePdO3), Rh was fixed so stably in the perovskite structure that it hardly segregated from the perovskite even in high temperature reduction atmospheres. However, in the CaTiRhO3 perovskite, with its A2+B4+O3 formula, the amount of Rh that actually segregated increased greatly in reduction atmospheres.
Technical Paper

Design of a Practical Intelligent Catalyst

2003-03-03
2003-01-0813
We have reported the innovation of “An Intelligent Catalyst” which has the function for self-regeneration of Pd realized through the solid solution and segregation of Pd in a perovskite crystal [1, 2, 3, 4 and 5]. We have looked for a design configuration for LaFePdO3 perovskite in the washcoat by comparing single and double layer washcaots as well as different loading locations for precious metals in order to maximize the Intelligent Catalyst's function in the practical conditions. The catalysts were attached to an engine exhaust system and subjected to an accelerated aging. The bed temperature of the catalysts reached to 1050 °C. The performance of the catalysts was evaluated on the engine dynamometer. Catalytic activity and long durability were improved by development of the washcoat configuration. The optimum design of the washcoat was double-layer with a tri-metal (Pt, Rh and Pd) system. The perovskite was located in the lower layer.
Technical Paper

A Hexa-Aluminate Automotive Three-Way Catalyst

2002-03-04
2002-01-0736
With emission regulations getting tighter and tighter, catalysts will need to be active at ever lower temperatures in order to meet future standards. To meet this need, automotive catalysts are being installed closer to the engine so as to be active immediately after start-up. In this location, catalysts must have high temperature durability. In this paper, we examined a heat-resistant support material, “hexa-aluminate”, for possible use in future automotive catalysts. Catalytic activity of hexa-aluminate was more better than La added γ - alumina after redox treatment in model gas and after engine aging. Since hexa-aluminate had the excellent thermal durability, and Pd, which are supported on it, maintains finer particles than those on La added γ-alumina. We suggest that hexa-aluminate is a effective support material for automotive catalysts. More specifically, hexa-aluminate is expected to be a key technology for meeting the stringent emission standards of the future.
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