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The current research focuses on enhancing the performance of Si solar cells by using Er2O3 (Erbium Oxide) in cubic crystalline nature serves as an anti-reflection coating material. An anti-reflective coating aims to improve the Efficient Power Conversion (EPC) of polycrystalline silicon wafers solar cells (PSSC) utilised in solar roof panels of the automotive sector. It also exhibits superior light transmittance and least light reflectance, which eventually leads to the increase EPC. Erbium oxide helps to convert low energy photons into high energy photons. The incident photons, which lies on the solar cell, gradually losses its energy to travel in a denser medium and dissipate in the form of heat energy. In order to overcome the rate of reflection, current research aims in synthesis of erbium oxide nanosheets using electrospinning deposition technique for varying deposition timings such as 1, 1.5 and 2 hours.