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Hydrogen exhibits the notable attribute of lacking carbon dioxide emissions when used in internal combustion engines. Nevertheless, hydrogen has a very low energy density per unit volume, along with large emissions of nitrogen oxides and the potential for backfire. Thus, stratified charge combustion (SCC) is used to reduce nitrogen oxides and increase engine efficiency. Although SCC has the capacity to expand the lean limit, the stability of combustion is influenced by the mixture formation time (MFT), which determines the equivalence ratio. Therefore, quantifying the equivalence ratio under different MFT is critical since it determines combustion characteristics. This study investigates the viability of using a Laser Induced Breakdown Spectroscopy (LIBS) for measuring the jet equivalence ratio. Furthermore, study was conducted to analyze the effect of MFT and the double injection parameter, namely the dwell time and split ratio, on the equivalence ratio.

Owing to climate change issues caused by global warming, the role of alternative fuels, such as low-carbon and non-carbon fuels, is becoming increasingly important, particularly in the transportation sector. Therefore, hydrogen has emerged as a promising fuel for internal combustion engines because it does not emit carbon dioxide. Direct injection is mandatory for hydrogen-based internal combustion engines to mitigate backfires and low energy density. However, there is a lack of measurement of the equivalence ratio methodology because hydrogen has a higher diffusion rate than conventional fuels. The objective of this research is a feasibility study of laser-induced breakdown spectroscopy (LIBs) for measuring the equivalence ratio. The second harmonic ND-YAG laser was implemented to induce the atomic emission of hydrogen via the breakdown phenomenon. Simultaneously, the hydrogen jet structure was visualized in a constant volume vessel using Schlieren imaging.