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In this paper the characteristics of a mixture of glycerol-based ethers usable in a compression ignition engine are investigated, in terms of efficiency and emissions. Alternative pathways for the energetic exploitation of biodiesel derived glycerol became of increasing interest as the biodiesel production was increased worldwide. Because of its detrimental physical and chemical properties, raw glycerol is hardly usable in conventional internal combustion engines (ICE). However, etherification of glycerol with tert-butyl alcohol and isobutylene allows obtaining a mixture mainly composed of higher glycerol ethers (GEM) suitable for compression ignition engines. Thus, the aim of this research study was to test a mixture of mono-, di- and tri-tert-butyl ethers of glycerol in blend with a commercial diesel fuel in a compression ignition engine, evaluating the fuel efficiency and the impact on the pollutant emissions.

Nowadays, alcohol fuels are of increasing interest as alternative transportation biofuels even in compression ignition engines because they are oxygenated and producible in a sustainable way. In this paper, the experimental research activity was conducted on a single cylinder research engine provided with a modern architecture and properly modified in a dual-fuel (DF) configuration. Looking at ethanol the as one of the future environmental friendly biofuels experimental campaign was aimed to evaluate in detail the effect of the use of the ethanol as port injected fuel in diesel engine on the size, morphology, reactivity and chemical features of the exhaust emitted soot particles. The engine tests were chosen properly in order to represent actual working conditions of an automotive light-duty diesel engine. A proper engine Dual-Fuel calibration was set-up respecting prefixed limits on in-cylinder peak firing pressure, cylinder pressure rise, fuel efficiency and gaseous emissions.