Technical Paper
Methane Dedicated Catalysts for Heavy-Duty Natural Gas Engines
1996-05-01
961087
Three developmental catalytic converters, provided by different companies, were tested at the exhaust of a SI (spark ignition) NG (natural gas) engine for bus application. The catalysts were all based on noble metals: Pt (platinum), Pd (palladium), Rh (rhodium) and differed in size, metal loading and active phase composition. Emission evaluation was performed according to the European ECE-R49 procedure (13 mode cycle), in stoichiometric and lean-burn conditions. In addition to regulated emission measurement, speciation of NMHC (non-methane hydrocarbons) and carbonyl compounds was performed. The results showed that all the catalyst compositions considered allowed the European emission limits to be complied when the engine operated in stoichiometric conditions, while the overall best performance in the lean region was obtained on the catalyst with noble metal composition Pd:Rh=21:1.