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Under the current emissions legislation, most of the diesel-powered vehicles have to use Diesel Particulate Filters (DPF) to remove soot particles from the exhaust gas and the accumulated soot particles have to be removed in regular intervals. To initialize the exhaust gas temperature for soot regeneration, diesel fuel is either injected into the combustion chamber in late engine cycle (e.g. post injection) or vaporized and then discharged into the exhaust gas via a dosing device (e.g. fuel vaporizer). Both approaches though require the exothermic catalyst to convert the fuel into thermal energy. For practical reasons, this paper is concentrated on describing how CFD could be used to model the fuel distribution in an aftertreatment system equipped with fuel vaporizer and the exothermic reactions in the catalysts.