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In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

Regulations have been established for the monitoring and reporting of greenhouse gas (GHG) emissions and fuel consumption from the transport sector. Low carbon fuels combined with new powertrain technologies have the potential to provide significant reductions in GHG emissions while decreasing the dependence on fossil fuel. In this study, a lean-burn ethanol-diesel dual-fuel combustion strategy has been used as means to improve upon the efficiency and emissions of a conventional diesel engine. Experiments have been performed on a 2.0 dm3 single cylinder heavy-duty engine equipped with port fuel injection of ethanol and a high-pressure common rail diesel injection system. Exhaust emissions and fuel consumption have been measured at a constant engine speed of 1200 rpm and various steady-state loads between 0.3 and 2.4 MPa net indicated mean effective pressure (IMEP).

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. This report is designed to determine how high biodiesel blends affect oil quality through testing on 2005 regulations engines with DPFs. When blends of 10-20% rapeseed methyl ester (RME) with diesel fuel are employed with 10W-30 engine oil, the oil change interval is reduced to about a half due to a drop in oil pressure. The oil pressure drop occurs because of the reduced kinematic viscosity of engine oil, which resulting from dilution of poorly evaporated RME with engine oil and its accumulation, however, leading to increased wear of piston top rings and cylinder liners.

Compared with diesel fuel, FAME is relatively unstable and readily generates acids such as acetic acid and propionic acid. When FAME-blended diesel fuel is used in existing diesel vehicles, it is important to maintain the concentration of FAME-origin acid in the fuel at an appropriately low level to assure vehicle safety. In the present study, the oxidation of diesel fuel containing 5% FAME is investigated. Several kinds of FAMEs were examined, including reagents such as methyl linoleate and methyl linolenate, as well as commercially available products. The level of acid, peroxide, water, and methanol and the pressure of the testing vessel were measured. The result shows that unsaturated FAMEs that have two or more double bonds are unstable. Also, water is generated by oxidation of FAME blended diesel fuel, accelerating corrosion of the terne sheet.

In this study, a MPT-HFRR (Multi-Pressure/Temperature High-Frequency Reciprocating Rig) was manufactured based on a diesel fuel lubricity test apparatus. The MPT-HFRR was designed to be used for conventional test methods as well as for liquefied gas fuel tests. Lubricity tests performed on a calibration standard sample under both atmospheric pressure and high pressure produced essentially constant values, so it was determined that this apparatus could be used for assessing the lubricity of fuel. Using this apparatus, the improvement of lubricity due to the addition of a DME (Dimethyl Ether) fuel additive was investigated. It was found that when 50ppm or more of a fatty acid lubricity improver was added, the wear scar diameter converged to 400μm or less, and a value close to the measured result for Diesel fuel was obtained. The lubricity obtained was considered to be generally satisfactory.

In this research, a test apparatus (VPT-HFRR) for evaluating lubricity was manufactured at an arbitrary pressure according to the lubricity test method (HFRR) for diesel fuel. The lubricity of LPG blended fuel (LBF) for diesel engines was examined using VPT-HFRR., This was a value close to that of diesel fuel, and when a suitable lubricity had been maintained, it was checked. Prototype trucks were manufactured and their durability was examined. After a run of 70,000km or more, no serious trouble had occurred, and when LBF was maintained at a suitable lubricity, it was checked.

The Agency of Natural Resources and Energy, Ministry of Economy, Trade and Industry has conducted conformity tests of diesel fuel containing Fatty Acid Methyl Ester (FAME) to amend diesel fuel standards in Japan. The objective of the tests is to examine appropriate specifications of diesel fuel containing FAME for automotive use for existing vehicles in the Japanese market. The conformity testing includes verification of fuel system component compatibility, tail pipe emissions, and characterization of the reliability and durability of the engine system, including the fuel injection system. In designing the conformity tests, the maximum FAME concentration was 5%. Most of the new standards are essentially equivalent to EN14214, but the total acid number (TAN) of specific acids, and oxidation stability of the new standards for diesel fuel containing FAME, are different from EN14214.

Fuels of wide range of density and viscosity were tested by using a DI diesel engine that conforms to present Japanese regulations. A total of 9 fuels was tested. Six test fuels were commercial automotive diesel fuel available in Japan. In order to expand the density range, test fuels of kerosene, high-density diesel fuel and automotive diesel fuel in Singapore were also included. The density range was 0.796 to 0.856 (g/cm3), and the viscosity range was 1.52 to 5.44 (mm2/s). The test mode was Japanese D13. Also, some fuels were tested by the Japanese transient test mode. Moreover, fuel spray was observed by an optical method to clarify the relationship between viscosity and Sauter mean diameter.

The control of NOx emissions is the greatest technical challenge in meeting future emission regulations for diesel engines. In this work, a modal analysis was performed for developing an engine control strategy to take advantage of fuel properties to minimize engine-out NOx emissions. This work focused on the use of EGR to reduce NOx while counteracting anticipated PM increases by using oxygenated fuels. A DaimlerChrysler OM611 CIDI engine for light-duty vehicles was controlled with a SwRI Rapid Prototyping Electronic Control System. Engine mapping consisted of sweeping parameters of greatest NOx impact, starting with OEM injection timing (including pilot injection) and EGR. The engine control strategy consisted of increased EGR and simultaneous modulation of both main and pilot injection timing to minimize NOx and PM emission indexes with constraints based on the impact of the modulation on BSFC, Smoke, Boost and BSHC.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

Carbon, hydrogen and oxygen are major elements in vehicle fuels. Knowledge of fuels elemental composition is helpful in addressing its performance characteristics. Carbon, hydrogen and oxygen composition is an important parameter in engine calibration affecting vehicle performance, emissions and fuel economy. Biodiesel, a fuel comprised of mono-alkyl esters of long-chain fatty acids also known as Fatty Acid Methyl Esters(FAME), derived from vegetable oils or animal fats, has become an important commercial marketplace automotive fuel in the United States (US) and around the world over last few years. FAME biodiesels have many chemical and physical property differences compared to conventional petroleum based diesel fuels. Also, the properties of biodiesel vary based on the feedstock chosen for biodiesel production. One of the key differences between petroleum diesel fuels and biodiesel is the oxygen content.

Gasoline-related factors that affect low-speed pre-ignition (LSPI) include the distillation properties of gasoline, manganese (Mn), ethanol, diesel fuel, detergent for aftermarket, and iron (Fe). The combined effect of Mn with ethanol or high calcium engine oil (high-Ca oil) has not been sufficiently clarified. Therefore, appropriate countermeasures for LSPI have not yet been implemented. To clarify the effect of the gasoline properties and additives on LSPI, engine tests were conducted using gasoline with different “PM Index” values, an indicator of distillation properties, different concentrations of Mn, ethanol, diesel fuel, detergent, Fe, and high-Ca oil. The results showed that the LSPI frequency tended to increase with the PM Index, Mn up to 60 ppm, diesel fuel up to 2 vol.%, and detergent up to three times the standard amount.

Ethanol for use in automotive fuels can be made from renewable feedstocks, which contributes to its increased use in recent years. There are many differences in physical and chemical properties between ethanol and petrochemicals refined from fossil oil. One of the differences is its energy content. The energy content, or heating value, is an important property of motor fuel, since it directly affects vehicle fuel economy. While the energy content can be measured by combustion of the fuel in a bomb, the test is time-consuming and expensive. It is generally satisfactory and more convenient to estimate that property from other commonly-measured fuel properties. Several standardized empirical methods have been developed in the past for estimating the energy content of hydrocarbon fuels such as gasoline, diesel fuel, and jet fuel.

A new concept of highly efficient and sulfur tolerant NOx reduction catalyst for diesel engines has been demonstrated. This catalyst has a double-layer construction and is composed of Pt and Rh as the precious metals, oxygen storage materials and some other catalytic components. Periodic lean/rich operation similar to the Lean NOx Trap catalyst was found to improve the highly efficient NOx reduction activity in a laboratory reactor test. As a result, this catalyst has the feature of high NOx reduction in a temperature window from 15°C to 35°C, and of high oxidation activity even in a lower temperature condition for HC and CO. Sulfur poisoning characteristics were also evaluated in a laboratory reactor test. The results showed that the proper desulfation procedure with a relatively low temperature environment enabled the stored sulfur to be reomved, and to maintain the NOx reduction efficiency for asignificantly long time period.