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Technical Paper

Validity of Low Ventilation for Accident Processing with Hydrogen Leakage from Hydrogen-Fuelled Vehicle

2013-04-08
2013-01-0211
Appropriate emergency response information is required for first responder before hydrogen fuel cell vehicles will become widespread. This paper investigates experimentally the hydrogen dispersion in the vicinity of a vehicle which accidentally releases hydrogen horizontally with a single volumetric flow of 2000 NL/min in the under-floor section while varying cross and frontal wind effects. This hydrogen flow rate represents normally a full throttle power condition. Forced wind was about maximum 2 m/s. The results indicated that the windward side of the vehicle was safe but that there were chiefly two areas posing risks of fire by hydrogen ignition. One was the leeward side of the vehicle's underbody where a larger region of flammable hydrogen dispersion existed in light wind than in windless conditions. The other was the area around the hydrogen leakage point where most of the leaked hydrogen remained undiffused in an environment with a wind of no stronger than 2 m/s.
Journal Article

Validation of the Localized Fire Test Method for On-Board Hydrogen Storage Systems

2014-04-01
2014-01-0421
The localized fire test provided in the Global Technical Regulation for Hydrogen Fuel Cell Vehicles gives two separate test methods: the ‘generic installation test - Method 1′ and the ‘specific vehicle installation test - Method 2′. Vehicle manufacturers are required to apply either of the two methods. Focused on Method 2, the present study was conducted to determine the characteristics and validity of Method 2. Test results under identical burner flame temperature conditions and the effects of cylinder protection covers made of different materials were compared between Method 1 and Method 2.
Technical Paper

Unregulated Emissions Evaluation of Gasoline Combustion Systems (Lean Burn / Stoichiometric DISI and MPI), State of the Art Diesel Aftertreatment Technologies (DPF, urea-SCR and DOC), and Fuel Qualities Effects (EtOH, ETBE, Aromatics and FAME)

2007-10-29
2007-01-4082
In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.
Technical Paper

Thermal Behavior in Hydrogen Storage Tank for FCV on Fast Filling (2nd Report)

2008-04-14
2008-01-0463
If a compressed hydrogen tank for vehicles is filled with hydrogen gas more quickly, the gas temperature in the tank will increase. In this study, we conducted hydrogen gas filling tests using the TYPE 3 and TYPE 4 tanks. During the tests, we measured the temperature of the internal liner surface and investigated its relationship with the gas temperature in the tank. We found that the gas temperature in the upper portion of the TYPE 4 tank rose locally during filling and that the temperature of the internal liner surface near that area also rose, resulting in a temperature higher than the gas temperature at the center of the tank. To keep the maximum temperature in the tank below the designed temperature (85°C) during filling and examine the representative tank internal temperatures, it is important to examine filling methods that can suppress local rises of tank internal temperature.
Technical Paper

The Possibility of Gas to Liquid (GTL) as a Fuel of Direct Injection Diesel Engine

2002-05-06
2002-01-1706
In this study, engine performances and exhaust emissions characteristics of compression ignition engine fueled with GTL were investigated by comparison with diesel fuel. Diesel engine could be operated fueled with GTL without any special modify for the test engine. With the high cetane number of GTL, the ignition lag was shorter, and the combustion started earlier than that of diesel fuel. Brake thermal efficiency operated with GTL increased at middle load conditions due to incomplete combustion emission such as CO and THC were lower than that of diesel fuel operation. NOx emission with GTL was comparable to diesel fuel, and there was a little decrease at high load. With GTL, soot emission was lower than with diesel fuel at above middle load condition. It seemed to be a reason of soot reduction that there was little sulphur contained in GTL.
Technical Paper

The Effects of the Compression Ratio, Equivalence Ratio, and Intake Air Temperature on Ignition Timing in an HCCI Engine Using DME Fuel

2005-10-12
2005-32-0002
Attention has recently been focused on homogeneous charge compression ignition combustion (HCCI) as an effective combustion process for resolving the essential nature of combustion. Meanwhile, dimethylether (DME) has attracted interest as a potential alternative fuel for compression ignition engines. Authors measured the combustion process of DME HCCI by using a spectroscopic method. A diesel engine was used as the test engine. The results of these analyses showed that changes in the compression ratio, intake air temperature and equivalence ratio influenced the ignition timing in the HCCI combustion process. This paper discusses these effects in reference to the experimental and calculated results.
Technical Paper

Test of Vehicle Ignition Due to Hydrogen Gas Leakage

2006-04-03
2006-01-0126
The distribution of concentrations of hydrogen leaking into the front compartment and the dispersion after the leak was stopped were investigated to obtain basic data for specifying the mounting positions of hydrogen leak detecting sensors and the threshold values of alarms for compressed hydrogen vehicles. Ignition tests were also conducted to investigate the flammability and the environmental impact (i.e. the impact on human bodies). These tests were also conducted with methane to evaluate the protection against hydrogen leaks in vehicles in comparison with natural gas (methane). We found that the concentration of hydrogen in the front compartment reached 23.7 vol% maximum when hydrogen gas was allowed to leak for 600 sec from the center of the bottom of the wheelbase at a rate of 131 NL/min, which is the allowable limit for a fuel leak at the time of collision of compressed hydrogen vehicles in Japan.
Technical Paper

Summary report of Japan Clean Air Program diesel and diesel fuel activities

2007-07-23
2007-01-1952
Diesel emissions are significant issue worldwide, and emissions requirements have become so tough that. the application of after-treatment systems is now indispensable in many countries To meet even more stringent future emissions requirements, it has become apparent that the improvement of market fuel quality is essential as well as the development in engine and exhaust after-treatment technology. Japan Clean Air Program II (JCAP II) is being conducted to assess the direction of future technologies through the evaluation of current automobile and fuel technologies and consequently to realize near zero emissions and carbon dioxide (CO2) emission reduction. In this program, effects of fuel properties on the performance of diesel engines and a vehicle equipped with two types of diesel NOx emission after-treatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined.
Technical Paper

Study on Realization of Dual Combustion Cycle by Lean Mixture and Direct Fuel Injection

2018-10-30
2018-32-0011
The purpose of this study is to realize dual-combustion cycle for gasoline engines. For the purpose, lean combustion and direct fuel injection were applied to small diesel engine. The lean gasoline-air mixture was provided and was ignited by small amount of pilot diesel fuel injection (constant volume combustion). Then, diesel fuel was injected by main injection and was burned with the remained oxygen after the lean combustion (diffusion combustion). The equivalence ratio 0.3, 0.4 and 0.5 of mixture were used to avoid the spontaneous compression auto-ignition. The total equivalence ratio with supplied gasoline and diesel fuel was adjusted to 1.0. The base pilot injection timing was selected as the ignition of pre-mixture took place at T.D.C. and pilot injection timings were changed 2 degree before and behind of base timing. The main fuel injection timings were 50, 75 and 100% of the duration between pilot injection timing and T.D.C.
Technical Paper

Study on Knocking Intensity and Autoignitive Propagation Velocity with the Same Methane Number Mixtures of Methane/Ethane and Methane/n-Butane

2023-10-24
2023-01-1803
Although methane number is widely used to predict knocking occurrence and its intensity, it does not determine a fuel composition uniquely, that means, the knocking intensity by the different composition fuel must show difference even if the same methane number fuels are employed. To establish a novel index, the knocking intensity and the autoignitive propagation velocity, as consequence of spontaneous ignition process, are investigated both experimentally and numerically by using the different composition gaseous fuels with same methane number. Methane/ethane/air and methane/n-butane/air mixtures with the same methane number of 70 and the equivalence ratio of 0.5 were employed. They are rapidly compressed and ignited spontaneously by a Rapid Compression Machine. Ignition delay times, autoignitive propagation velocities, and knocking intensity were measured by acquired pressure histories and high-speed imaging.
Technical Paper

Study on Knocking Characteristics for High-Efficiency Operation of a Super-Lean Spark Ignition Engine

2018-10-30
2018-32-0002
This study investigated the influence of EGR and spark advance on knocking under high compression ratio, ultra-lean mixture and supercharged condition using premium gasoline as a test fuel. A high-compression ratio, supercharged single cylinder engine was used in this experiment. As a result, the period from ignition to autoignition was prolonged. In addition, knock intensity was drastically reduced. In other words, it is inferred that by combining an appropriate amount of EGR and spark advance, high efficiency operation avoiding knocking can be realized.
Technical Paper

Study on Haptic Maneuver Guidance by Periodic Knocks on Accelerator Pedal

2015-03-10
2015-01-0039
This study proposes a method for presenting maneuver request information of accelerator pedal to a driver via the accelerator pedal itself. By applying periodic force like vibration on an accelerator pedal, information is transferred to the driver without displacing the accelerator pedal. In this study, the authors focus on a saw-tooth wave as the periodic force. When the saw-tooth-waved force is applied on the accelerator pedal, a human driver feels as if the accelerator pedal is knocked by someone periodically. In addition, information about the quantity of requested maneuver can be transferred by the amplitude of the saw-tooth wave. Based on these facts, the saw-tooth wave is modified and optimized empirically with ten human drivers so that the information of direction is transferred most reliably. In addition, the relationship between the amplitude of the saw-tooth wave and requested quantity of the pedal maneuver that the drivers feel is formulated.
Technical Paper

Study on Combustion and Exhaust Gas Emission Characteristics of Lean Gasoline-Air Mixture Ignited by Diesel Fuel Direct Injection

1998-10-19
982482
The uniform lean gasoline-air mixture was provided to diesel engine and was ignited by direct diesel fuel injection. The mixing region that is formed by diesel fuel penetration and entrainment of ambient mixture is regarded as combustible turbulent jet. The ignition occurs in this region and the ambient lean mixture is burned by flame propagation. The lean mixture of air-fuel ratio between 150 and 35 could be ignited and burned by this ignition method. An increase of diesel fuel injection is effective to ensure combustion and ignition. As diesel fuel injection increases, HC concentration decreases, and NOx and CO concentration increases.
Journal Article

Study of the Impact of High Biodiesel Blends on Engine Oil Performance

2011-08-30
2011-01-1930
In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. This report is designed to determine how high biodiesel blends affect oil quality through testing on 2005 regulations engines with DPFs. When blends of 10-20% rapeseed methyl ester (RME) with diesel fuel are employed with 10W-30 engine oil, the oil change interval is reduced to about a half due to a drop in oil pressure. The oil pressure drop occurs because of the reduced kinematic viscosity of engine oil, which resulting from dilution of poorly evaporated RME with engine oil and its accumulation, however, leading to increased wear of piston top rings and cylinder liners.
Technical Paper

Spray Characteristics of LPG Direct Injection Diesel Engine

2003-03-03
2003-01-0764
In this study, spray images of LPG Blended Fuels (LBF) for DI diesel engines were observed using a constant volume chamber at high ambient temperature and pressure, and the spray characteristics of the fuel were investigated. The LBF spray started to vaporize at the injector tip and the outer downstream regions of the spray, like diesel fuel, because of the high temperature at these areas. There were more vaporized areas compared to diesel fuel. Sufficient fuel injection volume and volatility of LBF resulted in good fuel-air mixture, then, THC emissions decreased compared to diesel fuel at high load engine test conditions. Butane spray image could not be observed at the injector tip. It seems that the high temperature of the injector tip caused the butane spray to vaporize rapidly. Spray tip penetration with LBF and butane were equal or greater than with diesel fuel. The high volatility of LBF and butane had no noticeable effect on spray penetration.
Technical Paper

Spectroscopic Analysis of Combustion in the DME Diesel Engine

2004-03-08
2004-01-0089
For better understanding of the combustion characteristics in a direct injection dimethyl ether (DME) engine, the chemiluminescences of a burner flame and in-cylinder flame were analyzed using the spectroscopic method. The emission intensities of chemiluminescences were measured by a photomultiplier after passing through a monochrome-spectrometer. For the burner flame, line spectra were found nearby the wave length of 310 nm, 430 nm and 515 nm, arising from OH, CH and C2 radicals, respectively. For the in-cylinder flame, a strong continuous spectrum was found from 340 nm wave length to 550 nm. Line spectra were also detected nearby 310 nm, 395 nm and 430 nm, arising from OH, HCHO, and C2 radicals, respectively, partially overlapping with the continuous spectrum. Of these line spectra, 310 nm of OH radical did not overlapped with the continuous spectrum.
Technical Paper

Spectroscopic Analysis of Combustion Flame Fueled with Dimethyl Ether (DME)

2003-05-19
2003-01-1797
To better understand the combustion characteristics of DME, emission intensities of DME combustion radicals from a pre-mixed burner flame were measured by a spectroscope and photomultiplier, Results were compared to other fuels, such as methane and butane. Large peaks in the band spectra from pre-mixed and diffusion DME flames were found near 310 nm, 430 nm, and 515 nm, arising from OH, CH and C2, respectively. The DME emission intensities decreased with increasing the equivalence ratio in this study. Notably, the relative decrease in the C2 band spectra peak was greater than that of the OH band. Comparing the pre-mixed DME and butane flames, the butane band spectra peaks were similar in shape, but much stronger than those for DME. However, it was remarkable that CH and C2 band spectra peaks decreased only slightly with increase in equivalence ratio compared to the DME case.
Technical Paper

Simultaneous Analysis of Light Absorption and Emission in Preflame Reactions under Knocking Operation

2000-01-15
2000-01-1416
The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.(1-3) Absorption spectroscopy was used to measure the behavior of HCHO and OH radicals during a progression from normal combustion to knocking operation. Emission spectroscopic measurements were obtained in the same way that radical added HCO. Radical behavior in preflame reactions was thus examined on the basis of simultaneous measurements, which combined each absorption wavelength with three emission wavelength by using a monochromator and a newly developed polychromator.(4-5) When n-heptane (0 RON) and blended fuel (50 RON) were used as test fuel, it was observed that radical behavior differed between normal combustion and knocking operation and a duration of the preflame reaction was shorter during the progression from normal combustion to a condition of knocking.
Technical Paper

Safety Evaluation on Fuel Cell Stacks Fire and Toxicity Evaluation of Material Combustion Gas for FCV

2007-04-16
2007-01-0435
Fuel cell vehicles represent a new system, and their safety has not yet been fully proved comparing with present automobile. Thorough safety evaluation is especially needed for the fuel system, which uses hydrogen as fuel, and the electric system, which uses a lot of electricity. The fuel cell stacks that are to be loaded on fuel cell vehicles generate electricity by reacting hydrogen and oxygen through electrolytic polymer membranes which is very thin. The safety of the fuel and electric systems should also be assessed for any abnormality that may be caused by electrolytic polymer membranes for any reasons. The purpose of our tests is to collect basic data to ultimately establish safety standards for fuel cell stacks. Methanol pool flame exposure tests were conducted on stationary use fuel cell stacks of two 200W to evaluate safety in the event of a fire.
Technical Paper

SOF Component of Lubricant Oil on Diesel PM in a High Boosted and Cooled EGR Engine

2007-04-16
2007-01-0123
The engine in the research is a single cylinder DI diesel using the emission reduction techniques such as high boost, high injection pressure and broad range and high quantity of exhaust gas recirculation (EGR). The study especially focuses on the reduction of particulate matter (PM) under the engine operating conditions. In the experiment the authors measured engine performance, exhaust gases and mass of PM by low sulfur fuel such as 3 ppm and low sulfur lubricant oil such as 0.26%. Then the PM components were divided into soluble organic fraction (SOF) and insoluble organic fraction (ISOF) and they were measured at each engine condition. The mass of SOF was measured from the fuel fraction and lubricant oil fraction by gas chromatography. Also each mass of soot fraction and sulfate fraction was measured as components of ISOF. The experiment was conducted at BMEP = 2.0 MPa as full load condition of the engine and changing EGR rate from 0% to 40 %.
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