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Porous wall permeability is one of the most critical factors for the estimation of backpressure, a key performance indicator in automotive particulate filters. Current experimental and analytical filter models could be calibrated to predict the permeability of a specific filter. However, they fail to provide a reliable estimation for the dependence of the permeability on key parameters such as wall porosity and pore size. This study presents a novel methodology for experimentally determining the permeability of filter walls. The results from four substrates with different porosities and pore sizes are compared with several popular permeability estimation methods (experimental and analytical), and their validity for this application is assessed. It is shown that none of the assessed methods predict all permeability trends for all substrates, for cold or hot flow, indicating that other wall properties besides porosity and pore size are important.

The increasing severity in emission standards around the world has been accompanied by the development of more active, durable catalysts. With a view to investigating the effects of high thermal aging on the catalyst performance and structure, the relationships of washcoat composition, washcoat structure, and PGM location with respect to catalyst activity were clarified using a model gas test, as well as physical and chemical characterization methods. The influence of newly developed washcoat components and PGM location on catalyst performance are also demonstrated by engine bench tests. The results obtained in this study indicate the newly developed Pt/Rh catalyst techologies are appropriate for future applications in which the catalyst will be exposed to extremely high temperature and flowrates.

New advanced Pd only, Pd:Rh and Pt:Pd:Rh catalysts are compared with a current platinum rhodium catalyst after poisoning and thermal ageing. The results indicate that at equivalent precious metal cost (at 1994 prices) the advanced palladium based catalysts achieve significantly improved performance compared with current Pt, Rh and Pd technology. The new Pd:Rh formulation is recommended for close coupled locations and the Pt:Pd:Rh formulation recommended for underfloor locations where residual fuel lead may be present. The formation of H2S is shown to be low with the palladium based catalysts. Finally, it is shown that the new catalysts with balanced oxidation and reduction capability perform better in multi-brick systems than addition of a highly loaded palladium only front brick.

Gasoline direct injection (GDI) engine technology is now widely used due to its high fuel efficiency and low CO2 emissions. However, particulate emissions pose one challenge to GDI technology, particularly in the presence of fuel injector deposits. In this paper, a 4-cylinder turbocharged GDI engine in the Chinese market was selected and operated at 2000rpm and 3bar BMEP condition for 55 hours to accumulate injector deposits. The engine spark timing, cylinder pressure, combustion duration, brake specific fuel consumption (BSFC), gaseous pollutants which include total hydro carbon (THC), NOx (NO and NO2) and carbon dioxide (CO), and particulate emissions were measured before and after the injector fouling test at eight different operating conditions. Test results indicated that mild injector fouling can result in an effect on engine combustion and emissions despite a small change in injector flow rate and pulse width.

With the advent of stricter vehicle emission standards, the improvement of three way catalyst performance and durability remains a pressing issue. A critical consideration in catalyst design is the potential for variations in fuel sulfur levels to have a significant impact on the ability to reach TLEV, LEV, and ULEV emission levels. As a result, a better understanding of the role of PGM composition in the interplay between thermal durability and sulfur tolerance is required. Three way catalysts representative of standard Pd-only, Pd/Rh and Pt/Rh formulations were studied over a variety of aging and evaluation conditions. The parameters investigated included aging temperature, air fuel ratio and sulfur level. Evaluations were performed on a 1994 TLEV vehicle using different sulfur level fuels. The effect of PGM loading was also included within the study.

The performance characteristics of a commercial lean-NOX trap catalyst were evaluated between 200 and 500°C, using H2, CO, and a mixture of both H2 and CO as reductants before and after different high-temperature aging steps, from 600 to 750°C. Tests included NOX reduction efficiency during cycling, NOX storage capacity (NSC), oxygen storage capacity (OSC), and water-gas-shift (WGS) and NO oxidation reaction extents. The WGS reaction extent at 200 and 300°C was negatively affected by thermal degradation, but at 400 and 500°C no significant change was observed. Changes in the extent of NO oxidation did not show a consistent trend as a function of thermal degradation. The total NSC was tested at 200, 350 and 500°C. Little change was observed at 500°C with thermal degradation but a steady decrease was observed at 350°C as the thermal degradation temperature was increased.

In a collaborative programme, the effects of gasoline sulphur content on regulated emissions from three-way catalyst equipped vehicles have been studied. The programme evaluated the sulphur tolerance of three different catalyst formulations on the same range of vehicles. The catalyst chemistries were chosen to be representative of typical current formulations in different markets, as follows: 1. Platinum/Rhodium (Pt/Rh) 2. Platinum/Rhodium/Nickel (Pt/Rh/Ni) 3. Palladium/Rhodium (Pd/Rh) Each vehicle/catalyst combination was tested with fuels containing sulphur at nominal levels of 50, 250 and 450 ppm weight. All fuels were produced using the low sulphur fuel as a base and doping to 250 and 450 ppm S with a mixture of nine sulphur compounds, typical of those actually occurring in European gasolines. The results show clear differences between the magnitudes of the sulphur effect with different catalyst formulations.

Progress made in reducing engine-out particulate emissions has prompted a revival in the design of flow-through oxidation catalysts for diesel engine applications. Effort in this area has focused primarily in the area of SOF control for the further reduction of particulate emissions. The work reported here covers some of the catalyst design parameters important for SOF and gas phase pollutant control. This is illustrated with both laboratory reactor and engine evaluation data for several formulary and operating parameters. Platinum-based catalysts are shown to be generally the most active, but they require treatments or additives to reduce the inherently high activity of platinum for the oxidation of SO2 present in the exhaust. The effect of additives and their loading on the oxidation activity of Pt/alumina for HC, CO, SOF and SO2 oxidation is discussed in detail and additives are identified which reduce SO2 oxidation with minimal effect on HC, CO or SOF oxidation activity.

Legislation aimed at reducing carbon dioxide emissions is forcing significant changes in passenger car engine hardware and lubricants. Reduced viscosity lubricants can reduce friction levels and are therefore helpful to manufacturers seeking legislative compliance. MAHLE and Shell have worked together to determine the crankshaft, bearing and lubricant combination which minimizes friction with an acceptable level of durability. This paper describes the results of our joint simulation studies. MAHLE Engine Systems have developed in-house simulation packages to predict bearing lubrication performance. SABRE-M is a “routine” simulation tool based on the mobility method [1] curve fitting from the finite bearing theory to simulate the hydrodynamic lubrication in steady-state conditions. Whereas, SABRE-TEHL is a specialized simulation package used for performing Thermo-Elasto-Hydrodynamic Lubrication (TEHL) analysis of bearing systems.

In a consortium of European industrial partners and research institutes, a combination of industrial development and scientific research was organised. The objective was to improve the catalytic NOx conversion for lean burn cars and heavy-duty trucks, taking into account boundary conditions for the fuel consumption. The project lasted for three years. During this period parallel research was conducted in research areas ranging from basic research based on a theoretical approach to full scale emission system development. NOx storage catalysts became a central part of the project. Catalysts were evaluated with respect to resistance towards sulphur poisoning. It was concluded that very low sulphur fuel is a necessity for efficient use of NOx trap technology. Additionally, attempts were made to develop methods for reactivating poisoned catalysts. Methods for short distance mixing were developed for the addition of reducing agent.

Selective NOx recirculation (SNR), involving adsorption, selective external recirculation and decomposition of the NOx by the combustion process, is itself a promising technique to abate NOx emissions. Three types of materials containing Ba: barium aluminate, barium tin perovskite and barium Y-zeolites have been developed to adsorb NOx under lean-burn or Diesel conditions, with or without the presence of S02. All these materials adsorb NO2 selectively (lean-burn conditions), and store it as nitrate/nitrite species. The desorption takes place by decomposition of these species at higher temperatures. Nitrate formation implies also sulfate formation in the presence of SO2 and SO3, while the NO2/SO2 competition governs the poisoning of such catalysts.

The SNR-technique is a new NOx aftertreatment system for lean burn gasoline and diesel applications. The objective of SNR is NOx removal from lean exhaust gas by NOx adsorption and subsequent selective external recirculation and decomposition of NOx in the combustion process. The SNR-project is composed of two major parts. Firstly the development of NOx adsorbents which are able to store large quantities of NOx in lean exhaust gas, and secondly the NOx decomposition by the combustion process. Emphasis of this paper is the investigation of NOx reduction in the combustion process, including experimental investigation and numerical simulation. The NOx decomposition process has been proven in diesel and lean-burn gasoline engines. Depending on the type of engine NOx-conversion rates up to 90 % have been observed. Regarding the complete SNR-system, including the efficiency of the adsorbing material and the NOx decomposition by the combustion, a NOx removal of more than 50% is achievable.

In April 2003, a small field study was initiated to evaluate the effect of lube oil formulations on ash accumulation in heavy-duty diesel DPFs. Nine (9) Fuel Delivery Trucks were retrofitted with passive diesel particulate filters and fueled with ultra low sulfur diesel which contains less than 15 ppm sulfur. Each vehicle operated in the field for 18 months or approximately 160,000 miles (241,401 km) using one of three lube oil formulations. Ash accumulation was determined for each vehicle and compared between the three differing lube oil formulations. Ash analyses, used lube oil analysis and filter substrate evaluations were performed to provide a complete picture of DPF operations. The evaluation also examined some of the key parameters that allows for the successful implementation of the passive DPF in this heavy-duty application.

The objective of this effort was to develop an understanding of how different converter substrate cell structures impact tailpipe emissions and pressure drop from a total systems perspective. The cell structures studied were the following: The catalyst technologies utilized were a new technology palladium only catalyst in combination with a palladium/rhodium catalyst. A 4.0-liter, 1997 Jeep Cherokee with a modified calibration was chosen as the test platform for performing the FTP test. The experimental design focused on quantifying emissions performance as a function of converter volume for the different cell structures. The results from this study demonstrate that the 93 square cell/cm2 structure has superior performance versus the 62 square cell/cm2 structure and the 46 triangle cell/cm2 structure when the converter volumes were relatively small. However, as converter volume increases the emissions differences diminish.

Particulate mass (PM) emissions from DISI engines can be reduced via fuels additive technology that facilitates injector deposit clean-up. A significant drawback of DISI engines is that they can have higher particulate matter emissions than PFI gasoline engines. Soot formation in general is dependent on the air-fuel ratio, combustion chamber temperature and the chemical structure and thermo-physical properties of the fuel. In this regard, PM emissions and DISI injector deposit clean-up were studied in three identical high sales-volume vehicles. The tests compared the effects of a fuel (Fuel A) containing a market generic additive at lowest additive concentration (LAC) against a fuel formulated with a novel additive technology (Fuel B). The fuels compared had an anti-knock index value of 87 containing up to 10% ethanol. The vehicles were run on Fuel A for 20,000 miles followed by 5,000 miles on Fuel B using a chassis dynamometer.

The effect of changing catalyst precious metal ratios and loadings on close coupled catalytic converter efficiencies has been studied. The three precious metals were platinum, palladium and rhodium. The specific matrix used for the development of response surface models is a central composite design and provides the capability of visually optimising the precious metal loadings. Catalysts were evaluated using perturbed scans. lightoff curves from the dynamometer aged, and vehicle emission tests. These scans show percent conversion efficiencies of the three legislated gases; HC, CO and NOx, over a range of Air Fuel Ratios (λ). Whilst lean and rich lightoff curves provide indications of conversion efficiencies at varying temperatures. Prior to testing the catalysts were aged, using an accelerated dynamometer ageing process, to 80K simulated kilometres. The catalysts were then fitted to a vehicle and chassis roll emission tests conducted.

Diesel particulate filter (DPF) is necessary for diesel engines to meet the increasingly stringent emission regulations. Many studies have demonstrated that the lubricant derived ash has a significant effect on DPF pressure drop and engine fuel economy, and this effect becomes more and more severe with the increasing of operating hours of the DPF because the ash accumulated in the DPF cannot be removed by regeneration. It is reported that most of the DPFs operated with more ash than soot in the filter for more than three quarters of the time during its lifetime [1]. In order to mitigate this problem, the original engine manufacturers (OEM) tend to use an oversized DPF for the engine. However, it will increase the costs of the DPF and reduce the compactness of the engine aftertreatment system.

In the USA, hydrogen sulfide emissions from three-way catalytic converter-equipped automobiles are effectively suppressed by the addition of nickel to catalyst formulations. This approach is generally not utilized in catalyst formulations for Europe because of European concern about the health, safety and environmental issues surrounding the use of nickel. A modified form of iron oxide has been identified which suppresses hydrogen sulfide emissions from three-way catalysts. This suppression has been achieved without affecting the fresh or aged performance of the catalyst, a problem often encountered with other materials. The performance and durability of catalyst formulations incorporating the new material are demonstrated with a variety of aging and evaluation protocols.

When performing catalyst modeling and parameter tuning it is desirable that the experimental data contain both transient and stationary points and can be generated over a short period of time. Here a method of creating such concentration transients for a full scale engine rig system is presented. The paper describes a valuable approach for changing the composition of engine exhaust gas going to a DOC (or potentially any other device) by conditioning the exhaust gas with an additional upstream DOC and/or SCR. By controlling the urea injection and the DOC bypass a wide range of exhaust compositions, not possible by only controlling the engine, could be achieved. This will improve the possibilities for parameter estimation for the modeling of the DOC.

Worldwide, Fuel Economy (FE) legislation increasingly influences vehicle and engine design, and drives friction reduction. The link between lubricant formulation and mechanical friction is complex and depends on engine component design and test cycle. This Motored Friction Tear Down (MFTD) study characterizes the friction within a 3.6L V6 engine under operating conditions and lubricant choices relevant to the legislated FE cycles. The high-fidelity MFTD results presented indicate that the engine is a low-friction engine tolerant of low viscosity oils. Experiments spanned four groups of engine hardware (reciprocating, crankshaft, valvetrain, oil pump), five lubricants (four candidates referenced against an SAE 0W-20) and five temperature regimes. The candidate lubricants explored the impact of base oil viscosity, viscosity modifier (VM) and friction modifier (FM) content.