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Exhaust gas recirculation (EGR) can be used to mitigate knock in SI engines. However, experiments have shown that the effectiveness of various EGR constituents to suppress knock varies with fuel type and compression ratio (CR). To understand some of the underlying mechanisms by which fuel composition, octane sensitivity (S), and CR affect the knock-mitigation effectiveness of EGR constituents, the current paper presents results from a chemical-kinetics modeling study. The numerical study was conducted with CHEMKIN, imposing experimentally acquired pressure traces on a closed reactor model. Simulated conditions include combinations of three RON-98 (Research Octane Number) fuels with two octane sensitivities and distinctive compositions, three EGR diluents, and two CRs (12:1 and 10:1). The experimental results point to the important role of thermal stratification in the end-gas to smooth peak heat-release rate (HRR) and prevent acoustic noise.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

We have developed a novel engine cycle simulation program (UniDES: universal diesel engine simulator) to reproduce the diesel combustion process over a wide range of engine operating parameters, such as the amount of injected fuel, the injection timing, and the EGR ratio. The approach described in this paper employs a zoning model, where the in-cylinder region is divided into up to five zones. We also applied a probability density function (PDF) concept to each zone to consider the effect of spatial non-homogeneities, such as local equivalence ratios and temperature, on the combustion characteristics. We linked this program to the commonly used commercial GT-Power® software (UniDES+GT). As a result, we were able to reproduce transient engine behavior very accurately.

The aim of this research is to develop the diesel combustion simulation (UniDES: Universal Diesel Engine Simulator) that incorporates multiple-injection strategies and in-cylinder composition changes due to exhaust gas recirculation (EGR), and that is capable of high speed calculation. The model is based on a zero-dimensional (0D) cycle simulation, and represents a multiple-injection strategy using a multi-zone model and inhomogeneity using a probability density function (PDF) model. Therefore, the 0D cycle simulation also enables both high accuracy and high speed. This research considers application to actual development. To expand the applicability of the simulation, a model that accurately estimates nozzle sac pressure with various injection quantities and common rail pressures, a model that accounts for the effects of adjacent spray interaction, and a model that considers the NOx reduction phenomenon under high load conditions were added.

Toyota developed a new hybrid unit “L4A0” for the new Tundra, which creates both good drivability and environmental performance. To ensure off-road, towing performance and typical truck driving characteristics, the unit is based on a transmission with a torque converter and a multi-plate lock up clutch, with a motor-generator and K0 clutch installed between the engine and transmission. The motor-generator and K0 clutch are built into a module, making it possible to create new hybrid units by combining the module with various transmissions. The unit features many different motor controls. For example, in the case of step-in acceleration input, in order to achieve the desired output torque, typically a kick-down shift is necessary [1]; however, by utilizing “L4A0” both high response and high power output is achieved even without a kick-down shift. This is accomplished by assisting the engine with the motor-generator even when the engine torque is delayed at low engine speeds.

The superior fuel economy of diesel engines compared to gasoline engines is favorable in reducing carbon dioxide (CO2) emissions. On the other hand, the reductions in nitrogen oxides (NOx) and particulate matter (PM) emissions are technically difficult, thus the improvement in the emission reduction technologies is important. Although the cooled exhaust gas recirculation (cooled-EGR) is the effective method to reduce NOx emissions, it is known to have durability and reliability problems, especially of the increased wear of piston rings and cylinder liners. Therefore, the degree of cooling and amount of EGR are both limited. To apply the cooled-EGR more effectively, the wear reduction technology for such components are indispensable. In this study, the negative effects of cooled-EGR on the wear are quantified by using a heavy-duty diesel engine, and its wear mechanism is identified.

To reduce NOx and Particulate Matter (PM) emissions from a heavy-duty diesel engine, the effects of urea selective catalytic reduction (SCR) systems were studied. Proto type urea SCR system was composed of NO oxidation catalyst, SCR catalyst and ammonia (NH3) reduction catalyst. The NOx reduction performance of urea SCR system was improved by a new zeolite type catalyst and mixer for urea distribution at the steady state operating conditions. NOx and PM reduction performance of the urea SCR system with DPF was evaluated over JE05 mode of Japan. The NOx reduction efficiency of the urea SCR catalyst system was 72% at JE05 mode. The PM reduction efficiency of the urea SCR catalyst system with DPF was 93% at JE05 mode. Several kinds of un-regulated matters were detected including NH3 and N2O leak from the exhaust gas. It is necessary to have further study for detailed measurements for un-regulated emissions from urea solution.

To reduce emissions from diesel engines, the effects of oxidation catalysts on the emissions reductions were studied. The effectiveness of several oxidation catalysts on both the regulated and unregulated emissions was evaluated. The oxidation activity of the catalysts was varied by changing Pt loading. The regulated emissions include particulate (PM), hydrocarbon (HC), and carbon monoxide (CO), and the unregulated emissions include benzene, formaldehyde, acetaldehyde, and benzo[a]pyrene (B[a]P). An 8 litter, turbocharged and aftercooled diesel engine was operated under the Japan Diesel 13 (D13) mode cycle for the evaluations. As the first step, evaluations were conducted with a commercially available JIS #2 diesel fuel (0.046 wt% sulfur). All the regulated and unregulated emissions except PM were reduced as the Pt loading (i.e. oxidation activity) increased. However, PM emissions were increased by the generation of sulfate when the Pt loading exceeded 0.2 g/l.

The Hino E13C was developed for heavy-duty truck application to meet Japan's 2003 NOx and 2005 particulate emissions standards simultaneously with significant fuel economy improvement. A combined EGR system consisting of an external EGR system with a highly efficient EGR cooler and an internal EGR system with an electronically controlled valve actuation device was newly developed to reduce NOx emissions for all operating conditions without requiring a larger engine coolant radiator. A Hino-developed DPR was installed to achieve extremely low particulate emissions at the tail pipe. Increased strength of engine structural components and a ductile cast iron piston enabled high BMEP operation at lower engine speeds and reductions of both engine size and weight. This paper describes key technologies developed for the E13C as well as the development results.

Recently, deposition of ash derived from engine oil on the surface of a diesel particle filter (DPF) has been reported to worsen the performance of the DPF. It is generally known that phosphorus in engine oil is adsorbed on the surface of an automotive exhaust catalyst and reduces the performance of the catalyst. Thus, the amounts of ash and phosphorus in engine oil have been decreased. We have developed a non-phosphorus and non-ash engine oil (NPNA) that does not contain metal-based detergents and zinc dialkyldithiophosphate (ZnDTP). We performed a performance test for NPNA using an actual engine and reported that the piston detergency and anti-wear performance of NPNA were sufficiently high. However, the piston detergency of NPNA required further improvement when engine running conditions were more severe.

Since in-cylinder flame temperature has a direct effect on an engine's NOx characteristics, this phenomena has been studied in detail in a multi-cylinder DI diesel engine using a new method allowing the in-cylider temperature distribution to be measured by the two color method. An endoscope is installed in the combustion chamber and flame light introduced from the endoscope is divided into two colors by filters. The images of combustion phenomena using the two wavelengths are recorded with a framing streak camera which includes a CCD camera. The flame temperature and KL factor are immediately calculated by a computer using the two color images from the CCD camera. In the case of EGR, the test was conducted under 75% load conditions. The flame temperature was reduced according to an increase of EGR rate.

There is ever increasing interest in the issues of fossil fuel depletion, global warming, due to increased atmospheric CO2, and air pollution, all of which are due in some extent to transportation, including automobiles. Hybrid Vehicles (HVs), whose performance and usage are equivalent to existing conventional vehicles, attract lots of attention and have started to come into wider use. Meanwhile, EVs have been considered by many as the best solution for the issues mentioned above. But the technical difficulty of battery energy density is an obstruction to successful implementation. Currently the Plug-in HV (PHEV), which combines the advantages of HV and EV, is being considered as one promising solution. PHEVs can be categorized into two types, according to operating modes. The first uses battery stored energy initially, only stating the internal combustion engine when the battery is depleted. This we call the All Electric Range (AER) system.

Polymer electrolyte membrane fuel cell (PEFC) systems for fuel cell vehicles (FCVs) require both performance and durability. Carbon is the typical support material used for PEFC catalysts. However, hydrogen starvation at the anode causes high electrode potential states (e.g., 1.3 V with respect to the reversible hydrogen electrode) that result in severe carbon support corrosion. Serious damage to the carbon support due to hydrogen starvation can lead to irreversible performance loss in PEFC systems. To avoid such high electrode potentials, FCV PEFC systems often utilize cell voltage monitor systems (CVMs) that are expensive to use and install. Simplifying PEFC systems by removing these CVMs would help reduce costs, which is a vital part of popularizing FCVs. However, one precondition for removing CVMs is the adoption of a durable support material to replace carbon.

Engine oils normally contain calcium detergents and ZnDTPs to have detergency and antiwear performance. However, it has been recently understood that these additives could deteriorate filter performance in catalyst and DPF. In this background this paper explains the study and the development about new type of engine oil excluding metal detergents and phosphorus compounds. The developed engine oil shows good durability in several JASO engine tests and a fleet test by formulating newly developed additives as substitute for calcium detergents and ZnDTPs.

Three-way catalyst shows high performance under stoichiometric atmosphere. The CeO2-ZrO2 based materials (CZ) are added as a buffer of O2 concentration. To improve the catalyst performance the larger O2 storage capacity (OSC) are needed. Theoretically, the sulfur oxidation-reduction reaction moves oxygen 8 times larger than cerium. We focused on this phenomenon and synthesized Ln2O2SO4 as a new OSC material. The experimental result under model gas shows that the OSC of Ln2O2SO4 is 5 times lager than CZ.

Performance improvements were studied for the diesel particulate and NOx reduction system (DPNR), a system that simultaneously reduces NOx and Particulate Matter (PM) from diesel engine exhaust gas. The experimental system (hereinafter called the “dual DPNR”) consists of two DPNR catalysts arranged in parallel, each provided with an exhaust throttle valve downstream to control the exhaust gas flow to the catalyst, plus a fuel injector that precisely controls the air-fuel ratio and the catalyst bed temperature. The fuel injector is used to supply a rich mixture to the DPNR catalyst, and the flow of exhaust gas is switched between the two catalysts by operating the exhaust throttle valves alternately. Tests were conducted with the engine running at steady state. The results indicated that the NOx reduction performance dramatically improved and the loss of fuel economy from the NOx reduction reduced.

The development of an alternative oxygen reduction electrocatalyst to platinum based electrocatalysts is critical for practical use of the polymer electrolyte membrane fuel cell (PEMFC). Transition metal sulfide chalcogenides have recently been reported as a possible candidate for Pt replacement. Our work focused on chalcogenides composed of ruthenium, molybdenum, and sulfur (RuMoS). We elucidate the factors affecting electrocatalytic activity of carbon supported RuXMoY SZ catalyst. This was demonstrated through a correlation of oxygen reduction reaction (ORR) activity of the catalysts with structural changes resulting from designed changes in sulfur composition in the catalysts.

A 2-LEG NOx Storage-Reduction (NSR) catalyst system is one of potential after-treatment technology to meet stringent NOx and PM emissions standards as Post New Long Term (Japanese 2009 regulation) and US'10. Concerning NOx reduction using NSR catalyst, a secondary fuel injection is necessary to make fuel-rich exhaust condition during the NOx reduction, and causes its fuel penalty. Since fuel injected in the high-temperature (∼250 degrees Celsius) exhaust instantly reacts with oxygen in common diesel exhaust, the proportion of fuel consumption to reduce the NOx stored on NSR catalyst is relatively small. A 2-LEG NSR catalyst system has the decreasing exhaust flow mechanism during NOx reduction, and the potential to improve the NOx reduction and fuel penalty. Therefore, this paper studies the 2-LEG NSR catalyst system. The after-treatment system consists of NSR catalysts, a secondary fuel injection system, flow controlled valves and a Catalyzed Diesel Particulate Filter (CDPF).

A new after-treatment system called DPNR (Diesel Particulate-NOx Reduction System) has been developed for simultaneous and continuous reduction of particulate matter (PM) and nitrogen oxides (NOx) in diesel exhaust gas. This system consists of both a new catalytic technology and a new diesel combustion technology which enables rich operating conditions in diesel engines. The catalytic converter for the DPNR has a newly developed porous ceramic structure coated with a NOx storage reduction catalyst. A fresh DPNR catalyst reduced more than 80 % of both PM and NOx. This paper describes the concept and performance of the system in detail. Especially, the details of the PM oxidation mechanism in DPNR are described.

Improving vehicle fuel economy is a central part of efforts toward achieving a sustainable society. An effective way for accomplishing this aim is to enhance the engine thermal efficiency. Measures to mitigate knocking and reduce engine cooling heat loss are important aspects of enhancing the engine thermal efficiency. Cooled exhaust gas recirculation (EGR) is regarded as a key technology because it is capable of achieving both of these objectives. For this reason, it has been adopted in a wide range of both hybrid and conventional vehicles in recent years. Toyota has been introducing these technologies as ESTEC (Economy with Superior Thermal Efficient Combustion). Improving cycle-to-cycle variations in combustion, in addition to fast combustion is essential for achieving high engine thermal efficiency.