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Technical Paper

Utilization of Advanced Three-Way Catalyst Formulations on Ceramic Ultra Thin Wall Substrates for Future Legislation

2002-03-04
2002-01-0349
The LEV II and SULEV/PZEV emission standards legislated by the US EPA and the Californian ARB will require continuous reduction in the vehicles' emission over the next several years. Similar requirements are under discussion in the European Union (EU) in the EU Stage V program. These future emission standards will require a more efficient after treatment device that exhibits high activity and excellent durabilty over an extended lifetime. The present study summarizes the findings of a joint development program targeting such demanding future emission challenges, which can only be met by a close and intensive co-operation of the individual expert teams. The use of active systems, e.g. HC-adsorber or electrically heated light-off catalysts, was not considered in this study. The following parameters were investigated in detail: The development of a high-tech three-way catalyst technology is described being tailored for applications on ultra thin wall ceramic substrates (UTWS).
Technical Paper

Ultra-Thin Wall (UTW) Substrate Thermal Shock Durability Study

2006-04-03
2006-01-1066
Thermal shock performance parameters to assure Ultra Thin Wall (UTW) substrate durability for close-coupled (CC) converter operating conditions have been defined through testing and FEM modeling. Propane burner tests simulating the engine exhaust conditions were performed and coordinated with FEM stress analysis. For the stress analysis, a newly developed Macro-Micro Thermal Stress Analysis method was employed. Validation of the Macro-Micro Thermal Stress Analysis method was made through comparing FEM analysis results with the electric furnace and the burner tests results. A thermal fatigue life prediction method taking into account variation in material strength, fatigue degradation and effective volume was developed. In the verification tests, crack generation stresses were predicted within a 20 % margin of error.
Technical Paper

The Influence of Tire Deformation on Ride Comfort of a Truck

1990-10-01
902268
When truck tires have a deformation such as radial runout, flat spot, and abnormal wear as a result of panic braking, they affect vehicle vibration in the form of displacement input whose spectrum involves higher order terms of tire revolution. While a truck has vibration modes of frame bending as well as pitching and unsprung-mass viberation in the input frequency range, the tire displacement input induces vehicle vibration as a combination of these modes. Results of calculations and experiments of a 4x2 medium-duty truck are analyzed and an example of means for improving ride comfort is described in this paper.
Technical Paper

Soot and Valve Train Wear in Passenger Car Diesel Engines

1983-10-31
831757
The effect of the use of the EGR system on the lubrication of a passenger car diesel engine was investigated. The higher the EGR rate, the more soot in the oil. And the most detrimental effect was found in valve train wear. Some engine tests, including motoring tests, were carried out to investigate the contribution of soot to valve train wear. The mechanism of cam and rocker arm wear in used oils was studied by analyzing for elements on the lubricated metal surface and subsequently the mechanism was more thoroughly studied using the four-ball test. Soot seems to act as an abrasive on the anti-wear solid film formed by the oil on the metal surface and this film contains Ca, O, P and S. Some hardware modifications and oil formulations to reduce valve train wear are also discussed.
Technical Paper

Small Engine - Concept Emission Vehicles

1971-02-01
710296
Three Japanese automobile manufacturers-Mitsubishi Motors Corp., Nissan Motor Co., Ltd., and Toyo Kogyo Co., Ltd.-have been making efforts over the past three years to design and develop effective thermal reactor-exhaust gas recirculation and catalytic converter systems suitable for small engines. The work is being done by members participating in the IIEC (Inter-Industry Emission Control) Program, and the exhaust emission levels of the concept vehicles developed by these companies have met the goal established by the IIEC Program at low mileage. Each system, however, has a characteristic relationship between exhaust emission level and loss of fuel economy. Much investigation is required, particularly with respect to durability, before any system that will fully satisfy all service requirements can be completed. This paper reports the progress of research and development of the individual concept vehicles.
Technical Paper

Selective Heat Insulation of Combustion Chamber Walls for a DI Diesel Engine with Monolithic Ceramics

1989-02-01
890141
The engine performance and emissions characteristics of a single-cylinder DI diesel engine were experimentally investigated. The combustion chamber walls of the engine were thermally insulated with ceramic materials of SSN (Sintered Silicon Nitride) and PSZ (Partially Stabilized Zirconia). Fuel economy and emissions characteristics were improved by insulating selected locations of the combustion chamber walls. The selective insulation helped to create activated diffusion combustion and resulted in more efficient use of the intake air.
Technical Paper

Product Design and Development of Ultra Thin Wall Ceramic Catalytic Substrate

2002-03-04
2002-01-0350
Development of the ultra thin wall ceramic catalytic substrate is necessary to meet increasingly strict emissions regulations. The cell walls need to be thinner in order to improve the warm-up characteristics related to the reduction of emissions and to lower the back pressure. However, the thinner the wall thickness, the smaller the mechanical strength of the substrate becomes. For substrates with 2.5mil wall thickness, we densified a conventional material with 35% porosity to less than 30%[1] to improve erosion resistance. Furthermore, for substrates less than 2.5mil wall thickness, a denser material and strengthened end surface is necessary to protect against erosion. In addition to that, we think that a reinforced periphery is necessary for isostatic strength. In this paper, we evaluated the effect of a densified material, strengthened end surface, and a reinforced periphery.
Technical Paper

Multi Layered Zirconia Oxygen Sensor with Modified Rhodium Catalyst Electrode

1988-02-01
880557
This paper describes the design and operation of the multi-layered zirconia heated exhaust gas oxygen sensor having small-sized and sheet-shaped sensing element. This sensor uses an electrode modified with a rhodium catalyst and heater by means of the thick-film technique. This modification of an electrode's composition and construction affects the reaction on unburned components in exhaust gas as well as the sensor performance. By the addition of a rhodium catalyst, the zirconia exhaust gas oxygen sensor shows acute sensitivity and faster response properties in the transient state on emission component(NOx) generation, in such a way that these sensors show better emission control properties for reduction of NOx emission in current emission control systems. The addition of a rhodium catalyst reduces the green effect of sensor properties, and no significant change of emission control properties is observed after 50,000 equivalent miles using the engine dynamometer durability test.
Technical Paper

Hot-Gas Spin Testing of Ceramic Turbine Rotor at TIT 1300° C

1989-02-01
890427
The high-temperature durability of 85 mm tip diameter silicon nitride ceramic radial turbine rotors was evaluated with a hot gas spin test rig. The rotors withstood up to a turbine tip speed of 700 m/s at TIT of 1300°C under partially loaded conditions and 570 m/s at TIT of 1300°C under fully loaded conditions, respectively. The material of the rotors was a post-HIPed silicon nitride. The basic fatigue properties of the material were measured at high temperatures. In the hot gas spin test, the temperature and stress distributions at the turbine blade were calculated with a finite element method. The results of the hot-gas spin test are discussed by means of a failure prediction analysis on the basis of the Weibull statistics.
Technical Paper

Evaluation of Advanced Diesel Oxidation Catalyst Concepts: Part 2

2006-04-03
2006-01-0032
The development of diesel powered passenger cars is driven by the enhanced emission legislation. To fulfill the future emission limits there is a need for advanced aftertreatment devices. A comprehensive study was carried out focusing on the improvement of the DOC as one part of these systems, concerning high HC/CO conversion rates, low temperature light-off behaviour and high temperature aging stability, respectively. The first part of this study was published in [1]. Further evaluations using a high temperature DPF aging were carried out for the introduced systems. Again the substrate geometry and the catalytic coating were varied. The results from engine as well as vehicle tests show advantages in a highly systematic context by changing either geometrical or chemical factors. These results enable further improvement for the design of the exhaust system to pass the demanding emission legislation for high performance diesel powered passenger cars.
Technical Paper

Engine Weight Reduction Using Alternative Light Materials

1992-09-01
922090
This paper presents several methods for reducing engine weight primarily through substitution with light-weight materials. The efficiency and performance of the engine were reviewed using a light-weight experimental engine (hereinafter called “weight-reduced engine”) constructed by the authors in order to investigate the possibility of practical use of the proposed weight reduction measures. The weight-reduced engine is based on an in-line 4-cylinder, 2.0 liter, gasoline engine with the base engine weight of 162 kg excluding engine oil and coolant and was reduced by 37 kg by applying alternative light-weight materiaLs and new manufacturing techniques. This corresponds to 23 % weight reduction. The materials used in the weight-reduced engine are 53 % steel, 33 % aluminum, 7 % plastics and 7 % other light-weight materials. It was found that by application of light-weight materials, the engine performance of the weight-reduced engine could be improved.
Technical Paper

Energy Absorption by the Plastic Deformation of Body Structural Members

1978-02-01
780368
Vehicle energy in head-on or rear-end collisions is mainly absorbed by the front or rear longitudinal members. This paper describes the methods of calculation of crush load and the energy absorbed during the static and dynamic crush of the sheet metal members with closed-hat section together with attached flanges or walls. Calculated results were compared with experiments including full-size automobile collisions. It is expected that the analysis considering the strain rate sensitivity will provide more accurate design information for improved automobile crash-worthiness.
Technical Paper

Effects of Shot Peening and Grinding on Gear Strength

1994-03-01
940729
In recent year, higher strength for truck and bus transmission gear has become necessary. For the transmission gears, carburized gears have generally been used. We have examined the effects of shot peening and grinding using a CBN grindstone on the pitting strength and the bending fatigue strength of a carburized gear, and further evaluated a material which reduces the structual anomalies produced during carburization. As a result, it has been found that shot peening or CBN grinding is more effective for improving both pitting strength and bending fatigue strength than improving the material composition. Therefore, it is evident that residual compressive stress caused by shot peening or CBN grinding suppresses the propagation of cracks.
Technical Paper

Development of thermoplastic elastomeric vacuum hose for engine control

2000-06-12
2000-05-0150
Vulcanized rubber hoses are difficult to recycle and have a complicated manufacturing process. Recently, we have developed the vacuum hose for engine control out of thermoplastic elastomers. As a result of this development, scrap material from the manufacturing process can be recycled and, in addition, about a 30 percent weight reduction and a 20 percent cost reduction are achievable by virtue of the lower specific gravity and by the more simplified manufacturing process. In order to assess the feasibility of using thermoplastic elastomers for vacuum hoses, we developed a heat aging simulation test method. This was achieved by first investigating the actual vehicle environmental conditions of currently used vacuum hoses by retrieving and examining these hoses from used vehicles. We then extrapolated what the condition of such hoses would be after being subjected to heat aging for 200,000 km of service in an actual vehicle, and applied this calculation to our newly developed hoses.
Technical Paper

Development of the Stainless Cast-Steel Exhaust Manifold

1993-03-01
930621
At Mitsubishi Motors, a thin-walled exhaust manifold, made of stainless cast-steel, has been developed with the aim of achieving higher heat-resisting reliability as well as weight reduction. The new exhaust manifold is made of ferritic stainless cast-steel, employing an advanced vacuum casting (CLAS). Its geometry was designed using finite element analysis and its durability was confirmed by testing both on various test devices and on a vehicle. The exhaust manifolds has been adopted on a production engine model and has proven the following advantages over a conventional cast-iron ones; excellent heat resistance. weight reduction of over 20%. possible exhaust emission reduction as a result of lower heat-capacity of the exhaust manifold.
Technical Paper

Development of the NOx Adsorber Catalyst for Use with High-Temperature Condition

2001-03-05
2001-01-1298
NOx adsorber has already been used for the after-treatment system of series production vehicle installed with a lean burn or direct injection engine [1,2,3]. In order to improve NOx adsorbability at high temperatures, many researchers have recently been trying an addition of potassium (K) as well as other conventional NOx adsorbents. Potassium, however, reacts easily with the cordierite honeycomb substrate at high temperatures, and not only causes a loss in NOx adsorbability but also damages the substrate. Three new technologies have been proposed in consideration of the above circumstances. First, a new concept of K-capture is applied in washcoat design, mixed with zeolite, to improve thermal stability of K and to keep high NOx conversion efficiency, under high temperatures, of NOx adsorber catalyst. Second, another new technology, pre-coating silica over the boundary of a substrate and washcoat, is proposed to prevent the reaction between potassium and cordierite.
Technical Paper

Development of a New Torsional Rubber Damper for Diesel Engines

1993-05-01
931308
It is well-known that double-mass torsional rubber dampers which have two masses and springs in parallel are effective for controlling torsional vibration characteristics over a wide range of engine speed. On the occasion of reliability estimation of the rubber dampers, it is important to consider generation of heat in the rubber due to torsional vibration. By predicting generation of heat at the designing stage, optimum design of the torsional rubber dampers can be achieved. By development and application of this prediction method, a new type double-mass damper was developed. It provided higher vibration control characteristics and reliability than conventional viscous dampers, and also it provided advantages in terms of noise, productivity and weight.
Journal Article

Development of a Ceramic EHC

2022-03-29
2022-01-0536
In recent years, electrically heated catalysts (EHCs) have been developed to achieve lower emissions. In several EHC heating methods, the direct heating method, which an electric current is applied directly to the catalyst substrate, can easily activate the catalyst before engine start-up. The research results reported on the use of the direct heating EHC to achieve significant exhaust gas purification during cold start-up [1]. From the perspective of catalyst loading, ceramics is considered to be a better material for the substrate than metal due to the difference in coefficient of thermal expansion between the catalyst and the substrate, but the EHC made of ceramics has difficulties such as controllability of the current distribution, durability and reliability of the connection between the substrate and the electrodes.
Technical Paper

Development of Titanium Alloy Valve Spring Retainers

1991-02-01
910428
Beta Ti alloy valve spring retainers are newly developed for use in mass produced automobiles for the first time. Ti alloy valve spring retainers vith a weight saving of 42%, compared to steel retainers, have reduced the inertial weight of the valve train components by 6%. And this weight reduction has the benefit of increasing the upper limit of the engine speed, which improves the engine performance. Ti alloy valve spring retainers are cold forged by the conventional fabrication facilities for steel retainers, using Ti-22V-4Al (the beta Ti alloy) which possesses excellent cold workability in a solution treated condition. Oxygen surface hardening is applied to protect Ti alloy valve spring retainers from wear damage. In addition, aging treatment and shot blasting are performed to improve strength and stiffness of valve retainers.
Technical Paper

Development of High Performance Heavy-Duty Diesel Engine Oil to Extend Oil Drain Intervals: 5W30 Fully Synthetic Oil Containing MoDTC

2000-06-19
2000-01-1992
In this study, the oxidation stability, soot dispersancy, antiwear performance, and friction-reducing capability of friction modifiers (FMs) were evaluated, and an SAE 5W-30 fully synthetic oil with MoDTC type FMs was developed for heavy-duty diesel engines. In several engine tests, it was confirmed that the developed oil can double the oil drain interval in comparison with API CD SAE 30, even when EGR is applied, and improves the fuel efficiency.
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