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Carefully controlled intake valve deposit (IVD) cleanup testing is found to be an effective method for differentiating the effect of the deposit control additives on combustion chamber deposits (CCD). The IVD buildup procedure produces a consistent initial level of CCD that the cleanup additive, the additive of interest, continues to build on until the end of the cleanup test. This “end of cleanup” CCD is found to be as repeatable and differentiable a measurement as tests run under the more common “keep clean” type operation. While IVD cleanup testing induces a mid-test disturbance in the form of the end of buildup measurement, it aligns well with two key CCD protocols in terms of the higher additive treat rates used and the extended total test length. In an analysis of results from IVD cleanup tests run using four different engine/vehicle procedures on seven different additives, several findings stood out.

The operating conditions of a typical motorcycle are considerably different than those of a typical passenger car and thus require an oil capable of handling the unique demands. One primary difference, wet clutch lubrication, is already addressed by the current JASO four-stroke motorcycle engine oil specification (JASO T 903:2011). Another challenge for the oil is gear box lubrication, which may be addressed in part with the addition of a gear protection test in a future revision to the JASO specification. A third major difference between a motorcycle oil and passenger car oil is the more severe conditions an oil is subjected to within a motorcycle engine, due to higher temperatures, engine speeds and power densities. Scooters, utilizing a transmission not lubricated by the crankcase oil, also place higher demands on an engine oil, once again due to higher temperatures, engine speeds and power densities.

The Association des Constructeurs Européen d'Automobiles (ACEA) light duty diesel engine specifications requires a kinematic viscosity measurement technique for Peugeot XUD-11 BTE drain oils. This viscosity measurement is used to define the medium temperature dispersivity of soot in the drain oil.(1) This paper discusses the use of rotational rheology methods to measure the Newtonian character of XUD-11 drain oils. The calculation of the rate index using the Hershel Bulkley model indicates the level of non-Newtonian behavior of the drain oil and directly reflects the level of soot dispersion or agglomeration. This study shows that the more non-Newtonian the drain oil the greater the difference between kinematic and rotational viscosity measurements Oscillation (dynamic) rheological techniques are used to characterize build up of soot structure.

One of the key functions of lubricating oil additives in diesel engines is to control oil thickening caused by soot accumulation. Over the last several years, it has become apparent that the composition of the base oil used within the lubricant plays an extremely important role in the oil thickening phenomenon. In particular, oil thickening observed in the Mack T-8 test is significantly affected by the aromatic content of the base oil. We have found that the Mack T-8 thickening phenomenon is associated with high electrical activity, i.e., engine drain oils which exhibit high levels of viscosity increase show significantly higher conductivities. These findings suggest that electrical interactions are involved in soot-induced oil thickening.

Historically, vehicle fluid condition has been monitored by measuring miles driven or hours operated. Many current vehicles have more sophisticated monitoring methods that use additional variables such as fuel consumption, engine temperature and engine revolutions to predict fluid condition. None of these monitoring means, however, actually measures a fluid property to determine condition, and that is about to change. New sensors and diagnostic systems are being developed that allow real time measurement of some lubricant physical and/or chemical properties and interpret the results in order to recommend oil change intervals and maximize performance. Many of these new sensors use electrochemical or acoustic wave technologies. This paper examines the use of these two technologies to determine engine oil condition and focuses on the effects of lubricant chemistry on interpreting the results.

The work presented here is the second of two papers investigating the KA24E engine test. The first paper characterized the KA24E engine in terms of the physical and chemical operating environment it presents to lubricants. The authors investigated oil degradation and wear mechanisms, and examined the differences between the KA24E and the Sequence VE engine tests. It was shown that while the KA24E does not degrade the lubricant to the extent that occurs in the Sequence VE, wear could be a serious problem if oils are poorly formulated. This second paper examines the wear response of the KA24E to formulation variables. A statistically designed matrix demonstrated that the KA24E is sensitive to levels of secondary zinc dialkyldithiophosphate (ZDP), dispersant and calcium sulfonate detergent. This matrix also showed that the KA24E appears to have good repeatability for well formulated oils and is a reasonable replacement for the wear component of the Sequence VE.

The Nissan KA24E engine test is designated to replace the Ford Sequence VE engine test as the low temperature valve train wear requirement for ILSAC (International Lubricant Standardization and Approval Committee) GF-3. The KA24E (recently designated the Sequence IV A) represents much of the current world-wide material and design technology while retaining the sliding cam/follower contact found in earlier engine designs. The work presented here is the first of two reports. In this first report, the physical and chemical environment the KA24E engine presents a lubricant is characterized and compared to those of the Sequence VE engine. Valve train materials and wear modes are investigated and described. Although chemical analysis of drain oils indicate the KA24E procedure does not degrade the lubricant to the extent seen in the Sequence VE test, valve train wear appears to proceed in a similar manner in both tests.

Throughout the evolution of the automobile, passenger car motor oils have been developed to address issues of wear, corrosion, deposit formation, friction, and viscosity stability. As a result, the internal combustion engines are now developed with the expectation that the lubricants to be used in them will deliver certain performance attributes. Metallurgies, clearances, and built-in stresses are all chosen with certain expectations from the lubricant. A family of chemicals that has been universally used in formulating passenger car motor oils is zinc dithiophosphates (ZDPs). ZDPs are extremely effective at protecting highly stressed valve train components against wear failure, especially in engine designs with a sliding contact between cams and followers. While ZDPs' benefits on wear control are universally accepted, ZDPs have been identified as the source of phosphorus, which deactivates noble metal aftertreatment systems.

This study describes the use of Quantitative Structure Activity Relationships (QSAR) to develop predictive models for non-acidic Lubricity agents. The work demonstrates the importance of separating certain chemical families to give better and more robust equations rather than grouping a whole data set together. These models can then be used as important tools in further development work by predicting activities of new compounds before actual synthesis/testing.

This paper outlines the history and background of the NLGI (formerly known as the National Lubricating Grease Institute) lubricating grease specifications, GC-LB classification of Automotive Service Greases as well as details on the development of new requirements for their High-Performance Multiuse (HPM) grease certification program. The performance of commercial lubricating grease formulations through NLGI's Certification Mark using the GC-LB Classification system and the recently introduced HPM grease certification program will be discussed. These certification programs have provided an internationally recognized specification for lubricating grease and automotive manufacturers, users and consumers since 1989. Although originally conceived as a specification for greases for the re-lubrication of automotive chassis and wheel bearings, GC-LB is today recognized as a mark of quality for a variety of different applications.

Soot related viscosity increase has been reported as a field issue in some diesel engines and this led to the development of the T-11 engine test, incorporated in the Mack EO-N Premium Plus 03 specification (014 GS 12037). This study compares T-11 laboratory engine tests and vehicle field tests and seeks to confirm the correlation between them. The findings are that the T-11 test provides an effective screening tool to investigate soot related viscosity increase, and the severity of the engine test limits gives a substantial margin of safety compared to the field. A complementary study was conducted in conjunction with this work that focuses on the successful application of electrochemical sensor technology to diagnose soot content and soot related viscosity increase. This will be the subject of a separate paper.

Recently, research and testing of oxygenated diesel fuels has increased, particularly in the area of exhaust emissions. Included among the oxygenated diesel fuels are blends of diesel fuel with ethanol, or E diesel fuels. Exhaust emissions testing of E diesel fuel has been conducted by a variety of test laboratories under various conditions of engine type and operating conditions. This work reviews the existing public data from previous exhaust emissions testing on E diesel fuel and includes new testing performed in engines of varied design. Emissions data compares E diesel fuel with normal diesel fuel under conditions of different engine speeds, different engine loads and different engine designs. Variations in performance under these various conditions are observed and discussed with some potential explanations suggested.

Direct injection spark ignition (DISI) engine technology offers tremendous potential advantages in fuel savings and is likely to command a progressively increasing share of the European passenger vehicle market in the future. A concern is its propensity to form deposits on the inlet valve. In extreme cases, these deposits can lead to poor drivability and deteriorating emission performance. This inlet valve deposit build up is a well-known phenomenon in DISI engines since even additised fuel cannot wash over the back of intake valves to keep them clean. Two lubricants and two fuels were tested in a four car matrix. One of the lubricants was a fluid specifically developed by Lubrizol for DISI technology; the other was a baseline oil meeting Ford lubricants requirements and was qualified to ACEA A1/B1/ ILSAC GF2 performance level. Similarly, a baseline fuel was tested against an additised system.

Mist generated from water-soluble fluids used in machining operations represents a potentially significant contribution to worker exposure to airborne particles. Part I of this study [1], discussed polymer additives as mist suppressants for straight mineral oil metalworking fluids (MWF), which have been successfully employed at several locations. This paper focuses on recent developments in polymer mist suppressants for water-based MWF, particularly in the production environment. The polymer developed and tested in this study functions on a similar basis to that for straight oil anti-mist additives. This water soluble polymer suppresses the formation of small mist droplets and results in a distribution of larger droplet sizes. These larger droplets tend to settle out near the point of machining, resulting in a significant decrease in the total airborne mist concentration.

Increasingly stringent fuel economy and emissions regulations around the world have forced the further optimization of nearly all vehicle systems. Many technologies exist to improve fuel economy; however, only a smaller sub-set are commercially feasible due to the cost of implementation. One system that can provide a small but significant improvement in fuel economy is the lubrication system of an internal combustion engine. Benefits in fuel economy may be realized by the reduction of engine oil viscosity and the addition of friction modifying additives. In both cases, advanced engine oils allow for a reduction of engine friction. Because of differences in engine design and architecture, some engines respond more to changes in oil viscosity or friction modification than others. For example, an engine that is designed for an SAE 0W-16 oil may experience an increase in fuel economy if an SAE 0W-8 is used.

This paper features the results of emission tests conducted on diesel oxidation catalysts, and the combination of diesel oxidation catalysts and water blend fuel (diesel fuel continuous emulsion). Vehicle chassis emission tests were conducted using an urban bus. The paper reviews the impact and potential benefits of combining catalyst and water blend diesel fuel technologies to reduce exhaust emissions from diesel engines.

Wet clutch friction devices are the primary means by which torque is transmitted in many of today's modern vehicle drivelines. These devices are used in automatic transmissions, torque vectoring devices, active on-demand vehicle stability systems, and torque biasing differentials. As discussed in a previous SAE paper ( 2006-01-3270 - Next Generation Torque Control Fluid Technology, Part I: Break-Away Friction Slip Screen Test Development), a testing tool was developed to simulate a limited slip differential break-away event using a Full Scale-Low Velocity Friction Apparatus (FS-LVFA). The purpose of this test was to investigate the fundamental interactions between lubricants and friction materials. The original break-away friction screen test, which used actual vehicle clutch plates and a single friction surface, proved a useful tool in screening new friction modifier technology.

The search for alternative energy sources, particularly renewable sources, has led to increased activity in the area of ethanol blended diesel fuel, or E diesel. E diesel offers potential benefits in reducing greenhouse gases, reducing dependence on crude oil and reducing engine out emissions of particulate matter. However, there are some concerns about the use of E diesel in the existing vehicle fleet. One of the chief concerns of the use of E diesel is the affect of the ethanol on the lubricating properties of the fuel and the potential for fuel system wear. Additive packages that are used to formulate E diesel fuels can improve fuel lubricity and prevent abnormal fuel system wear. This work studies the lubricity properties of several E diesel blends and the diesel fuels that are used to form them. In addition to a variety of bench scale lubricity tests, injector pump tests were performed as an indicator of long term durability in the field.

In general the mechanical design and function of synchronized manual transmissions has remained relatively constant over the years, with incremental improvements in components, gears, bearings, seals, synchronizers and fluids continuing to advance the quality of the overall product. Marketplace demands generally drive improvements which are primarily aimed at durability and shift quality. Recently, however, advances in control and actuation technology have led to a new generation of automated manual transmissions. As a result, compatibility with electronic and valve components is becoming increasingly important. The synchronizers and fluid are two components that can affect the overall transmission performance experienced by the end user. Historically, there has been a variety of synchronizer materials, primarily brass for smaller vehicles such as passenger cars and molybdenum-based products for larger commercial vehicles.

Phosphorus is known to reduce effectiveness of the three-way catalysts (TWC) commonly used by automotive OEMs. This phenomenon is referred to as catalyst deactivation. The process occurs as zinc dialkyldithiophosphate (ZDDP) decomposes in an engine creating many phosphorus species, which eventually interact with the active sites of exhaust catalysts. This phosphorous comes from both oil consumption and volatilization. Novel low-volatility ZDDP is designed in such a way that the amounts of volatile phosphorus species are significantly reduced while their antiwear and antioxidant performances are maintained. A recent field trial conducted in New York City taxi cabs provided two sets of “aged” catalysts that had been exposed to GF-4-type formulations. The trial compared fluids formulated with conventional and low-volatility ZDDPs. Results of field test examination were reported in an earlier paper (1).