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With the current use of bio-renewable fuel, the application of Ethanol in Flex-Fuel vehicles presents a very low CO2 emission alternative when the complete cycle, from plantation, fuel production, till vehicle use, is considered. In Brazil more than 80% of the car production is composed of Flex-Fuel vehicles. Due to the lower heating content of the Ethanol, more aggressive combustion calibrations are used to obtain the same engine power than when burning gasoline. Such Ethanol demands, associated with the continuous increase of engine specific power has lead to thermo-mechanical loads which challenges the tribology of piston rings. The ethanol use brings also some specific tribological differences not very well understood like fuel dilution in the lube oil, especially on cold start, corrosive environment etc. Under specific driving conditions, incipient failures like spalling on nitrided steel top rings have been observed.

Due to several market demands of higher wear and scuffing resistance, Duplex PVD (Physical Vapor Deposition) CrN top ring has been used in Heavy Duty Diesel (HDD) engines. The ring comprises a nitrided high chromium stainless steel with a PVD ceramic CrN coating. For High Speed Diesel (HSD) vehicles with lower demands, MAHLE has developed an alternative PVD coated ring, which balances the cost and performance ratio. This alternative, named High Value PVD (HV-PVD), consists of applying the best resistant coating for wear and scuffing, PVD, onto a less costly ring material, Ductile Cast Iron. The HV-PVD top ring has been tested in HSD engines and shown excellent performance. Additional advantages of the HV-PVD are its lower friction coefficient and better tribological compatibility with the cylinder bore materials when compared to the traditional galvanic chrome based coatings. Such features lead to reduced engine friction and lower cylinder wear.