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One possibility to improve the fuel economy of SI-engines is to run the engine with a lean air-fuel-ratio (AFR). Hydrocarbon and carbon monoxide after-treatment has been proven under lean operation, but NOx-control remains a challenge to catalyst and car manufacturers. One strategy that is being considered is to run the engine lean with occasional operation at stoichiometry. This would be in conjunction with a three-way-catalyst (TWC) to achieve stoichiometric conversion of the three main pollutants in the normal way and a NOx trap. The NOx trap stores NOx under lean operation to be released and reduced under rich conditions. The trap also functions as a TWC and has good HC and CO conversion at both lean and stoichiometric AFR's. Under lean conditions NO is oxidised to NO2 on Pt which is then adsorbed on an oxide surface. Typical adsorbent materials include oxides of potassium, calcium, zirconium, strontium, lanthanum, cerium and barium.

The two major problems of diesel emission control are the reduction of nitrogen oxides and particulates. This paper describes experimental investigations to achieve both a separation of soot particles as well as a catalytic NOx reduction with hydrocarbons under lean diesel exhaust gas conditions. For that purpose a diesel particle trap is coated with a catalyst based on a Pt containing zeolite. Preliminary studies have been performed on the catalytic NOx reduction to evaluate the efficiency of a Pt/zeolite system as well as to establish the impact of operation conditions on the catalyst performance. The activity of the prepared samples (catalytic coating on particle trap) has been determined under model gas test conditions. Much attention has been focussed on the steady-state kinetics of the surface processes. Another aspect considered is the N2O formation which can be reduced, when alkali-earth or rare-earth oxides are added to the catalyst system.