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Journal Article

Well-to-Wheels Emissions of Greenhouse Gases and Air Pollutants of Dimethyl Ether from Natural Gas and Renewable Feedstocks in Comparison with Petroleum Gasoline and Diesel in the United States and Europe

2016-10-17
2016-01-2209
Dimethyl ether (DME) is an alternative to diesel fuel for use in compression-ignition engines with modified fuel systems and offers potential advantages of efficiency improvements and emission reductions. DME can be produced from natural gas (NG) or from renewable feedstocks such as landfill gas (LFG) or renewable natural gas from manure waste streams (MANR) or any other biomass. This study investigates the well-to-wheels (WTW) energy use and emissions of five DME production pathways as compared with those of petroleum gasoline and diesel using the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET®) model developed at Argonne National Laboratory (ANL).
Technical Paper

Washcoat Technology and Precious Metal Loading Study Targeting the California LEV MDV2 Standard

1996-10-01
961904
Meeting the California Medium-Duty truck emissions standards presents a significant challenge to automotive engineers due to the combination of sustained high temperature exhaust conditions, high flow rates and relatively high engine out emissions. A successful catalyst for an exhaust treatment system must be resistant to high temperature deactivation, maintain cold start performance and display high three-way conversion efficiencies under most operating conditions. This paper describes a catalyst technology and precious metal loading study targeting a California Medium-Duty truck LEV (MDV2) application. At the same time a direction is presented for optimizing toward the Federal Tier 1 standard through reduction of precious metal use. The paper identifies catalytic formulations for a twin substrate, 1.23 L medium-coupled converter. Two are used per vehicle, mounted 45 cm downstream of each manifold on a 5.7 L V8 engine.
Technical Paper

Virtual Exhaust Gas Temperature Measurement

2017-03-28
2017-01-1065
Exhaust temperature models are widely used in the automotive industry to estimate catalyst and exhaust gas temperatures and to protect the catalyst and other vehicle hardware against over-temperature conditions. Modeled exhaust temperatures rely on air, fuel, and spark measurements to make their estimate. Errors in any of these measurements can have a large impact on the accuracy of the model. Furthermore, air-fuel imbalances, air leaks, engine coolant temperature (ECT) or air charge temperature (ACT) inaccuracies, or any unforeseen source of heat entering the exhaust may have a large impact on the accuracy of the modeled estimate. Modern universal exhaust gas oxygen (UEGO) sensors have heaters with controllers to precisely regulate the oxygen sensing element temperature. These controllers are duty cycle based and supply more or less current to the heating element depending on the temperature of the surrounding exhaust gas.
Technical Paper

Utilizing Public Vehicle Travel Survey Data Sets for Vehicle Driving Pattern and Fuel Economy Studies

2017-03-28
2017-01-0232
Realistic vehicle fuel economy studies require real-world vehicle driving behavior data along with various factors affecting the fuel consumption. Such studies require data with various vehicles usages for prolonged periods of time. A project dedicated to collecting such data is an enormous and costly undertaking. Alternatively, we propose to utilize two publicly available vehicle travel survey data sets. One is Puget Sound Travel Survey collected using GPS devices in 484 vehicles between 2004 and 2006. Over 750,000 trips were recorded with a 10-second time resolution. The data were obtained to study travel behavior changes in response to time-and-location-variable road tolling. The other is Atlanta Regional Commission Travel Survey conducted for a comprehensive study of the demographic and travel behavior characteristics of residents within the study area.
Journal Article

Unified Power-Based Vehicle Fuel Consumption Model Covering a Range of Conditions

2020-04-14
2020-01-1278
Previously fuel consumption on a drive cycle has been shown to be proportional to traction work, with an offset for powertrain losses. This model had different transfer functions for different drive cycles, performance levels, and applied powertrain technologies. Following Soltic it is shown that if fuel usage and traction work are both expressed in terms of cycle average power, a wide range of drive cycles collapse to a single transfer function, where cycle average traction power captures the drive cycle and the vehicle size. If this transfer function is then normalized by weight, i.e. by working in cycle average power/weight (P/W), a linear model is obtained where the offset is mainly a function of rated performance and applied technology. A final normalization by rated power/weight as the primary performance metric further collapses the data to express the cycle average fuel power/rated power ratio as a function of cycle average traction power/rated power ratio.
Journal Article

Unified Power-Based Analysis of Combustion Engine and Battery Electric Vehicle Energy Consumption

2022-03-29
2022-01-0532
The previously developed power-based fuel consumption theory for Internal Combustion Engine Vehicles (ICEV) is extended to Battery Electric Vehicles (BEV). The main difference between the BEV model structure and the ICEV is the bi-directional character of traction motors and batteries. A traction motor model was developed as a bi-linear function of positive and negative traction power. Another difference is that the accessories and cabin heating are powered directly from the battery, and not from the powertrain. The resulting unified model for ICEV and BEV energy consumption has linear terms proportional to positive and negative traction power, accessory power, and overhead, in varying proportions. Compared to the ICEV, the BEV powertrain has a high marginal efficiency and low overhead. As a result, BEV energy consumption data under a wide range of driving conditions are mainly proportional to net traction power, with only a small offset.
Technical Paper

Transient NOx Emission Reduction Using Exhaust Oxygen Concentration Based Control for a Diesel Engine

2005-04-11
2005-01-0372
Meeting EPA Tier 2 emission standards presents a great challenge to engine manufacturers. In addition to having an actively controlled aftertreatment system, engine-out NOx emission needs to be reduced significantly to achieve regulatory compliance. Using advanced combustion methods, such as low temperature combustion and/or HCCI, has been shown to reduce engine-out NOx emissions. However, all this new combustion technologies are yet to permeate down into any production system. In current practice, large amount of exhaust gas recirculation (EGR) into the cylinders is widely used to reduce emissions. However, NOx emission from transient engine operation still constitutes a very large percentage of the total NOx output during a Federal Test Procedure (FTP) cycle and has yet to be adequately addressed. Currently, the EGR flow is controlled using the intake mass airflow (MAF) measurement.
Journal Article

Tier 2 Test Fuel Impact to Tier 3 Aftertreatment Systems and Calibration Countermeasures

2018-04-03
2018-01-0941
During the course of emissions and fuel economy (FE) testing, vehicles that are calibrated to meet Tier 3 emissions requirements currently must demonstrate compliance on Tier 3 E10 fuel while maintaining emissions capability with Tier 2 E0 fuel used for FE label determination. Tier 3 emissions regulations prescribe lower sulfur E10 gasoline blends for the U.S. market. Tier 3 emissions test fuels specified by EPA are required to contain 9.54 volume % ethanol and 8-11 ppm sulfur content. EPA Tier 2 E0 test fuel has no ethanol and has nominal 30 ppm sulfur content. Under Tier 3 rules, Tier 2 E0 test fuel is still used to determine FE. Tier 3 calibrations can have difficulty meeting low Tier 3 emissions targets while testing with Tier 2 E0 fuel. Research has revealed that the primary cause of the high emissions is deactivation of the aftertreatment system due to sulfur accumulation on the catalysts.
Technical Paper

Three-Way Catalyst Diagnostics and Prognostics Based on Support Vector Machines

2017-03-28
2017-01-0975
A three-way catalytic converter (TWC) is an emissions control device, used to treat the exhaust gases in a gasoline engine. The conversion efficiency of the catalyst, however, drops with age or customer usage and needs to be monitored on-line to meet the on board diagnostics (OBD II) regulations. In this work, a non-intrusive catalyst monitor is developed to diagnose the track the remaining useful life of the catalyst based on measured in-vehicle signals. Using air mass and the air-fuel ratio (A/F) at the front (upstream) and rear (downstream) of the catalyst, the catalyst oxygen storage capacity is estimated. The catalyst capacity and operating exhaust temperature are used as an input features for developing a Support Vector Machine (SVM) algorithm based classifier to identify a threshold catalyst. In addition, the distance of the data points in hyperspace from the calibrated threshold plane is used to compute the remaining useful life left.
Technical Paper

The Use of Subjective Jury Evaluations for Interior Acoustic Packaging

2003-05-05
2003-01-1506
Unweighted dB, dB(A), and Articulation Index do not always accurately identify the sound quality of vehicle interior noise. This paper attempts to determine the relevance of sound quality in interior automotive acoustics. Traditionally, overall dB(A) levels have been the driving factor, along with cost, in selecting an interior automotive acoustic package. In this paper, we make use of subjective jury evaluations to compare perceptions of various interior acoustic packages and compare these results to objective values. These values include, but are not restricted to, dB, dB(A), and Articulation Index. Considerations are made as to whether differences between packages can be perceived by customers. This paper also attempts to show that subjective evaluations can differ with the standard metrics used to select acoustic packages and describe why such evaluations might be important in acoustic package selection.
Technical Paper

The Use of Low Viscosity Oils to Improve Fuel Economy in Light Duty Diesel Engines

2000-06-19
2000-01-2054
Historically, fuel cost conscious customers have tended to purchase diesel passenger cars. However, with increasing competition from alternative fuels and lean burn and direct injection gasoline fuelled engines, diesel engined vehicles currently face tough challenges from the point of fuel economy and emissions. In gasoline engines, low viscosity friction modified oils have demonstrated their potential for reducing internal engine friction and thus improving fuel economy, without adversely effecting engine durability. These fuel economy improvements have led to the introduction of such a low viscosity friction modified 5W-30 oil as the initial and service fill for the majority of Ford products sold in Europe. The trend towards even lower viscosities continues. To assess the potential benefits and issues of moving to 5W-20 in diesel engines, a short pilot study has been conducted using a Ford 1.8l direct injection diesel engine.
Technical Paper

The Influence of Ammonia Slip Catalysts on Ammonia, N2O and NOX Emissions for Diesel Engines

2007-04-16
2007-01-1572
The use of urea-based selective catalytic reduction (SCR) is a promising method for achieving U.S. Tier 2 diesel emission standards for NOx. To meet the Tier 2 standards for Particulate Matter (PM), a catalyzed diesel particulate filter (CDPF) will likely be present and any ammonia (NH3) that is not consumed over an SCR catalyst would pass over the CDPF to make nitrous oxide (N2O) emissions and/or oxides of nitrogen (NOx), or exit the exhaust system as NH3. N2O is undesirable due to its high greenhouse gas potential, while NOx production from the slipped NH3 would reduce overall system NOx conversion efficiency. This paper reviews certain conditions where NH3 slip past an SCR system may be a concern, looks at what would happen to this slipped NH3 over a CDPF, and evaluates the performance of various supplier NH3 slip catalysts under varied space velocities, temperatures and concentrations of NH3 and NOx.
Technical Paper

The Effects of Load Control with Port Throttling at Idle- Measurements and Analyses

1989-02-01
890679
An experimental and analytical study was conducted to investigate the effects of load control with port throttling on stability and fuel consumption at idle. With port throttling, the pressure in the intake port increases during the valve-closed period due to flow past the throttle. If the pressure in the port recovers to ambient before the valve overlap period, back flow into the intake system from the cylinder is eliminated. This allows increased valve overlap to be used without increasing the residual mass fraction in the cylinder. Results showed that, with high valve overlap and port throttling, idle stability and fuel consumption can be maintained at values associated with low overlap in a conventionally throttled engine. However, implementation of this concept in production is regarded to require precision-fit and balanced port throttles, an external vacuum pump for vacuum systems support, and revision of the PCV system.
Technical Paper

The Effects of Aging Temperature and PGM Loading on the NOx Storage Capacity of a Lean NOx Trap

2005-04-11
2005-01-1117
A laboratory aging study was performed on samples of a lean NOx trap with platinum group metal (PGM) loadings of 0.53, 1.06, 2.12, and 3.18 g/liter. The LNT samples were aged at inlet temperatures of 650°C, 750°C, 800°C, and 850°C behind samples of a three-way catalyst that were aged on a pulse-flame combustion reactor with a Ford-proprietary durability schedule representing 80,000 km of customer use. For all aging temperatures, higher PGM loadings were beneficial for low temperature NOx performance, attributable to an increase in the oxidation of NO to NO2. Conversely, lower PGM loadings were beneficial for high temperature NOx performance after aging at 650°C and 750°C, as higher loadings promoted the decomposition of the nitrates during lean operation and thereby decreased the NOx storage capability at high temperatures. Also, higher PGM loadings increased the OSC of the trap and thereby increased the purge requirements.
Journal Article

The Effect of Hydrocarbons on the Selective Catalyzed Reduction of NOx over Low and High Temperature Catalyst Formulations

2008-04-14
2008-01-1030
Selective Catalytic Reduction of NOx is a promising technology to enable diesel engines to meet certification under Tier 2 Bin 5 emissions requirements. SCR catalysts for vehicle use are typically zeolitic materials known to store both hydrocarbons and ammonia. Ammonia storage on the zeolite has a beneficial effect on NOx conversion; hydrocarbons however, compete with ammonia for storage sites and may also block access to the interior of the zeolites where the bulk of the catalytic processes take place. This paper presents the results of laboratory studies utilizing surrogate hydrocarbon species to simulate engine-out exhaust over catalysts formulated to operate in both low (≈175-500°C) and high temperature (≈250-600°C) regimes. The effects of hydrocarbon exposure of these individual species on the SCR reaction are examined and observations are made as to necessary conditions for the recovery of SCR activity.
Technical Paper

The Effect of Different Ageing Conditions on Spatial Variations in Emissions Across the Radius of a Close-coupled After-treatment System

2005-04-11
2005-01-1095
Using local emissions measurements immediately downstream of a close-coupled catalyst, spatial variations in emissions have been analysed for close-coupled catalysts with different ageing histories. Comparison of the radial emissions profiles between a uniformly-aged (oven-aged) catalyst and two vehicle-aged parts suggests that the vehicle-aged parts have substantial variations in catalyst damage across the radius of the catalyst. The radial variations in damage were confirmed by bench reactor and post-mortem studies. The radial catalyst damage profiles inferred from engine-based evaluations of vehicle aged catalysts show broad correlation with high flow areas identified by CFD predictions and high temperature regions as measured during engine tests.
Technical Paper

The Development of Low Temperature Three-Way Catalysts for High Efficiency Gasoline Engines of the Future: Part II

2018-04-03
2018-01-0939
It is anticipated that future gasoline engines will have improved mechanical efficiency and consequently lower exhaust temperatures at low load conditions, although the exhaust temperatures at high load conditions are expected to remain the same or even increase due to the increasing use of downsized turbocharged engines. In 2014, a collaborative project was initiated at Ford Motor Company, Oak Ridge National Lab, and the University of Michigan to develop three-way catalysts with improved performance at low temperatures while maintaining the durability of current TWCs. This project is funded by the U.S. Department of Energy and is intended to show progress toward the USDRIVE target of 90% conversion of hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx) at 150 °C after high mileage aging. The testing protocols specified by the USDRIVE ACEC team for stoichiometric S-GDI engines were utilized during the evaluation of experimental catalysts at all three facilities.
Journal Article

The Development of Low Temperature Three-Way Catalysts for High Efficiency Gasoline Engines of the Future

2017-03-28
2017-01-0918
In anticipation that future gasoline engines will have improved fuel efficiency and therefore lower exhaust temperatures during low load operation, a project was initiated in 2014 to develop three-way catalysts (TWC) with improved activity at lower temperatures while maintaining the durability of current TWCs. This project is a collaboration between Ford Motor Company, Oak Ridge National Laboratory, and the University of Michigan and is funded by the U.S. Department of Energy. The ultimate goal is to show progress towards the USDRIVE goal of 90% conversion of hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx) at 150°C after high mileage aging. A reactor was set up at Ford to follow the catalyst testing protocols established by the USDRIVE ACEC tech team for evaluating catalysts for stoichiometric gasoline direct-injection (S-GDI) engines; this protocol specifies a stoichiometric blend of CO/H2, NO, C3H6, C2H4, C3H8, O2, H2O, and CO2 for the evaluations.
Technical Paper

The Aerodynamic Development of the Probe IV Advanced Concept Vehicle

1983-06-06
831000
The aerodynamic development and characteristics of a four-passenger advanced concept automobile are described. An overview of the areas of the vehicle design which were dealt with to obtain a drag coefficient value of 0.153 is provided. The interior packaging philosophy is outlined which led to the potential for packaging four to six passengers within an extremely low drag automobile. Parametric shape studies of the major surface design elements are documented from the contributing development testing. The particular design treatments adopted and the rationale behind the choice of design are examined for each of the aerodynamically-sensitive areas of the vehicle. Examinations of the unique solutions to vehicle cooling, ramp and curb clearance, front wheel skirting and vehicle attitude are presented. Full scale wind tunnel data is shown for the configurations examined and vehicle stability parameters compared with conventional vehicles.
Journal Article

TWC+LNT/SCR Systems for Satisfying Tier 2, Bin 2 Emission Standards on Lean-Burn Gasoline Engines

2015-04-14
2015-01-1006
A laboratory study was performed to assess the potential capability of TWC+LNT/SCR systems to satisfy the Tier 2, Bin 2 emission standards for lean-burn gasoline applications. It was assumed that the exhaust system would need a close-coupled (CC) TWC, an underbody (U/B) TWC, and a third U/B LNT/SCR converter to satisfy the emission standards on the FTP and US06 tests while allowing lean operation for improved fuel economy during select driving conditions. Target levels for HC, CO, and NOx during lean/rich cycling were established. Sizing studies were performed to determine the minimum LNT/SCR volume needed to satisfy the NOx target. The ability of the TWC to oxidize the HC during rich operation through steam reforming was crucial for satisfying the HC target.
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