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Since the mid 1980s, NASA has developed advanced waste management technologies that collect and process waste. These technologies include incineration, hydrothermal oxidation, pyrolysis, electrochemical oxidation, activated carbon production, brine dewatering, slurry bioreactor oxidation, composting, NOx control, compaction, and waste collection. Some of these technologies recover resources such as water, oxygen, nitrogen, carbon dioxide, carbon, fuels, and nutrients. Other technologies such as the Waste Collection System (WCS - the commode) collect waste for storage or processing. The need for waste processing varies greatly depending upon the mission scenario. This paper reviews the waste management technology development activities conducted by NASA since the mid 1980s and explores the drivers that determine the application of these technologies to future missions.

This paper discusses the development of a Vapor Phase Catalytic Ammonia Reduction (VPCAR) teststand and the results of an experimental program designed to evaluate the potential of the technology as a water purification process. In the experimental program the technology is evaluated based upon product water purity, water recovery rate, and power consumption. The experimental work demonstrates that the technology produces high purity product water and attains high water recovery rates at a relatively high specific power consumption. The experimental program was conducted in 3 phases. In phase I an Igepon™ soap and water mixture was used to evaluate the performance of an innovative Wiped-Film Rotating-Disk evaporator and associated demister. In phase II a phenol-water solution was used to evaluate the performance of the high temperature catalytic oxidation reactor.

This project is a Phase III SBIR contract between NASA and Water Reuse Technology (WRT). It covers the redesign, modification, and construction of the Wiped-Film Rotating-Disk (WFRD) evaporator for use in microgravity and its integration into a Vapor Phase Catalytic Ammonia Removal (VPCAR) system. VPCAR is a water processor technology for long duration space exploration applications. The system is designed as an engineering development unit specifically aimed at being integrated into NASA Johnson Space Center's Bioregenerative Planetary Life Support Test Complex (BIO-Plex). The WFRD evaporator and the compressor are being designed and built by WRT. The balance of the VPCAR system and the integrated package are being designed and built by Hamilton Sundstrand Space Systems International, Inc. (HSSSI) under a subcontract with WRT. This paper provides a description of the VPCAR technology and the advances that are being incorporated into the unit.

The CELSS Antarctic Analog Project (CAAP) is a joint NSF and NASA project tor the development, deployment and operation of CELSS technologies at the Amundsen-Scott South Pole Station. CAAP is implemented through the joint NSF/NASA Antarctic Space Analog Program (ASAP), initiated to support the pursuit of future NASA missions and to promote the transfer of space technologies to the NSF. As a joint endeavor, the CAAP represents an example of a working dual agency cooperative project. NASA goals are operational testing of CELSS technologies and the conduct of scientific study to facilitate technology selection, system design and methods development required for the operation of a CELSS. Although not fully closed, food production, water purification, and waste recycle and reduction provided by CAAP will improve the quality of life for the South Pole inhabitants, reduce logistics dependence, and minimize environmental impacts associated with human presence on the polar plateau.

Terraforming of Mars is the long-term goal of colonization of Mars. However, this process is likely to be a very slow process and conservative estimates involving a synergetic, technocentric approach suggest that it may take around 10,000 years before the planet can be parallel to that of Earth and where humans can live in open systems (Fogg, 1995). Hence, for the foreseeable future, any missions will require habitation within small confined habitats with high biomass to atmospheric mass ratios, thereby requiring that all wastes be recycled. Processing of the wastes will ensure predictability and reliability of the ecosystem and reduce resupply logistics. Solid wastes, though smaller in volume and mass than the liquid wastes, contain more than 90% of the essential elements required by humans and plants.

This paper presents the results from a joint research initiative between NASA Ames Research Center and Lawrence Berkeley National lab. The objective of the research is to produce activated carbon from life support wastes and to use the activated carbon to adsorb and chemically reduce the NOx and SO2 contained in incinerator flue gas. Inedible biomass waste from food production is the primary waste considered for conversion to activated carbon. Results to date show adsorption of both NOx and SO2 in activated carbon made from biomass. Conversion of adsorbed NOx to nitrogen has also been observed.

Mixed liquid/solid wastes, including feces, water processor effluents, and food waste, can be lyophilized (freeze-dried) to recover the water they contain and stabilize the solids that remain. Our previous research has demonstrated the potential benefits of using thermoelectric heat pumps to build a lyophilizer for processing waste in microgravity. These results were used to build a working prototype suitable for ground-based human testing. This paper describes the prototype design and presents results of functional and performance tests.

An energy-efficient lyophilization technique is being developed to recover water from highly contaminated spacecraft waste streams. In the lyophilization process, water in an aqueous waste is frozen and then sublimed, separating the waste into a dried solid material and liquid water. This technology is ideally suited to applications such as the Mars Reference Mission, where water recovery rates approaching 100% are desirable but production of CO2 is not. Candidate wastes include feces, concentrated brines from water processors, and other solid wastes that contain water. To operate in microgravity, and to minimize power consumption, thermoelectric heat pumps can be used in place of traditional fluid cycle heat pumps. A mathematical model of a thermoelectric lyophilizer is described and used to generate energy use and processing rate estimates.

The Lightweight Contingency Water Recovery System (LWC-WRS) harvests water from various sources in or around the Orion spacecraft in order to provide contingency water at a substantial mass savings when compared to stored emergency water supplies. The system uses activated carbon treatment (for urine) followed by forward osmosis (FO). The LWC-WRS recovers water from a variety of contaminated sources by directly processing it into a fortified (electrolyte and caloric) drink. Primary target water sources are urine, seawater, and other on board vehicle waters (often referred to as technical waters). The product drink provides hydration, electrolytes, and caloric requirements for crew consumption. The system hardware consists of a urine collection device containing an activated carbon matrix (Stage 1) and an FO membrane treatment element (or bag) which contains an internally mounted cellulose triacetate membrane (Stage 2).

Designers of future space vehicles envision simplifying the Atmosphere Revitalization (AR) system by combining the functions of trace contaminant (TC) control and carbon dioxide removal into one swing-bed system. Flow rates and bed sizes of the TC and CO2 systems have historically been very different. There is uncertainty about the ability of trace contaminant sorbents to adsorb adequately in a high-flow or short bed length configurations, and to desorb adequately during short vacuum exposures. This paper describes preliminary results of a comparative experimental investigation into adsorbents for trace contaminant control. Ammonia sorbents and low temperature catalysts for CO oxidation are the foci. The data will be useful to designers of AR systems for Constellation. Plans for extended and repeated vacuum exposure of ammonia sorbents are also presented.

A high fidelity, direct-interface, fusible heat sink for cooling astronauts during extravehicular activity was constructed and tested. The design includes special connectors that allow the coolant loop to be directly connected to the fusible material, in this case water. Aspects tested were start-up characteristics, cooling rate, and performance during simulated heat loads. A simplified math model was used to predict the effect of increasing the effective thermal conductivity on heat sink freezing rate. An experiment was designed to measure the effective thermal conductivity of a water/Aluminum foam system, and full gravity tests were conducted to compare the freezing rates of water and water/foam systems. This paper discusses the results of these efforts.

This paper presents a description of the Controlled Ecological Life Support System (CELSS) Antarctic Analog Project (CAAP) and its functionality as a pilot study for the design of a future Lunar-Mars habitat. A description of the prototype development testbed, located at Ames Research, is provided as well as an analysis of the key design parameters. The CAAP program is tasked with the development of a life support testbed at the South Pole. This facility will include food production, waste processing, and in situ energy production capabilities. The testbed will provide NASA with a remote facility located in an extremely harsh environment which has been designed to provide a useful analog to the deployment of a future Lunar-Martian habitat. NASA's program goals are the operational testing of life support technologies and the conduct of scientific studies to facilitate future technology selection and system design.

In February 2004 NASA released “The Vision for Space Exploration.” The important goals outlined in this document include extending human presence in the solar system culminating in the exploration of Mars. Unprocessed waste poses a biological hazard to crew health and morale. The waste processing methods currently under consideration include incineration, microbial oxidation, pyrolysis and compaction. Although each has advantages, no single method has yet been developed that is safe, recovers valuable resources including oxygen and water, and has low energy and space requirements. Thus, the objective of this project is to develop a low temperature oxidation process to convert waste cleanly and rapidly to carbon dioxide and water. In the Phase I project, TDA Research, Inc. demonstrated the potential of a low temperature oxidation process using ozone. In the current Phase II project, TDA and NASA Ames Research Center are developing a pilot scale low temperature ozone oxidation system.

NASA is currently developing two new human rated launch systems. They are the Crew Exploration Vehicle (CEV) and the Lunar Surface Access Module (LSAM). Both of these spacecraft will require new life support systems to support the crew. These life support systems can also be designed to reduce the mass required to keep humans alive in space. Water accounts for about 80% of the mass required to keep a person alive. As a result recycling water offers a high return on investment. Recycling water can also increase mission safety by providing an emergency supply of drinking water. This paper evaluates the potential benefits of two wastewater treatment technologies that have been designed to reduce the mass of the CEV and LSAM missions. For a 3 day CEV mission to the International Space Station (ISS) this approach could reduce the mass required to provide drinking water by 65% when compared to stored water. For an 18 day Lunar mission a mass savings of 70% is possible.

In February 2004 NASA released “The Vision for Space Exploration.” The goals outlined in this document include extending the human presence in the solar system, culminating in the exploration of Mars. A key requirement for this effort is to identify a safe and effective method to process waste. Methods currently under consideration include incineration, microbial oxidation, pyrolysis, drying, and compaction. Although each has advantages, no single method has yet been developed that is safe, recovers valuable resources including oxygen and water, and has low energy and space requirements. Thus, the objective of this work is to develop a low temperature oxidation process to convert waste cleanly and rapidly to carbon dioxide and water. Previously, TDA Research, Inc. demonstrated the potential of a low temperature dry oxidation process using ozone in a small laboratory reactor.

The purification of waste water is a critical element of any long-duration space mission. The Vapor Phase Catalytic Ammonia Removal (VPCAR) system offers the promise of a technology requiring low quantities of expendable material that is suitable for exploration missions. NASA has funded an effort to produce an engineering development unit specifically targeted for integration into the NASA Johnson Space Center's Integrated Human Exploration Mission Simulation Facility (INTEGRITY) formally known in part as the Bioregenerative Planetary Life Support Test Complex (Bio-Plex) and the Advanced Water Recovery System Development Facility. The system includes a Wiped-Film Rotating-Disk (WFRD) evaporator redesigned with micro-gravity operation enhancements, which evaporates wastewater and produces water vapor with only volatile components as contaminants. Volatile contaminants, including organics and ammonia, are oxidized in a catalytic reactor while they are in the vapor phase.

New variable environment Modified Energy Cascade (MEC) crop models were developed for all the Advanced Life Support (ALS) candidate crops and implemented in SIMULINK. The MEC models are based on the Volk, Bugbee, and Wheeler Energy Cascade (EC) model and are derived from more recent Top-Level Energy Cascade (TLEC) models. The MEC models were developed to simulate crop plant responses to day-to-day changes in photosynthetic photon flux, photoperiod, carbon dioxide level, temperature, and relative humidity. The original EC model allowed only changes in light energy and used a less accurate linear approximation. For constant nominal environmental conditions, the simulation outputs of the new MEC models are very similar to those of earlier EC models that use parameters produced by the TLEC models. There are a few differences. The new MEC models allow setting the time for seed emergence, have more realistic exponential canopy growth, and have corrected harvest dates for potato and tomato.

NASA’s planned advanced space transportation vehicles will benefit from the use of integral/conformal cryogenic propellant tanks which will reduce the launch weight and lower the earth-to-orbit costs considerably. To implement the novel concept of integral/conformal tanks requires developing an equally novel concept in thermal protection materials. Providing insulation against reentry heating and preserving propellant mass can no longer be considered separate problems to be handled by separate materials. A new family of materials, Superthermal Insulation (STI), has been conceived and investigated by NASA’s Ames Research Center to simultaneously provide both thermal protection and cryogenic insulation in a single, integral material. The present paper presents the results of a series of proof-of-concept tests intended to characterize the thermal performance of STI over a range of operational conditions representative of those which will be encountered in use.

Life Sciences research on Space Station will utilize rats to study the effects of the microgravity environment on mammalian physiology and to develop countermeasures to those effects for the health and safety of the crew. The animals will produce metabolic water which must be reclaimed to minimize logistics support. The condensate from the Research Animal Holding Facility (RAHF) flown on Spacelab Life Sciences-2 (SLS-2) in October 1993 was used as an analog to determine the type and quantity of constituents which the Space Station (SS) water reclamation system will have to process. The most significant organics present in the condensate were 2-propanol, glycerol, ethylene glycol, 1,2-propanediol, acetic acid, acetone, total proteins, urea and caprolactam while the most significant inorganic was ammonia. Microbial isolates included Xanthomonas, Sphingobacterium, Pseudomonas, Penicillium, Aspergillus and Chrysosporium.

Pyrolysis processing of solid waste in space will inevitably lead to carbon formation as a primary pyrolysis product. The amount of carbon depends on the composition of the starting materials and the pyrolysis conditions (temperature, heating rate, residence time, pressure). Many paper and plastic materials produce almost no carbon residue upon pyrolysis, while most plant biomass materials or human wastes will yield up to 20-40 weight percent on a dry, as-received basis. In cases where carbon production is significant, it can be stored for later use to produce CO2 for plant growth. Alternatively it can be partly gasified by an oxidizing gas (e.g., CO2, H2O, O2) in order to produce activated carbon. Activated carbons have a unique capability of strongly absorbing a great variety of species, ranging from SO2 and NOx, trace organics, mercury, and other heavy metals.