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HC emission standards will be tightened during the 1990's in the US. A key issue in reducing HC emission is improving the warm-up characteristics of catalysts during the cold start of engines. For this purpose, studies are under way on reduction of heat mass of ceramic substrates. Reduction of cell walls in substrates to thickness smaller than the current thickness of 12mil or 6mil has resulted in reduced heat mass, and also reduced flow restriction of substrates. The warm-up characteristics of low bulk density catalysts are better than those of high bulk density, i.e., the warm-up characteristics of thinner wall or lower cell density catalysts are better than those of thicker wall or higher cell density catalysts. A relationship between geometric surface area and warm-up characteristics is observed.

A practical ZrO2 NOx sensor using dual oxygen pumping cells has been introduced for the control of NOx emitted from a lean-burn gasoline engine and diesel engine.(1),(2). However, the measuring accuracy was not high enough to be useful for controlling or monitoring a low level of NOx concentration such as several tens ppm behind a three way catalyst or lean NOx catalyst which is NOx adsorption or De-NOx catalyst. This paper describes improvement of the interference effect of oxygen in the exhaust gas from the lean-burn gasoline engine and diesel engine. The cause of oxygen dependency is analyzed/revealed and a method of improvement is introduced. The improved NOx sensor has an approximately · · 2% measuring error in the wide range of oxygen concentration on a model gas system, compared to the · ·10% of the previous one.

This paper describes the design concept and evaluation test results of a multi-layered, thick film zirconia NOx sensor which can be used for lean-burn engine management. The oxygen concentration in the measuring gas is lowered to a predetermined level with an oxygen pumping cell, in the first stage. In the second stage, another pumping cell further lowers the oxygen concentration which results in simultaneous NOx decomposition. The second stage pumping current is proportional to the NOx concentration in the measuring gas.

This paper proposes a high temperature catalytic converter design using a ceramic substrate and intumescent matting. It also describes the improvement of converter performance using an advanced thin wall ceramic substrate. Due to future tightening of emission regulations and improvement of fuel economy, higher exhaust gas temperatures are suggested. Therefore, reduction of thermal reliability of an intumescent mat will be a concern because the catalytic converter will be exposed to high temperatures. For this reason, a new design converter has been developed using a dual cone structure for both the inlet and outlet cones. This minimizes heat conduction through the cone and decreases the temperature affecting the mat area. This design converter, without the use of a heat-shield, reduces the converter surface temperature to 441°C despite a catalyst bed temperature of 1050°C. The long term durability of the converter is demonstrated by the hot vibration test.

The DPF(Diesel Particulate Filter) has been established as a key technology in reducing diesel PM emission. Also Catalyzed-DPF Systems are viewed as the next generation DPF System in the automotive sector, replacing the current Fuel Additive System. The performance requirements of the DPF-equipped vehicle are good fuel economy, good driving performance, high PM regeneration performance of accumulated soot and high durability. In this paper the effect of Catalyzed-DPF characteristics, such as porosity, pore size, cell structure and catalyst loading have been defined on pressure drop, filtration efficiency, regeneration efficiency and regeneration behavior.

In this study, to satisfy increasingly strict emission regulations, the conversion efficiency of a 0.11 mm (4 mil) thin-wall catalyst is discussed. The effects of catalyst bulk density on reducing heat mass to improve catalyst emission conversion in the early cold transient mode (Bag 1 in the FTP-75 mode) is quantitatively discussed. To analyze the effects of low heat mass, catalyst's bed temperatures were measured. Effects of the geometric surface area (GSA) and volume of the catalyst were also analyzed. An early feedback control system with an HEGO oxygen sensor and a secondary air injection control system with an original oxygen sensor were compared with an original control system on THC, CO, and NOx emission amounts.

The Diesel Particulate Filter (DPF) system has been developed as one of key technologies to comply with tight diesel PM emission regulations. For the DPF control system, it is necessary to maintain temperature inside the DPF below the allowable service temperature, especially during soot regeneration to prevent catalyst deterioration and cracks. Therefore, the evaluation of soot regeneration is one of the key development items for the DPF system. On the other hand, regeneration evaluation requires a lot of time and cost since many different regeneration conditions should be investigated in order to simulate actual driving. The simulation tool to predict soot regeneration behavior is a powerful tool to accelerate the development of DPF design and safe regeneration control strategies. This paper describes the soot regeneration model applied to fuel additive and catalyzed types, and shows good correlation with measured data.

The engine performance and emissions characteristics of a single-cylinder DI diesel engine were experimentally investigated. The combustion chamber walls of the engine were thermally insulated with ceramic materials of SSN (Sintered Silicon Nitride) and PSZ (Partially Stabilized Zirconia). Fuel economy and emissions characteristics were improved by insulating selected locations of the combustion chamber walls. The selective insulation helped to create activated diffusion combustion and resulted in more efficient use of the intake air.

Ceramic honeycombs have been used as automotive catalyst supports in US, Japan, Europe and other highly urbanized countries. Now, engine output is a great concern for automanufacturers, and reduction of the wall thickness of honeycomb substrates became indespensable for maintenance of gas flow restriction to a certain low level. To reduce wall thickness, material should be strong to maintain canning strength of substrates. Mechanical strength was improved with high density cordierite. However, isostatic strength of whole substrates was still insufficient with reduced thin walls for canning in spite of the material's high mecanical strength. Discussion is carried out on further possibility of improving canning performance of thin wall substrates as well as flow restriction, and warm up characteristics.

Regulatory compliance measurements for vehicle emissions are generally performed in well equipped test facilities using chassis dynamometers that simulate on-road conditions. There is also a requirement for obtaining accurate information from vehicles as they operate on the road. An on-board system has been developed to measure real-time mass emission of NOx, fuel consumption, road load, and engine output. The system consists of a dedicated data recorder and a variety of sensors that measure air-to-fuel ratios, NOx concentrations, intake air flow rates, and ambient temperature, pressure and humidity. The system can be placed on the passenger seat and operate without external power. This paper describes in detail the configuration and signal processing techniques used by the on-board measurement system. The authors explain the methods and algorithms used to obtain (1) real-time mass emission of NOx, (2) real-time fuel consumption, (3) road load, and (4) engine output.

This paper describes a thick film ZrO2 NOx sensor feasible for diesel and gasoline engine applications, and introduces modification items from the previous concept design.(1) The modification items comprise simplifying the sensing element design to reduce output terminals for package design and applying temperature control to the sensing element in order to minimize sensor performance dependency on gas temperature. The NOx sensor indicates a stable linear signal in proportion to NOx concentration in a wide range of temperature, A/F and NOx concentration as a practical condition on both gasoline and diesel engines. The NOx sensor shows a good response in hundred msec. and a sharp signal following NOx generation in a transient state as well. Besides, another type of a NOx sensor is proposed for low NOx measurement in a practical use, by an electromotive force(EMF) voltage instead of a pumping current.

In order to meet the challenging CO2 targets beyond 2020 without sacrificing performance, Gasoline Direct Injection (GDI) technology, in combination with turbo charging technology, is expanding in the automotive industry. However, while this technology does provide a significant CO2 reduction, one side effect is increased Particle Number (PN) emission. As a result, from September 2017, GDI vehicles in Europe are required to meet the stringent PN emission limits of 6x1011 #/km under the Worldwide harmonized Light vehicles Test Procedure (WLTP). In addition, it is required to meet PN emission of 9x1011 #/km under Real Driving Emission (RDE) testing, which includes a Conformity Factor (CF) of 1.5 to account for current measurement inaccuracies on the road. This introduction of RDE testing in Europe and China will especially provide a unique challenge for the design of exhaust after-treatment systems due to its wide boundary conditions.

In order to meet the challenging CO2 targets beyond 2020 despite keeping high performance engines, Gasoline Direct Injection (GDI) technology usually combined with charged aspiration is expanding in the automotive industry. While providing more efficient powertrains to reduce fuel consumption one side effect of GDI is the increased particle formation during the combustion process. For the first time for GDI from September 2014 there is a Particle Number (PN) limit in EU of 6x10 sup 12 #/km, which will be further reduced by one order of magnitude to 6x10 sup 11 #/km effective from September 2017 to be the same level as applied to Diesel engines. In addition to the PN limit of the certification cycle NEDC further certification of Real Driving Emissions (RDE) including portable PN measurements are under discussion by the European Commission. RDE test procedure requires stable and low emissions in a wide range of engine operations and durable over a distance of 160 000 km.

A computational model which describes the combustion and heat transfer that takes place during forced regeneration of honeycomb structured wall flow type diesel particulate filter was developed. In this model, heat released by the soot- oxygen reaction, convection heat transfer in the gas phase, conductive heat transfer in solid walls, and heat transfer between the gas and wall of each honeycomb cell at various radial positions in a filter are calculated. Each honeycomb cell was modeled as one solid phase and two gas phases and these three phases were divided in the axial direction into small elements. Conductive heat transfer between the small solid elements and convection heat transfer between the small gas elements were calculated for each small time increment. Conductive radial heat transfer between honeycomb cells was also calculated.

Heavy Duty Vehicle (HDV) Diesel emission regulations are set to be tightened in the future. The introduction of PN PEMS testing for Euro VI-e, and the expected tightening of PM/NOx targets set to be introduced by CARB in the US beyond 2024 are expected to create challenging tailpipe PN conditions for OEMs. Additionally, warranty and the useful life period will be extended from current levels. Improved fuel efficiency (reduction of CO2) also remains an important performance criteria. Furthermore, future non-road diesel emission regulations may follow tighten HDV diesel emission regulations contents, and non-road cycles evaluation needs to be considered as well for future. In response to the above tightened regulation, for Diesel Particulate Filter (DPF) technologies will require higher PN filtration performance, lower pressure drop, higher ash capacity and better pressure drop hysteresis for improved soot detectability.

Ammonia Selective Catalytic Reduction (SCR) and Lean NOx Trap (LNT) systems are key technologies to reduce NOx emission for diesel on-highway vehicles to meet worldwide tighter emission regulations. In addition DeNOx catalysts have already been applied to several commercial off-road applications. Adding the DeNOx catalyst to existing Diesel Oxidation Catalyst (DOC) and Diesel Particulate Filter (DPF) emission control system requires additional space and will result in an increase of emission system back pressure. Therefore it is necessary to address optimizing the DeNOx catalyst in regards to back pressure and downsizing. Recently, extruded zeolite for DeNOx application has been considered. This technology improves NOx conversion at low temperature due to the high catalyst amount. However, this technology has concerned about strength and robustness, because the honeycomb body is composed of catalyst.

The presentation describes technology developments and the integration of these technologies into new emission control systems. As in other years, the reader will find a wide range of topics from various parts of the world. This is reflective of the worldwide scope and effort to reduce diesel exhaust emissions. Topics include the integration of various diesel particulate matter (PM) and Nitrogen Oxide (NOx) technologies as well as sensors and other emissions related developments. Presenter Atsuo Kondo, NGK Insulators, Ltd.

Diesel Particulate Filters (DPF) are becoming mandatory for many Heavy Duty Vehicle (HDV) and Non Road Mobile Machinery (NRMM) applications as the requirement for particulate filtration performance has increased over this past decade. In a previous study, a new generation of cordierite DPF was developed to meet the latest major emission regulations; PN-PEMS requirement for EuroVI StepE, while maintaining a lower pressure drop and high ash capacity. Despite the improvements made in the latest generation DPF material, the introduction of tighter particulate regulations demands further improvement in DPF technology. More specifically, PN emission limits for Euro7 under wide operation conditions in conjunction with PN down to 10nm, as described in the proposal from Consortium for Ultra Low Vehicle Emission (CLOVE), requires further improvement in PN filtration performance. Pressure drop, which may negatively influence the CO2 emissions, remains a key performance criteria.

The Inlet-Membrane DPF, which has a small pore size membrane formed on the inlet side of the body wall, has been developed as a next generation diesel particulate filter (DPF). It simultaneously achieves low pressure drop, small pressure drop hysteresis, high robustness, and high filtration efficiency. Low pressure drop improves fuel economy. Small pressure drop hysteresis has the potential to extend the regeneration interval since the linear relationship between pressure drop and accumulated soot mass improves the accuracy of soot mass detection by means of the pressure drop values. The Inlet-membrane DPF's high robustness also extends the regeneration interval resulting in improved fuel economy and a lower risk of oil dilution while its high filtration efficiency reduces PM emissions. The concept of the Inlet-Membrane DPF was confirmed using disc type filters in 2008 and its performance was evaluated using full block samples in 2009.

This paper describes improvements achieved with regard to the long term stability and the system integrability of a previously described thick film NOx sensor for gasoline lean burn and diesel applications. (1, 2, 3) Durability test up to 1000 hours consisting of a temperature cycle have been carried out by a stoichiometric operating gasoline engine test bench. The NOx sensor demonstrates the NOx output shift in terms of the NOx sensitivity less than 5 % on a model gas apparatus and ± 7 % measuring accuracy in practical operating condition on a diesel engine after 1000 hours that is equivalent to approximately 60K miles driving. The integration of the control electronics for the sensor in its connector is achieved for the sensitive measuring current in the μA-range or less on vehicle applications. The developed electronics functions closed-loop controls for a tip temperature and oxygen pumps as well as a diagnosis of sensor malfunctions.