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Meeting the California Medium-Duty truck emissions standards presents a significant challenge to automotive engineers due to the combination of sustained high temperature exhaust conditions, high flow rates and relatively high engine out emissions. A successful catalyst for an exhaust treatment system must be resistant to high temperature deactivation, maintain cold start performance and display high three-way conversion efficiencies under most operating conditions. This paper describes a catalyst technology and precious metal loading study targeting a California Medium-Duty truck LEV (MDV2) application. At the same time a direction is presented for optimizing toward the Federal Tier 1 standard through reduction of precious metal use. The paper identifies catalytic formulations for a twin substrate, 1.23 L medium-coupled converter. Two are used per vehicle, mounted 45 cm downstream of each manifold on a 5.7 L V8 engine.

HC emission standards will be tightened during the 1990's in the US. A key issue in reducing HC emission is improving the warm-up characteristics of catalysts during the cold start of engines. For this purpose, studies are under way on reduction of heat mass of ceramic substrates. Reduction of cell walls in substrates to thickness smaller than the current thickness of 12mil or 6mil has resulted in reduced heat mass, and also reduced flow restriction of substrates. The warm-up characteristics of low bulk density catalysts are better than those of high bulk density, i.e., the warm-up characteristics of thinner wall or lower cell density catalysts are better than those of thicker wall or higher cell density catalysts. A relationship between geometric surface area and warm-up characteristics is observed.

Exhaust temperature models are widely used in the automotive industry to estimate catalyst and exhaust gas temperatures and to protect the catalyst and other vehicle hardware against over-temperature conditions. Modeled exhaust temperatures rely on air, fuel, and spark measurements to make their estimate. Errors in any of these measurements can have a large impact on the accuracy of the model. Furthermore, air-fuel imbalances, air leaks, engine coolant temperature (ECT) or air charge temperature (ACT) inaccuracies, or any unforeseen source of heat entering the exhaust may have a large impact on the accuracy of the modeled estimate. Modern universal exhaust gas oxygen (UEGO) sensors have heaters with controllers to precisely regulate the oxygen sensing element temperature. These controllers are duty cycle based and supply more or less current to the heating element depending on the temperature of the surrounding exhaust gas.

During the course of emissions and fuel economy (FE) testing, vehicles that are calibrated to meet Tier 3 emissions requirements currently must demonstrate compliance on Tier 3 E10 fuel while maintaining emissions capability with Tier 2 E0 fuel used for FE label determination. Tier 3 emissions regulations prescribe lower sulfur E10 gasoline blends for the U.S. market. Tier 3 emissions test fuels specified by EPA are required to contain 9.54 volume % ethanol and 8-11 ppm sulfur content. EPA Tier 2 E0 test fuel has no ethanol and has nominal 30 ppm sulfur content. Under Tier 3 rules, Tier 2 E0 test fuel is still used to determine FE. Tier 3 calibrations can have difficulty meeting low Tier 3 emissions targets while testing with Tier 2 E0 fuel. Research has revealed that the primary cause of the high emissions is deactivation of the aftertreatment system due to sulfur accumulation on the catalysts.

A three-way catalytic converter (TWC) is an emissions control device, used to treat the exhaust gases in a gasoline engine. The conversion efficiency of the catalyst, however, drops with age or customer usage and needs to be monitored on-line to meet the on board diagnostics (OBD II) regulations. In this work, a non-intrusive catalyst monitor is developed to diagnose the track the remaining useful life of the catalyst based on measured in-vehicle signals. Using air mass and the air-fuel ratio (A/F) at the front (upstream) and rear (downstream) of the catalyst, the catalyst oxygen storage capacity is estimated. The catalyst capacity and operating exhaust temperature are used as an input features for developing a Support Vector Machine (SVM) algorithm based classifier to identify a threshold catalyst. In addition, the distance of the data points in hyperspace from the calibrated threshold plane is used to compute the remaining useful life left.

A practical ZrO2 NOx sensor using dual oxygen pumping cells has been introduced for the control of NOx emitted from a lean-burn gasoline engine and diesel engine.(1),(2). However, the measuring accuracy was not high enough to be useful for controlling or monitoring a low level of NOx concentration such as several tens ppm behind a three way catalyst or lean NOx catalyst which is NOx adsorption or De-NOx catalyst. This paper describes improvement of the interference effect of oxygen in the exhaust gas from the lean-burn gasoline engine and diesel engine. The cause of oxygen dependency is analyzed/revealed and a method of improvement is introduced. The improved NOx sensor has an approximately · · 2% measuring error in the wide range of oxygen concentration on a model gas system, compared to the · ·10% of the previous one.

Unweighted dB, dB(A), and Articulation Index do not always accurately identify the sound quality of vehicle interior noise. This paper attempts to determine the relevance of sound quality in interior automotive acoustics. Traditionally, overall dB(A) levels have been the driving factor, along with cost, in selecting an interior automotive acoustic package. In this paper, we make use of subjective jury evaluations to compare perceptions of various interior acoustic packages and compare these results to objective values. These values include, but are not restricted to, dB, dB(A), and Articulation Index. Considerations are made as to whether differences between packages can be perceived by customers. This paper also attempts to show that subjective evaluations can differ with the standard metrics used to select acoustic packages and describe why such evaluations might be important in acoustic package selection.

The use of urea-based selective catalytic reduction (SCR) is a promising method for achieving U.S. Tier 2 diesel emission standards for NOx. To meet the Tier 2 standards for Particulate Matter (PM), a catalyzed diesel particulate filter (CDPF) will likely be present and any ammonia (NH3) that is not consumed over an SCR catalyst would pass over the CDPF to make nitrous oxide (N2O) emissions and/or oxides of nitrogen (NOx), or exit the exhaust system as NH3. N2O is undesirable due to its high greenhouse gas potential, while NOx production from the slipped NH3 would reduce overall system NOx conversion efficiency. This paper reviews certain conditions where NH3 slip past an SCR system may be a concern, looks at what would happen to this slipped NH3 over a CDPF, and evaluates the performance of various supplier NH3 slip catalysts under varied space velocities, temperatures and concentrations of NH3 and NOx.

A laboratory aging study was performed on samples of a lean NOx trap with platinum group metal (PGM) loadings of 0.53, 1.06, 2.12, and 3.18 g/liter. The LNT samples were aged at inlet temperatures of 650°C, 750°C, 800°C, and 850°C behind samples of a three-way catalyst that were aged on a pulse-flame combustion reactor with a Ford-proprietary durability schedule representing 80,000 km of customer use. For all aging temperatures, higher PGM loadings were beneficial for low temperature NOx performance, attributable to an increase in the oxidation of NO to NO2. Conversely, lower PGM loadings were beneficial for high temperature NOx performance after aging at 650°C and 750°C, as higher loadings promoted the decomposition of the nitrates during lean operation and thereby decreased the NOx storage capability at high temperatures. Also, higher PGM loadings increased the OSC of the trap and thereby increased the purge requirements.

Selective Catalytic Reduction of NOx is a promising technology to enable diesel engines to meet certification under Tier 2 Bin 5 emissions requirements. SCR catalysts for vehicle use are typically zeolitic materials known to store both hydrocarbons and ammonia. Ammonia storage on the zeolite has a beneficial effect on NOx conversion; hydrocarbons however, compete with ammonia for storage sites and may also block access to the interior of the zeolites where the bulk of the catalytic processes take place. This paper presents the results of laboratory studies utilizing surrogate hydrocarbon species to simulate engine-out exhaust over catalysts formulated to operate in both low (≈175-500°C) and high temperature (≈250-600°C) regimes. The effects of hydrocarbon exposure of these individual species on the SCR reaction are examined and observations are made as to necessary conditions for the recovery of SCR activity.

Using local emissions measurements immediately downstream of a close-coupled catalyst, spatial variations in emissions have been analysed for close-coupled catalysts with different ageing histories. Comparison of the radial emissions profiles between a uniformly-aged (oven-aged) catalyst and two vehicle-aged parts suggests that the vehicle-aged parts have substantial variations in catalyst damage across the radius of the catalyst. The radial variations in damage were confirmed by bench reactor and post-mortem studies. The radial catalyst damage profiles inferred from engine-based evaluations of vehicle aged catalysts show broad correlation with high flow areas identified by CFD predictions and high temperature regions as measured during engine tests.

Since the monolithic ceramic substrate was introduced for automotive catalytic converters, the reduction of the substrate wall thickness has been a continuing requirement to reduce pressure drop and improve catalytic performance. The thin wall substrate of 0.10 mm (4 mil) thick wall/400 cpsi cell density has been introduced to production by achieving mechanical strength equivalent to a conventional 0.15 mm (6 mil)/400 cpsi substrate. Although a round cross-section substrate can have a reduced catalyst volume compared to an oval cross-section substrate because of uniform gas flow distribution, the smaller cross-section of the round substrate increases pressure drop. The thin wall technology was applied to the round substrate to offset the pressure drop increase and to further improve catalytic performance.

It is anticipated that future gasoline engines will have improved mechanical efficiency and consequently lower exhaust temperatures at low load conditions, although the exhaust temperatures at high load conditions are expected to remain the same or even increase due to the increasing use of downsized turbocharged engines. In 2014, a collaborative project was initiated at Ford Motor Company, Oak Ridge National Lab, and the University of Michigan to develop three-way catalysts with improved performance at low temperatures while maintaining the durability of current TWCs. This project is funded by the U.S. Department of Energy and is intended to show progress toward the USDRIVE target of 90% conversion of hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx) at 150 °C after high mileage aging. The testing protocols specified by the USDRIVE ACEC team for stoichiometric S-GDI engines were utilized during the evaluation of experimental catalysts at all three facilities.

In anticipation that future gasoline engines will have improved fuel efficiency and therefore lower exhaust temperatures during low load operation, a project was initiated in 2014 to develop three-way catalysts (TWC) with improved activity at lower temperatures while maintaining the durability of current TWCs. This project is a collaboration between Ford Motor Company, Oak Ridge National Laboratory, and the University of Michigan and is funded by the U.S. Department of Energy. The ultimate goal is to show progress towards the USDRIVE goal of 90% conversion of hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx) at 150°C after high mileage aging. A reactor was set up at Ford to follow the catalyst testing protocols established by the USDRIVE ACEC tech team for evaluating catalysts for stoichiometric gasoline direct-injection (S-GDI) engines; this protocol specifies a stoichiometric blend of CO/H2, NO, C3H6, C2H4, C3H8, O2, H2O, and CO2 for the evaluations.

The aerodynamic development and characteristics of a four-passenger advanced concept automobile are described. An overview of the areas of the vehicle design which were dealt with to obtain a drag coefficient value of 0.153 is provided. The interior packaging philosophy is outlined which led to the potential for packaging four to six passengers within an extremely low drag automobile. Parametric shape studies of the major surface design elements are documented from the contributing development testing. The particular design treatments adopted and the rationale behind the choice of design are examined for each of the aerodynamically-sensitive areas of the vehicle. Examinations of the unique solutions to vehicle cooling, ramp and curb clearance, front wheel skirting and vehicle attitude are presented. Full scale wind tunnel data is shown for the configurations examined and vehicle stability parameters compared with conventional vehicles.

A laboratory study was performed to assess the potential capability of TWC+LNT/SCR systems to satisfy the Tier 2, Bin 2 emission standards for lean-burn gasoline applications. It was assumed that the exhaust system would need a close-coupled (CC) TWC, an underbody (U/B) TWC, and a third U/B LNT/SCR converter to satisfy the emission standards on the FTP and US06 tests while allowing lean operation for improved fuel economy during select driving conditions. Target levels for HC, CO, and NOx during lean/rich cycling were established. Sizing studies were performed to determine the minimum LNT/SCR volume needed to satisfy the NOx target. The ability of the TWC to oxidize the HC during rich operation through steam reforming was crucial for satisfying the HC target.

In this study, to satisfy increasingly strict emission regulations, the conversion efficiency of a 0.11 mm (4 mil) thin-wall catalyst is discussed. The effects of catalyst bulk density on reducing heat mass to improve catalyst emission conversion in the early cold transient mode (Bag 1 in the FTP-75 mode) is quantitatively discussed. To analyze the effects of low heat mass, catalyst's bed temperatures were measured. Effects of the geometric surface area (GSA) and volume of the catalyst were also analyzed. An early feedback control system with an HEGO oxygen sensor and a secondary air injection control system with an original oxygen sensor were compared with an original control system on THC, CO, and NOx emission amounts.

A laboratory study was performed to assess the potential of using selective catalytic reduction (SCR) with NH3 to treat the NOx emissions from lean-burn gasoline engines. A primary concern was the potential for hot rich exhaust conditions on the vehicle, as such conditions could degrade the zeolite-based SCR catalysts being developed for automotive applications. Samples of an iron/zeolite formulation were aged for 34 hours behind samples of a three-way catalyst (TWC) on a pulse-flame combustion reactor using different A/F ratio schedules that exposed the catalysts to either continuously lean operation, mostly stoichiometric operation, or mostly rich operation. For each A/F ratio schedule, separate SCR samples were aged with inlet temperatures of 750°C, 800°C, or 850°C. The aged SCR samples were evaluated for NOx conversion at 25K hr-1 during lean temperature ramps with 500 ppm NO and NH3.

Over the past decade urea-based selective catalytic reduction (SCR) has become a leading aftertreatment solution to meet increasingly stringent Nitrogen oxide (NOx) emissions requirements in diesel powertrains. A common trend seen in modern SCR systems is the use of "split-brick" configurations where two SCR catalysts are placed in thermally distinct regions of the aftertreatment. One catalyst is close-coupled to the engine for fast light-off and another catalyst is positioned under-floor to improve performance at high space velocities. Typically, a single injector is located upstream of the first catalyst to provide the reductant necessary for efficient NOx reduction. This paper explores the potential benefit, in terms of improved NOx reduction, control of NH3 slip or reduced reductant consumption, of having independently actuated injectors in front of each catalyst.

Ceramic honeycombs have been used as automotive catalyst supports in US, Japan, Europe and other highly urbanized countries. Now, engine output is a great concern for automanufacturers, and reduction of the wall thickness of honeycomb substrates became indespensable for maintenance of gas flow restriction to a certain low level. To reduce wall thickness, material should be strong to maintain canning strength of substrates. Mechanical strength was improved with high density cordierite. However, isostatic strength of whole substrates was still insufficient with reduced thin walls for canning in spite of the material's high mecanical strength. Discussion is carried out on further possibility of improving canning performance of thin wall substrates as well as flow restriction, and warm up characteristics.