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The aim of this research was to investigate the mechanism causing autoignition and the effect of exhaust gas recirculation (EGR) on combustion by detecting the behavior of the OH radical and other excited molecules present in the flame in a spark ignition engine. The test equipment used was a 2-cycle engine equipped with a Schnürle scavenging system. Using emission spectroscopy, the behavior of the OH radical was measured at four locations in the end zone of the combustion chamber. The OH radical plays an important role in the elemental reactions of hydrocarbon fuels. When a certain level of EGR was applied according to the engine operating conditions, the unburned gas became active owing to heat transfer from residual gas near the measurement positions on the exhaust port side and the influence of excited species in the residual gas, and autoignition tended to occur.

This research focused on the light emission behavior of the OH radical (characteristic spectrum of 306.4 nm) that plays a key role in combustion reactions, in order to investigate the influence of the residual gas on autoignition. The test engine used was a 2-stroke, air-cooled engine fitted with an exhaust pressure control valve in the exhaust manifold. When a certain level of internal EGR is forcibly applied, the temperature of the unburned end gas is raised on account of heat transfer from the hot residual gas and also due to compression by piston motion. As a result, the unburned end gas becomes active and autoignition tends to occur.

This research focused on the light emission behavior of the OH radical (characteristic spectrum of 306.4 [nm]) that plays a key role in combustion reactions, in order to investigate the influence of the residual gas on autoignition. Authors also analyzed on the heat release and thermodynamic mean temperature due to research activity state of unburned gas. The test engine used was a 2-stroke, air-cooled engine fitted with an exhaust pressure control valve in the exhaust manifold. Raising the exhaust pressure forcibly recirculated more exhaust gas internally. When a certain level of internal EGR is forcibly applied, the temperature of the unburned end gas is raised on account of heat transfer from the hot residual gas and also due to compression by piston motion. As a result, the unburned end gas becomes active and autoignition tends to occur.

In recent years, it has been expected the conversion of wasted biomass to industry available energy. In this study, 80 wt.% of wood and 20 wt.% of polypropylene were liquefied by the mineral oil used as solvent. The liquefied material was distilled, and distillation fraction of temperature from 493 to 573 K was recognized as light oil fraction CLF (Cellulose Liquefaction Fuel) and that from 378 to 493 K was recognized as naphtha fraction CLF. CLFs were blended with light oil and, in engine performance test, mixing ratio of light oil fraction CLF was 5 wt.%, and in vehicle running test, weight mixing ratios were 5 or 10 wt.%. In engine performance test, indicator diagrams and rate of heat releases of light oil fraction CLF 5 wt.% mixed light oil were almost equivalent to those of light oil in all load conditions, and engine performance and exhaust gas emissions were also almost equivalent to light oil.