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Experimental work was carried out on a small displacement Euro 5 automotive diesel engine alternatively fuelled with ultra low sulphur diesel (ULSD) and with two blends (30% vol.) of ULSD and of two different fatty acid methyl esters (FAME) obtained from both rapeseed methyl ester (RME) and jatropha methyl ester (JME) in order to evaluate the effects of different fuel compositions on particle number (PN) emissions. Particulate matter (PM) emissions for each fuel were characterized in terms of number and mass size distributions by means of two stage dilutions system coupled with a scanning mobility particle sizer (SMPS). Measurements were performed at three different sampling points along the exhaust system: at engine-out, downstream of the diesel oxidation catalyst (DOC) and downstream of the diesel particulate filter (DPF). Thus, it was possible to evaluate both the effects of combustion and after-treatment efficiencies on each of the tested fuels.

The aim of this work is to analyze particle number and size distribution from a small displacement Euro 5 common rail automotive diesel engine, equipped with a close coupled aftertreatment system, featuring a DOC and a DPF integrated in a single canning. In particular the effects of different combustion processes on PM characteristics were investigated, by comparing measurements made both under normal operating condition and under DPF regeneration mode. Exhaust gas was sampled at engine outlet, at DOC outlet and at DPF outlet, in order to fully characterize PM emissions through the whole exhaust line. After a two stage dilution system, sampled gas was analyzed by means of a TSI 3080 SMPS, in the range from 6 to 240 nm. Particle number and size distribution were evaluated at part load operating conditions, representative of urban driving.

A set of manganese oxide catalysts was synthesized and doped with Cu and/or Fe by means of the citric acid sol-gel preparation method. The samples were studied by means of several characterization techniques: field-emission scanning electron microscopy (FESEM), X-ray powder diffraction (XRD), N2-physisorption at -196 °C, H2 and soot temperature-programmed reduction (H2-TPR, soot-TPR) and X-ray photoelectron spectroscopy (XPS). The catalytic performance of the prepared catalysts was investigated in the oxidation of a probe VOC molecule (propylene) and carbon soot singularly and simultaneously. The catalytic performances were studied as well assuring a content of 5 vol.% of water in the gaseous reactive mix. The investigations evidenced that the best soot catalytic oxidation rates occurred over the Mn2O3 sample, while the copper-doped manganese oxide (i.e. the MnCu15) showed the best performance in the decomposition of propylene.