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Ammonia is a new type of carbon-free fuel with low cost, clean and safe. The research and application of zero-carbon fuel internal combustion engines has become the mainstream of future development. However, there still exist problems should be solved in the application of ammonia fuel. Due to the lower flame laminar speed and higher ignition temperature, ammonia may have unstable combustion phenomena. In this work, the characteristics of ammonia combustion have been investigated, based on controllable thermal activated atmosphere burner. The ignition delay has been used to analyze the ammonia combustion characteristics. With the increase in co-flow temperature, the ignition delay of ammonia/air has an obvious decline. In order to investigate the emission characteristics of ammonia, CHEMKIN is used to validate the different chemical reaction mechanisms and analyse the ammonia emissions.