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In studying H2S emissions, it is desirable to have an analytical technique which is rapid, continuous, accurate and easy to use in a laboratory or vehicle exhaust environment. Typically, H2S has been measured using the EPA impinger method with collection times on the order of 1 to 2 minutes. Other techniques have been developed with significantly shorter response times. However, it has been shown that the major release of H2S occurs in less than 20 seconds after a vehicle changes from rich to lean operation. Therefore, it is highly desirable to have an H2S analytical technique with a response time of less than 10 seconds. In this paper, the benefits of use of a chemical ionization mass spectrometer (CIMS) to continuously monitor H2S and SO2, emissions are reported. Using the CIMS technique, the effects of several operating parameters on the release of H2S and SO2 from automotive catalysts were studied.

This study reports on laser-based diagnostics to temporally track the evolution of liquid and gaseous fuel in the cylinder of a direct injection production type Diesel engine. A two-dimensional Mie scattering technique is used to record the liquid phase and planar laser-induced fluorescence of Diesel is used to track both liquid and vaporised fuel. LIF-Signal is visible in liquid and gas phase, Mie scattering occurs only in zones where fuel droplets are present. Distinction between liquid and gaseous phase becomes therefore possible by comparing LIF- and Mie-Signals. Although the information is qualitative in nature, trends of spray evolution are accessible. Within this study a parametric variation of injection pressure, in-cylinder conditions such as gas temperature and pressure as well as piston geometry are discussed. Observations are used to identify the most sensitive parameters and to qualitatively describe the temporal evolution of the spray for real engine conditions.

The paper presents the results of the STYFF-DEXA project which has delivered an attractive computational approach based on detailed treatment of the filtration and regeneration processes inside diesel particulate foam filter materials. The new approach can provide accurate macroscopic material parameters by utilizing tomographic data and novel algorithms to reconstruct three-dimensional digital representations of the foam material microstructure. The Lattice-Boltzmann (LB) Method is used as a basis for computing the flow within the foam pores. The latter is coupled to sub-models of particle transport/deposition and size distribution based on the very efficient Method of Moments which employs a probability density function representation of the suspended soot. Additionally, acoustics modelling functionality has been developed which permits the evaluation of the engine noise attenuation capabilities of the foams and similar microstructures.

For the first time in volume production, supporting welded aluminum structures were used in the chassis area. Metal sheets, extruded sections, longitudinally seam welded pipes and castings were used as semi-finished products. Extensive strength tests, in cooperation with the Design Department and Production, resulted in sophisticated design solutions. In considering matters important to the customer, these solutions were substantiated through numerous examinations which are especially necessary for aluminum.

A stationary model of a car air conditioning system was developed to evaluate refrigerant, mechanical power and all the fluid properties along the circuit. The model requires only the characteristics of the constituents, which are normally available from suppliers. This approach enables estimation of system performance with satisfactory accuracy, already during the design approach, and allows to determine the most appropriate components in order to meet target requirements with a satisfactory balance of the refrigerant circuit.

Secondary air injection after cold start gives two effects for reduced exhaust emissions: An exothermic reaction at the hot exhaust valves occurs, which increases the temperature of the exhaust gas. It gives sufficient air to the catalyst during the cold start fuel enrichment that is necessary to prevent driveability problems. Handicaps for the wide use of air injection include space constraints, weight and price. An electrical air blower was choosen to best satisfy all these requirements. The development steps are described. The result is a three stage radialblower with extremly high revolutions of about 18000 rpm. The system configuration and the outcome are demonstrated on the new C-Class of Mercedes-Benz. The results show emission reductions higher than 50 %, while also satisfying the development goals of noise, volume, weight and cost requirements.

In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure Basic investigations of elementary steps of the chemical reaction Production and prescreening of different catalytic material on laboratory scale Application oriented screening of industrial catalyst material Catalyst testing on a lean bum gasoline engine, passenger car diesel engines (swirl chamber and DI) and on a DI truck engine Although a number of solid body structures show nitrogen oxide reduction by hydrocarbons, only noble metal containing catalysts and transition metal exchanged zeolites gave catalytic efficiencies of industrial relevance. A maximum of 25 % NOx reduction was found in the European driving cycle for passenger cars, about 40 % for truck engines in the respective European test.

BMW - the driving force for progress As we approach the new millenium, to ensure the continuation of the progress into the future, BMW uses leading edge approaches in its materials research and processing. Overview production sites all over the world - Plant Dingolfing Quality requirements for automobile painting The complex and wide-ranging demands that the outer skin of an automobile has to meet offered us the chance to advance with a technological leap from liquid clear coat to the potentials of powder clear coat. The new clear coat technology The clear coat creates the ultimate gloss effect - and powder-based clear coat makes the surface of the car even more brilliant. To achieve this effect the body is covered by microscopically small paint particles. A pioneer achievement A lot of challenges in both material development and systems-engineering had to be made. The automotive world was watching, many experts said it could not be successfully used as an OEM clear coat.

A new category of hypereutectic aluminum liners, made by PM route is now available on the market (SILITEC) and it is successfully applied to high-pressure die casting process to produce open deck cylinder blocks. The claimed achievable engine performances over cast-iron liners (weight saving, reduction of oil consumption, optimal heat transfer, wear and friction losses reduction) justify the interest of automotive industry in developing such a technology. The paper will present the experience and the achieved results in permanent mold gravity casting with Silitec liners, where metal flow definition and temperature distribution control make the casting technique more challenging for the manufacturing of closed deck cylinder blocks.

The emissions legislation in the US and Europe introduces the need for the application of diesel particulate filters (DPF) in most diesel vehicles. In order to fulfill future OBD legislations, which include more stringent requirements on monitoring the functionality of those particulate filters, new sensors besides the differential pressure sensor are necessary. The new sensors need to directly detect the soot emission after DPF and withstand the harsh exhaust gas environment. Based on multi layer ceramic sensor technology, an exhaust gas sensor for particulate matter (EGS-PM) has been developed. The soot-particle-sensing element consists of two inter-digitated comb-like electrodes with an initially infinite electrical resistance. During the sensor operation, soot particles from the exhaust gas are collected onto the inter-digital electrodes and form conductive paths between the two electrode fingers leading to a drop of the electrical resistance.

Ceramic protective coatings on cutting tools for steel machining are state of the art in industrial applications. Several concepts to improve the efficiency of machining processes as for instance high-speed or dry cutting yield increasing demands regarding the wear and corrosion resistance of the protective tool coatings. The generic process characteristics of PVD-coating techniques offer opportunities to tailor the coatings in terms of microstructure and residual stress states by adjusting appropriate process parameters. Besides chemical composition and microstructure the residual stresses in the coatings strongly influence their in-service performance and, are therefore important to assess and to correlate with process parameters.

The quality of the paint application in automotive industry depends on several process parameters. Thus, finding an optimal solution based on experimental configuration is tedious and time consuming. A first step to reduce the effort is to model the application within the framework of a simulation environment. In this study, we present an approach for the systematic variation of design parameters of the paint process to quantify their influence on the quality of the paint application. Using that information the design space is reduced by neglecting the parameters with low impact and later used to predict an optimal set of input parameters for an optimal paint application.

The air conditioning system of a car uses the reverse Carnot thermodynamic cycle of a refrigerant gas. The fluids normally used have at least a direct impact on global warming, so their losses have to be avoided. A very simple method to detect refrigerant charge level was developed, using few standard sensors. Results show that it is possible to have an estimation of system charge level with satisfactory accuracy, and seems able to avoid complete loss of refrigerant.

Modern zirconia oxygen sensors are heated internally to achieve an optimal detection of the oxygen concentration in the exhaust gas and fast light off time. The temperature of the gas in the exhaust pipe varies in a wide range. The zirconia sensor is cooled by radiation and forced convection caused by cold exhaust gas. If the zirconia temperature falls, the oxygen detection capability of the sensor decreases. To minimize the cooling effects, protection tubes cover the zirconia sensor. However, this is in conflict with the aim to accelerate the dynamics of the lambda sensor. In this paper, the heat transfer at the surface of a heated planar zirconia sensor with two different double protection tubes of a Bosch oxygen sensor is examined in detail. The geometric configuration of the tubes forces different flow patterns in the inner protection tube around the zirconia sensor. The zirconia sensor is internally electrically heated by a platinum heater layer.

Within the scope of this work, the convective mass transfer to the zirconia sensor element of an exhaust oxygen sensor was analyzed experimentally and numerically. For the experimental setup, a heightened model of an oxygen sensor was built from Lucite® considering the similarity theory. Mass transfer is measured based on the absorption of ammonia and subsequent immediate color reaction. For the numerical investigation, a three-dimensional model of the test rig was built. To predict the flow pattern and the species transport inside the protection tubes, the commercial CFD-Code FLUENT® is used. The model for the mass transfer to the surface is implemented through user-defined functions.

Today's wide range oxygen sensors are based on the limiting current principle, where an applied voltage induces electrochemical reactions in a ceramic cell. Since the diffusive transport of exhaust gas to the electrodes is limited by a transport barrier, the resulting electric current can be related to the exhaust gas composition. A model is presented which describes the transient transport of gas mixtures from the bulk exhaust gas to the electrodes of an oxygen sensor at variable pressure and composition. The internal structure of the transport barrier was accounted for by geometrical parameters. A variety of numerical results are compared with experimental data.

Current regulatory developments aim for stricter emission limits, increased environmental protection and purification of air on a local and global scale. In order to find solutions for a cleaner combustion process, it is necessary to identify the critical components and parameters responsible for the formation of emissions. This work provides an evaluation process for particle formation during combustion of a modern direct injection engine, which can help to create new aftertreatment techniques, such as a gasoline particle filter (GPF) system, that are fit for purpose. With the advent of “real driving emission” (RDE) regulations, which include market fuels for the particulate number testing procedure, the chemical composition and overall quality of the fuel cannot be neglected in order to yield a comparable emission test within the EU and worldwide.

The manufacture of semiconductor sensors requires high investment and does not become economically viable until very high production numbers come into consideration. In the case of low production numbers, of the kind that come into consideration for production startups, and in the case of variations e.g. in the measuring range and similar, as may be the case due to the adaptation of models, it may be more viable to employ other techniques which likewise have a high rationalization potential which comes into effect already at low production numbers and which exhibits greater flexibility. The film techniques offer alternative sensor concepts for many measured quantities, whose production is reasonable in price even at smaller production numbers and possesses the necessary alteration flexibility. Besides these, are the advantages of the laser adjustment and the seamless connection of the evaluation electronics. Even possibilities laying within micro-machining technology can be used.

A lot of very valuable information has already been gained in the process of dismantling, assorting and reconditioning plastic parts on old cars, in reconditioning defective plastic parts from workshops, and in the use of reject parts from production. This know-how is now applied primarily to increase the use of recycled plastics and to optimise the composition and design of future plastic components in the interest of recycling, since further development in these areas is essential in order to establish economically stable material cycles functioning properly in the long term. The present paper describes the most important criteria through which the materials and designs chosen affect the processes and principles of recycling in the case of plastic parts and components.

Ultrasonic transducers are widely used in automotive and industrial applications for surround sensing. Anisotropic directivity patterns with a narrow-angled beam in the vertical plane and a wide-angled beam in the horizontal plane are needed in automotive applications particularly. Today’s ultrasonic transducers for automotive applications are mainly metal based, pot-like ultrasonic transducers. The anisotropic directivity pattern is achieved by increasing the thickness of the vibrating plate-like part of the structure locally. Composites with locally structured fiber reinforcements open up the possibility to design the dynamical behavior of components without changing its contour. Using this new dimension of design to modify the directivity pattern of sound radiating components is less examined in literature.