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In studying H2S emissions, it is desirable to have an analytical technique which is rapid, continuous, accurate and easy to use in a laboratory or vehicle exhaust environment. Typically, H2S has been measured using the EPA impinger method with collection times on the order of 1 to 2 minutes. Other techniques have been developed with significantly shorter response times. However, it has been shown that the major release of H2S occurs in less than 20 seconds after a vehicle changes from rich to lean operation. Therefore, it is highly desirable to have an H2S analytical technique with a response time of less than 10 seconds. In this paper, the benefits of use of a chemical ionization mass spectrometer (CIMS) to continuously monitor H2S and SO2, emissions are reported. Using the CIMS technique, the effects of several operating parameters on the release of H2S and SO2 from automotive catalysts were studied.

Novel Combustion technologies and strategies show high potential in reducing the fuel consumption of gasoline spark ignition (SI) engines. In this paper, a comparison between various gasoline combustion concepts at two representative engine operating points is shown. Advantages of the combustion concepts are analyzed using thermodynamic split of losses method. In this paper, a tool for thermodynamic assessment (Split of Losses) of conventional and new operating strategies of SI engine and its derivatives is used. Technologies, like variable valve actuation and/or gasoline direct injection, allow new strategies to run the SI engine unthrottled with early inlet valve closing (SI-VVA) combined with high EGR, charge stratification (SI-STRAT) and controlled auto ignition (CAI), also known as gasoline homogeneous charge compression ignition (HCCI). These diverse combustion concepts show thermodynamic gains that stem from several, often different sources.

The Bosch Common Rail Fuel Injection System with the new technologies developed for the Duramax 6600 engine offer numerous performance advantages including exhaust emissions control and noise. The layout of the fuel system components and electrical parts is specifically designed to control fuel injection characteristics. The new injector and nozzle technology was integrated to achieve the required system performance. The new 1600bar fuel pump is also a prerequisite for required system performance.

For the BMW V8 engine, a new LEV/EU3 emission concept has been developed by improvements to the previous engine management and secondary air supply and a complete new exhaust system. Beside the emission limits, also high engine output targets and high operating reliability were targeted. In addition the new exhaust system had to meet low cost targets. Based on these requirements an exhaust concept with separate pre catalyst and main catalyst was chosen. To reduce the heat mass and to optimize the pressure drop, 4.3mil/400cpsi thin wall ceramic substrates were used for the pre and main catalyst.

To meet LEV and EU Stage III emission requirements, it is necessary for new catalytic converters to be designed which exceed light-off temperature as quickly as possible. The technical solutions are secondary air injection, active heating systems such as the electrically heated catalytic converter, and the close coupled catalytic converter. Engine control functions are extensively used to heat the converter and will to play a significant role in the future. The concept of relocating the converter to a position close to the engine in an existing vehicle involves new conflicts. Examples include the space requirements, the thermal resistance of the catalytic coating and high temperature loads in the engine compartment.

The tightening of Heavy Duty Diesel (HDD) emissions legislation throughout the world is leading to the development of emission control devices to enable HDD engines to meet the new standards. NOx and Particulate Matter (PM) are the key pollutants which these emission control systems need to address. Diesel Particulate Filters (DPFs) are already in use in significant numbers to control PM emissions from HDD vehicles, and Selective Catalytic Reduction (SCR) is a very promising technology to control NOx emissions. This paper describes the development and performance of the Compact SCR-Trap system - a pollution control device comprising a DPF-based system (the Continuously Regenerating Trap system) upstream of an SCR system. The system has been designed to be as easy to package as possible, by minimising the total volume of the system and by incorporating the SCR catalysts on annular substrates placed around the outside of the DPF-based system.

Secondary air injection after cold start gives two effects for reduced exhaust emissions: An exothermic reaction at the hot exhaust valves occurs, which increases the temperature of the exhaust gas. It gives sufficient air to the catalyst during the cold start fuel enrichment that is necessary to prevent driveability problems. Handicaps for the wide use of air injection include space constraints, weight and price. An electrical air blower was choosen to best satisfy all these requirements. The development steps are described. The result is a three stage radialblower with extremly high revolutions of about 18000 rpm. The system configuration and the outcome are demonstrated on the new C-Class of Mercedes-Benz. The results show emission reductions higher than 50 %, while also satisfying the development goals of noise, volume, weight and cost requirements.

In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure Basic investigations of elementary steps of the chemical reaction Production and prescreening of different catalytic material on laboratory scale Application oriented screening of industrial catalyst material Catalyst testing on a lean bum gasoline engine, passenger car diesel engines (swirl chamber and DI) and on a DI truck engine Although a number of solid body structures show nitrogen oxide reduction by hydrocarbons, only noble metal containing catalysts and transition metal exchanged zeolites gave catalytic efficiencies of industrial relevance. A maximum of 25 % NOx reduction was found in the European driving cycle for passenger cars, about 40 % for truck engines in the respective European test.

The usage of Electronic Diesel Control is increasing with todays stringent emissions regulations. This requirement also necessitates that such systems be versatile to meet the needs of the engine/vehicle manufacturer. EGR, start of injection, and fuel delivery can be electronically controlled. Depending on the design goals of the manufacturer any one or two of these can be controlled for partial and all of them for full Electronic Diesel Control. The development and application process has several critical areas. These include, development of the sensors, application of the different subsystems, failure warning and failure mode operation. All of these must be combined if design goals are to be met. As the capabilities of electronics increase it follows that electronic vehicle systems will also improve. Today impressive results have been achieved with systems that are in full or pilot production.

The success of model-based ECU-functions relies on precise and efficient modeling of the behavior of combustion engines. Due to the limited computing power, usually a combination of physical models and calibration parameters is preferred for engine modeling in ECU. The parameters can be scalars, 1 or 2-dimensional empirical models, such as look-up table for volumetric efficiency and effective area of the exhaust gas recirculation (EGR). A novel algorithm is proposed to automatically calibrate the look-up tables characterizing stationary functional relationships in ECU-function of the air system of a diesel engine with minimum calibration cost. The algorithm runs in the framework of online design of experiment (DoE), in which Gaussian process model (GPM) is adopted to approximate the relationships of interest.

Misfiring of the engine can cause damage to the catalyst within short time and increase emissions. Under misfiring conditions, unburned fuel and oxygen are pumped into the catalyst, where its combustion heavily increases the temperature. For this reason there is a demand for fast detection of misfiring. Once judged, one can take countermeasures to avoid further temperature rise. Two methods of misfire detection with the prospect of future use in series production are discussed. A first approach uses the trace shape of the λ-sensor signal for evaluation. The second approach uses the speed fluctuations of the engine for detection. Efficient algorithms give the possibility of misfire detection in the full load-speed range with reasonable effort to protect the catalyst. However there will remain some misfire conditions, increasing the emissions above regulation limits, that cannot be detected by those methods.

Previous research has shown that elevating fuel injection pressure results in better air-fuel mixture formation, allowing for a further increase in maximum exhaust gas recirculation (EGR) rate while consequently reducing NOx emissions. The aim of this paper is to find out whether there is an optimum injection pressure for lowest soot-NOx emissions at a given boost pressure in high-speed diesel engines. Experiments are carried out on a single-cylinder research engine with a prototype common-rail system, capable of more than 200 MPa injection pressure. The effect of injection pressure on soot-NOx formation is investigated for a variety of boost conditions, representing the conditions of single to multi-stage turbocharger systems. Analysis of the data is performed at the application relevant soot to NOx ratio of approximately 1:10. It is observed that above a critical injection pressure, soot-NOx emissions are not reduced any further.

1 High precision high pressure diesel common rail fuel injection systems play a key role in emission control, fuel consumption and driving performance. Deposits have been observed on internal injector components, for example in the armature assembly, in the slots of the piston and on the nozzle needle. The brownish to colourless deposits can adversely impact driveability and result in non-compliance with the Euro 4 or Euro 5 emission limits. The deposits have been extensively studied to understand their composition and their formation mechanism. Due to the location of these deposits, the influence of combustion gas can be completely ruled out. In fact, their formation can be explained by interactions of certain diesel fuel additives, including di- and mono-fatty acids. This paper describes the methodology used and the data generated that support the proposed mechanisms. Moreover, approaches to avoid such interactions are discussed.

Apart from the reduction of engine-out emissions from the powerplant, the development of an efficient and reliable catalytic converter heating system is an important task of automotive engineering in the future to meet standards that will require reduction of cold start emissions. Carrying out a comprehensive study in this field, BMW has tested and evaluated possible solutions to this challenge. In additon to the electrically heated catalytic converter (E-cat) and the afterburner chamber, an incorporated burner system would meet the requirement for fast catalyst light-off in the future, particularly in the case of larger engines.

Historically, whenever the automotive solutions’ state of art reaches a saturation level, the integration of new verticals of technology has always raised new opportunities to innovate, enhance and optimize automotive solutions. The predictive powertrain solutions using connectivity elements (e.g., navigation unit, e-Horizon or cloud-based services) are one of such areas of huge interest in automotive industry. The prior knowledge of trip destination and its route characteristics has potential to make prediction of powertrain modes or events in certain order and therefore it can add value in various application areas such as optimized energy management, lower fuel consumption, superior safety and comfort, etc.

Meeting current exhaust emission standards requires rapid catalyst light-off. Closed-coupled catalysts are commonly used to reduce light-off time by minimizing exhaust heat loss between the engine and catalyst. However, this exhaust gas system design leads to a coupling of catalyst heating and engine operation. An engine-independent exhaust gas aftertreatment can be realized by combining a burner heated catalyst system (BHC) with an underfloor catalyst located far away from the engine. This paper describes some basic characteristics of such a BHC system and the results of fitting this system into a Volkswagen Touareg where a single catalyst was located about 1.8 m downstream of the engine. Nevertheless, it was possible to reach about 50% of the current European emission standard EU 4 without additional fuel consumption caused by the BHC system.

The production of the BMW ALPINA B12 5.7 with Switch-Tronic transmission provides the markets of Europe and Japan with an exclusive, luxury-orientated, high performance limited series limousine. This is the first vehicle worldwide to be fitted with the progressive exhaust gas aftertreatment technology known as the Electrically Heated Catalyst (EHC), in which the effectiveness of the power utilized is increased significantly by an alternating heating process for both catalytic converters. Only since this achievement has the implementation of the EHC been viable without extensive modification to the battery and alternator. With this exhaust gas aftertreatment concept, the emissions of this high performance vehicle will fall to less than half the maximum permissible for compliance with 1996 emission standards.

The study presented in this paper focuses on measures to minimize exhaust gas emissions to meet SULEV targets on a V6 engine by using a cost efficient system configuration. The study consists of three parts. A) In the first stage, the influence of engine management both on raw emissions and catalyst light off performance was optimized. B) Afterwards, the predefined high cell density catalyst system was tested on an engine test bench. In this stage, thermal data and engine out emissions were used for modeling and prediction of light-off performance for further optimized catalyst concepts. C) In the final stage of the program, the emission performance of the test matrix, including high cell density as well as multifunctional single substrate systems, are studied during the FTP cycle. The presented results show the approach to achieve SULEV emission compliance with innovative engine control strategies in combination with a cost effective metallic catalyst design.

In this article a new zero-dimensional model is presented for simulating the cylinder pressure in direct injection diesel engines. The model enables the representation of current combustion processes considering multiple injections, high exhaust gas recirculation rates, and turbocharging. In these methods solely cycle-resolved, scalar input variables from the electronic control unit in combination with empirical parameters are required for modeling. The latter are adapted automatically to different engines or modified applications using measured cylinder pressure traces. The verification based on measurements within the entire operating range from engines of different size and type proves the universal applicability and high accuracy of the proposed method.

The present paper concentrates on the option of catalytic autothermal reforming of gasoline for fuel cell applications. Major parameters of this process are the “Steam to Carbon Ratio” S/C and the air to fuel ratio λ. Computations assuming thermodynamic equilibrium in the autothermal reactor outlet (ATR) were carried out to attain information about their proper choice, as failure in adjusting the parameters within narrow limits has severe consequences on the reforming process. In order to quantify velocity distribution just ahead the catalyst and to evaluate mixing uniformity we designed an ATR featuring an optical access: Thus flow visualization using PIV (Particle Image Velocimetry) and LIF (Laser Induced Fluorescence) technique is possible. Preliminary PIV-results are presented and compared with CFD computations (Computational Fluid D ynamics).