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In order to reduce fuel consumption and polluting emissions from engines, alternative fuels such as hydrogen could play an important role towards carbon neutrality. Moreover, dual-fuel (DF) technology has the potential to offer significant improvements in carbon dioxide emissions for transportation and energy sectors. The dual fuel concept (natural gas/diesel or hydrogen/diesel) represents a possible solution to reduce emissions from diesel engines by using low-carbon or carbon-free gaseous fuels as an alternative fuel. Moreover, DF combustion is a possible retrofit solution to current diesel engines by installing a PFI injector in the intake manifold while diesel is injected directly into the cylinder to ignite the premixed mixture. In the present study, dual fuel operation has been investigated in a single cylinder research engine.

The application of an alternative fuel such as hydrogen to internal combustion engines is proving to be an effective and flexible solution for reducing fuel consumption and polluting emissions from engines. An easy to use and immediate application solution is the dual fuel (DF) technology. It has the potential to offer significant improvements in carbon dioxide emissions from light compression ignition engines. The dual fuel concept (natural gas / diesel or hydrogen / diesel) represents a possible solution to reduce emissions from diesel engines by using low-carbon or carbon-free gaseous fuels as an alternative fuel. Moreover, DF combustion is a possible retrofit solution to current diesel engines by installing a PFI injector in the intake manifold while diesel is injected directly into the cylinder to ignite the premixed mixture. In the present study, dual fuel operation has been investigated in a single cylinder research engine.

Although in the latest years the use of compression ignition engines has been a thread of discussion in the automotive field, it is possible to affirm that it still will be a fundamental producer of mechanical power in other sectors, such as naval and off-road applications. However, the necessity of reducing emissions requires to keep on studying new solutions for this kind of engine. Dual fuel combustion concept with methane has demonstrated to be effective in preserving the performance of the original engine and reducing soot, but issues related to the low flame speed forced researcher to find an alternative fuel at low impact of CO2. Hydrogen, thanks to its chemical and physical properties, can be a perfect candidate to ensure a good level of combustion efficiency; however, this is possible only with a proper management of the in-cylinder mixture ignition by means of a pilot injection, preventing uncontrolled autoignition events as well.

Nowadays, the stricter regulations in terms of emissions have limited the use of diesel engines on urban roads. On the contrary, for marine and off-road applications the diesel engine still represents the most feasible solution for work production. In the last decades, dual fuel operation with methane supply has been widely investigated. Starting from previous studies on a research engine, where diesel-methane dual fuel combustion has been deepened both experimentally and numerically with the aid of a CFD code, the authors implemented and tested a kinetic mechanism. It is obtained from the combination of the well-established GRIMECH 3.0 and a detailed scheme for a diesel surrogate oxidation. Moreover, the Autoignition-Induced Flame Propagation model, included in the ANSYS Forte® software, is applied because it can be considered the most appropriate model to describe dual fuel combustion.

In the perspective of a reduction of emissions and a rapid decarbonisation, especially for compression ignition engines, hydrogen plays a decisive role. The dual fuel technology is perfectly suited to the use of hydrogen, a fuel characterized by great energy potential. In fact, replacing, at the same energy content, the fossil fuel with a totally carbon free one, a significant reduction of the greenhouse gases, like carbon dioxide and total hydrocarbon, as well as of the particulate matter can be obtained. The dual fuel with indirect injection of gaseous fuel in the intake manifold, involves the problem of hydrogen autoignition. In order to avoid this difficulty, the optimal conditions for the injection of the incoming mixture into the cylinder were experimentally investigated. All combustion processes are carried out on a research engine with optical access. The engine speed has is set at 1500 rpm, while the EGR valve is deactivated.

In this work, an ozone/air/gasoline mixture has been used as an alternative strategy to achieve a stable combustion in a spark ignition (SI) single cylinder PFI research engine. The air intake manifold has been modified to include four cells to produce ozone with different concentrations. In the research engine, various operating parameters have been monitored such as the in-cylinder pressure, temperature and composition of the exhaust gases, pressure and temperature of the mixture in the intake manifold, engine power and torque and specific fuel consumption. Experimental tests have been carried out under stoichiometric mixture conditions to observe the influence of ozone addition on the combustion process. The results show an advance and an increase of the in-cylinder pressure compared to the reference test-case, where a gasoline/air mixture is used. It is worth noting that, especially under stoichiometric condition, ozone concentration induces auto-ignition and knock.