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Mechanisms responsible for enhanced charge reactivity with intake added ozone (O3) were explored in a single-cylinder, optically accessible, research engine configured for low-load advanced compression ignition (ACI) experiments. The influence of O3 concentration (0-40 ppm) on engine performance metrics was evaluated as a function of intake temperature and start of injection for the engine fueled by iso-octane, 1-hexene, or a 5-component gasoline surrogate. For the engine fueled by either the gasoline surrogate or 1-hexene, 25 ppm of added O3 reduced the intake temperature required for stable combustion by 65 and 80°C, respectively. An ultraviolet (UV) light absorption diagnostic was also used to measure crank angle (CA) resolved in-cylinder O3 concentrations for select motored and fired operating conditions. The O3 measurements were compared to results from complementary 0D chemical kinetic simulations that utilized detailed chemistry mechanisms augmented with O3 oxidation chemistry.

Post-injection strategies aimed at reducing engine-out emissions of unburned hydrocarbons (UHC) were investigated in an optical heavy-duty diesel engine operating at a low-load, low-temperature combustion (LTC) condition with high dilution (12.7% intake oxygen) where UHC emissions are problematic. Exhaust gas measurements showed that a carefully selected post injection reduced engine-out load-specific UHC emissions by 20% compared to operation with a single injection in the same load range. High-speed in-cylinder chemiluminescence imaging revealed that without a post injection, most of the chemiluminescence emission occurs close to the bowl wall, with no significant chemiluminescence signal within 27 mm of the injector. Previous studies have shown that over-leaning in this near-injector region after the end of injection causes the local equivalence ratio to fall below the ignitability limit.

The soot distribution as function of ambient O₂ mole fraction in a heavy-duty diesel engine was investigated at low load (6 bar IMEP) with laser-induced incandescence (LII) and natural luminosity. A Multi-YAG laser system was utilized to create time-resolved LII using 8 laser pulses with a spacing of one CAD with detection on an 8-chip framing camera. It is well known that the engine-out smoke level increases with decreasing oxygen fraction up to a certain level where it starts to decrease again. For the studied case the peak occurred at an O₂ fraction of 11.4%. When the oxygen fraction was decreased successively from 21% to 9%, the initial soot formation moved downstream in the jet. At the lower oxygen fractions, below 12%, no soot was formed until after the wall interaction. At oxygen fractions below 11% the first evidence of soot is in the recirculation zone between two adjacent jets.