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Φ-sensitivity is a fuel characteristic that has important benefits for the operation and control of low-temperature gasoline combustion (LTGC) engines. A fuel is φ-sensitive if its autoignition reactivity varies with the fuel/air equivalence ratio (φ). Thus, multiple-injection strategies can be used to create a φ-distribution that leads to several benefits. First, the φ-distribution causes a sequential autoignition that reduces the maximum heat release rate. This allows higher loads without knock and/or advanced combustion timing for higher efficiencies. Second, combustion phasing can be controlled by adjusting the fuel-injection strategy. Finally, experiments show that intermediate-temperature heat release (ITHR) increases with φ-sensitivity, increasing the allowable combustion retard and improving stability. A detailed mechanism was applied using CHEMKIN to understand the chemistry responsible for φ-sensitivity.

Exhaust gas recirculation (EGR) can be used to mitigate knock in SI engines. However, experiments have shown that the effectiveness of various EGR constituents to suppress knock varies with fuel type and compression ratio (CR). To understand some of the underlying mechanisms by which fuel composition, octane sensitivity (S), and CR affect the knock-mitigation effectiveness of EGR constituents, the current paper presents results from a chemical-kinetics modeling study. The numerical study was conducted with CHEMKIN, imposing experimentally acquired pressure traces on a closed reactor model. Simulated conditions include combinations of three RON-98 (Research Octane Number) fuels with two octane sensitivities and distinctive compositions, three EGR diluents, and two CRs (12:1 and 10:1). The experimental results point to the important role of thermal stratification in the end-gas to smooth peak heat-release rate (HRR) and prevent acoustic noise.

The objectives of this paper are to describe the research efforts in diesel engine combustion at Sandia National Laboratories' Combustion Research Facility and to provide recent experimental results. We have four diesel engine experiments supported by the Department of Energy, Office of Heavy Vehicle Technologies: a one-cylinder version of a Cummins heavy-duty engine, a diesel simulation facility, a one-cylinder Caterpillar engine to evaluate combustion of alternative fuels, and a homogeneous-charge, compression-ignition (HCCI) engine. Recent experimental results of diesel combustion research will be discussed and a description will be given of our HCCI experimental program and of our HCCI modeling work.

To cope with regulatory standards, minimizing tailpipe emissions with rapid catalyst light-off during cold-start is critical. This requires catalyst-heating operation with increased exhaust enthalpy, typically by using late post injections for retarded combustion and, therefore, increased exhaust temperature. However, retardability of post injection(s) is constrained by acceptable pollutant emissions such as unburned hydrocarbon (UHC). This study provides further insight into the mechanisms that control the formation of UHC under catalyst-heating operation in a medium-duty diesel engine, and based on the understanding, develops combustion strategies to simultaneously improve exhaust enthalpy and reduce harmful emissions. Experiments were performed with a full boiling-range diesel fuel (cetane number of 45) using an optimized five-injections strategy (2 pilots, 1 main, and 2 posts) as baseline condition.

For better understanding of soot formation and oxidation processes applicable to diesel engines, the size, morphology, and nanostructure of soot particles directly sampled in a diesel spray flame generated in a constant-volume combustion chamber have been investigated using Transmission Electron Microscopy (TEM). For this soot diagnostics, the effects of the sampling processes, TEM observation methodology and image processing methods on the uncertainty in the results have not been extensively discussed, mainly due to the complexity of the analysis.

Unburned hydrocarbon (UHC) and carbon monoxide (CO) emission sources are examined in an optical, light-duty diesel engine operating under low load and engine speed, while employing a highly dilute, partially premixed low-temperature combustion (LTC) strategy. The impact of engine load and charge dilution on the UHC and CO sources is also evaluated. The progression of in-cylinder mixing and combustion processes is studied using ultraviolet planar laser-induced fluorescence (UV PLIF) to measure the spatial distributions of liquid- and vapor-phase hydrocarbon. A separate, deep-UV LIF technique is used to examine the clearance volume spatial distribution and composition of late-cycle UHC and CO. Homogeneous reactor simulations, utilizing detailed chemical kinetics and constrained by the measured cylinder pressure, are used to examine the impact of charge dilution and initial stoichiometry on oxidation behavior.

Two-scale command shaping is a recently proposed feedforward control method aimed at mitigating undesirable vibrations in nonlinear systems. The TSCS strategy uses a scale separation to cancel oscillations arising from nonlinear behavior of the system, and command shaping of the remaining linear problem. One promising application of TSCS is in reducing engine restart and shutdown vibrations found in conventional and in hybrid electric vehicle powertrains equipped with start-stop features. The efficacy of the TSCS during internal combustion engine restart has been demonstrated theoretically and experimentally in the authors’ prior works. The present article presents simulation results and describes the verified experimental apparatus used to study TSCS as applied to the ICE shutdown case. The apparatus represents a typical HEV powertrain and consists of a 1.03 L three-cylinder diesel ICE coupled to a permanent magnet alternating current electric machine through a spur gear coupling.

In-cylinder concentrations of nitric oxide (NO) in a diesel engine were studied using a laser-induced fluorescence (LIF) technique that employs two-photon excitation. Two-photon NO LIF images were acquired during the expansion and exhaust portions of the engine cycle providing useful NO fluorescence signal levels from 60° after top dead center through the end of the exhaust stroke. The engine was fueled with the oxygenated compound diethylene glycol diethyl ether to minimize soot within the combustion chamber. Results of the two-photon NO LIF technique from the exhaust portion of the cycle were compared with chemiluminescence NO exhaust-gas measurements over a range of engine loads from 1.4 to 16 bar gross indicated mean effective pressure. The overall trend of the two-photon NO LIF signal showed good qualitative agreement with the NO exhaust-gas measurements.

For better understanding of soot formation and oxidation processes in a biodiesel spray flame, the morphology, microstructure and sizes of soot particles directly sampled in a spray flame fuelled with soy-methyl ester were investigated using transmission electron microscopy (TEM). The soot samples were taken at different axial locations in the spray flame, 40, 50 and 70 mm from injector nozzle, which correspond to soot formation, peak, and oxidation zones, respectively. The biodiesel spray flame was generated in a constant-volume combustion chamber under a diesel-like high pressure and temperature condition (6.7 MPa, 1000K). Density, diameter of primary particles and radius of gyration of soot aggregates reached a peak at 50 mm from the injector nozzle and was lower or smaller in the formation or oxidation zones of the spray.

For a better understanding of soot formation and oxidation processes in conventional diesel and biodiesel spray flames, the morphology, microstructure and sizes of soot particles directly sampled in spray flames fuelled with US#2 diesel and soy-methyl ester were investigated using transmission electron microscopy (TEM). The soot samples were taken at 50mm from the injector nozzle, which corresponds to the peak soot location in the spray flames. The spray flames were generated in a constant-volume combustion chamber under a diesel-like high pressure and high temperature condition (6.7MPa, 1000K). Direct sampling permits a more direct assessment of soot as it is formed and oxidized in the flame, as opposed to exhaust PM measurements. Density of sampled soot particles, diameter of primary particles, size (gyration radius) and compactness (fractal dimension) of soot aggregates were analyzed and compared. No analysis of the soot micro-structure was made.

Diesel low-temperature combustion strategies often rely on early injection timing to allow sufficient fuel-ambient mixing to avoid NOx and soot-forming combustion. However, these early injection timings permit the spray to penetrate into a low ambient temperature and density environment where vaporization is poor and liquid impingement upon the cylinder liner and piston bowl are more likely to occur. The objective of this study is to measure the transient liquid and vapor penetration at early-injection conditions. High-speed Mie-scatter and shadowgraph imaging are employed in an optically accessible chamber with a free path of 100 mm prior to wall impingement and using a single-spray injector. The ambient temperature and density within the chamber are well-controlled (uniform) and selected to simulate in-cylinder conditions when injection occurs at -40 crank-angle degrees (CAD) or fewer before top-dead center (TDC).

Fuel injection during negative valve overlap (NVO) can extend low-load gasoline HCCI operation through control of main combustion phasing. Reactions and heat release accompanying NVO fuel injection give rise to changes in temperature and composition of the charge prior to main combustion. The extent of reaction of injected NVO fuel and the relative importance of resulting thermal and chemical effects on main combustion are a current research topic. In this work, bulk temperature computations are used to quantify thermal conditions prior to main ignition for cases with and without NVO fueling. To separate measured thermal effects from chemical effects of NVO fuel reactions on the main combustion, cases without NVO fuel but with similar mixture temperatures and combustion phasing are compared. Effects of varying NVO fuel amount and injection timing on heat release, combustion phasing, bulk temperature evolution, and iso-octane ignition temperatures are analyzed.

Although soot-formation processes in diesel engines have been well characterized during the mixing-controlled burn, little is known about the distribution of soot throughout the combustion chamber after the end of appreciable heat release during the expansion and exhaust strokes. Hence, the laser-induced incandescence (LII) diagnostic was developed to visualize the distribution of soot within an optically accessible single-cylinder direct-injection diesel engine during this period. The developed LII diagnostic is semi-quantitative; i.e., if certain conditions (listed in the Appendix) are true, it accurately captures spatial and temporal trends in the in-cylinder soot field. The diagnostic features a vertically oriented and vertically propagating laser sheet that can be translated across the combustion chamber, where “vertical” refers to a direction parallel to the axis of the cylinder bore.

Fundamental engine research is primarily conducted under steady-state conditions, in order to better describe boundary conditions which influence the studied phenomena. However, light-duty automobiles are operated, and tested, under heavily transient conditions. This mismatch between studied conditions and in-use conditions is deemed acceptable due to the fundamental knowledge gained from steady-state experiments. Nonetheless, it is useful to characterize the conditions encountered during transient operation and determine if the governing phenomena are unduly influenced by the differences between steady-state and transient operation, and further, whether transient behavior can be reasonably extrapolated from steady-state behavior. The transient operation mode used in this study consists of 20 fired cycles followed by 80 motored cycles, operating on a continuous basis.

The accurate quantification and control of mixture stoichiometry is critical in many applications using new combustion strategies and fuels (e.g., homogeneous charge compression ignition, gasoline direct injection, and oxygenated fuels). The parameter typically used to quantify mixture stoichiometry (i.e., the proximity of a reactant mixture to its stoichiometric condition) is the equivalence ratio, ϕ. The traditional definition of ϕ is based on the relative amounts of fuel and oxidizer molecules in a mixture. This definition provides an accurate measure of mixture stoichiometry when the fuel molecule does not contain oxidizer elements and when the oxidizer molecule does not contain fuel elements. However, the traditional definition of ϕ leads to problems when the fuel molecule contains an oxidizer element, as is the case when an oxygenated fuel is used, or once reactions have started and the fuel has begun to oxidize.

Heat release analysis of the in-cylinder pressure records and images of the naturally occurring combustion luminosity obtained in an optical engine are used to explore the effect of variable swirl ratio on the diesel combustion process. Swirl ratios Rs at IVC of 1.5, 2.5, and 3.5 were investigated. The engine is equipped with common-rail fuel injection equipment, and the combustion chamber geometry is maintained as close as possible to typical engines intended for automotive applications. The operating condition employed was 2000 rpm, with a gross IMEP of 5.0 bar and 800 bar injection pressure. Swirl ratio is found to exert a measurable influence on most of the combustion process, from ignition to late-cycle oxidation. Ignition delay decreases with increasing Rs, as do the magnitudes of the initial premixed burn, the peak rates of heat release, and the maximum rates of pressure rise.

Simultaneous two-component measurements of gas velocity and multi-dimensional numerical simulation are employed to characterize the evolution of the in-cylinder turbulent flow structure in a re-entrant bowl-in-piston engine under motored operation. The evolution of the mean flow field, turbulence energy, turbulent length scales, and the various terms contributing to the production of the turbulence energy are correlated and compared, with the objectives of clarifying the physical mechanisms and flow structures that dominate the turbulence production and of identifying the source of discrepancies between the measured and simulated turbulence fields. Additionally, the applicability of the linear turbulent stress modeling hypothesis employed in the k-ε model is assessed using the experimental mean flow gradients, turbulence energy, and length scales.

The objective of this investigation is to verify and characterize the influence of fuel volatility on maximum liquid-phase fuel penetration for a variety of actual Diesel fuels under realistic Diesel engine operating conditions. To do so, liquid-phase fuel penetration was measured for a total of eight Diesel fuels using laser elastic-scatter imaging. The experiments were carried out in an optically accessible Diesel engine of the “heavy-duty” size class at a representative medium speed (1200 rpm) operating condition. In addition to liquid-phase fuel penetration, ignition delay was assessed for each fuel based on pressure-derived apparent heat release rate and needle lift data. For all fuels examined, it was observed that initially the liquid fuel penetrates almost linearly with increasing crank angle until reaching a maximum characteristic length. Beyond this characteristic length, the fuel is entirely vapor phase and not just smaller fuel droplets.

In-cylinder flow and combustion processes simulated with the standard k-ε turbulence model and with an alternative model-employing a non-linear, quadratic equation for the turbulent stresses-are contrasted for both motored and fired engine operation at two loads. For motored operation, the differences observed in the predictions of mean flow development are small and do not emerge until expansion. Larger differences are found in the spatial distribution and magnitude of turbulent kinetic energy. The non-linear model generally predicts lower energy levels and larger turbulent time scales. With fuel injection and combustion, significant differences in flow structure and in the spatial distribution of soot are predicted by the two models. The models also predict considerably different combustion efficiencies and NOx emissions.

Fuel tracer-based planar laser-induced fluorescence is used to investigate the vaporization and mixing behavior of pilot injections for variations in pilot mass of 1-4 mg, and for two injection pressures, two near-TDC ambient temperatures, and two swirl ratios. The fluorescent tracer employed, 1-methylnaphthalene, permits a mixture of the diesel primary reference fuels, n-hexadecane and heptamethylnonane, to be used as the base fuel. With a near-TDC injection timing of −15°CA, pilot injection fuel is found to penetrate to the bowl rim wall for even the smallest injection quantity, where it rapidly forms fuel-lean mixture. With increased pilot mass, there is greater penetration and fuel-rich mixtures persist well beyond the expected pilot ignition delay period. Significant jet-to-jet variations in fuel distribution due to differences in the individual jet trajectories (included angle) are also observed.